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Kathleen A. Radloff Anya R. Manning Brian Mailloux Yan Zheng M. Moshiur Rahman M. Rezaul Huq Kazi M. Ahmed Alexander van Geen 《Applied Geochemistry》2008
Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment. 相似文献
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Inhomogeneous substrate analysis using EM300 backscatter imagery 总被引:2,自引:0,他引:2
Backscatter reflectivity from multibeam echo-sounders provides a powerful tool to efficiently characterize seafloor substrates. A comprehensive EM300 bathymetric and backscatter survey has been completed of Cook Strait, in central New Zealand. This paper presents a detailed analysis of the realtime corrections applied to the raw EM300 multibeam data and additional corrections required to compute angular variations of the backscatter strength. The corrections, including the local absorption coefficient, the influence of seafloor topography and sound refraction in the water column, are determined for different Cook Strait seafloor substrates. Modifying MB-System software code, we extracted the backscatter signal parameters in order to quantify the raw backscatter strength and apply additional processing. Profiles of backscatter strength versus incidence angle were computed for a variety of sites characterized by flat seafloor and homogeneous substrates, and for which ground-truth data were available. For each homogeneous site, different but characteristic backscatter profiles are observed that can be interpreted in terms of sediment facies. To analyze heterogeneous substrates, we present a statistical technique, based on a 3-dimensional distribution of (incidence angle, backscatter strength) couples that preserves geological information of the substrate components. This analysis, using backscatter data acquired on a submarine volcano, north of New Zealand, clearly differentiates soft sediments and lava flows within a heterogeneous substrate. 相似文献
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Alkylphenolic compounds are present in estuarine and marine environments. They are moderately bioaccumulative, and oestrogenic to fish following three week, in vivo, exposures. The effects of prolonged exposure are, as yet, unclear. Sand goby (Pomatoschistus minutus) were exposed to measured concentrations of 4-tert-octylphenol (OP) in a 28-day, dose-ranging study, and a six month temporal response study. Following 28-days exposure to measured 31+/-6 or 101+/-47 microg l(-1) OP (mean+/-SD), immature male sand goby showed elevated vitellogenin (VTG) mRNA expression. Plasma alkali-labile phosphate concentrations were elevated in both sexes and were higher in females than males. Although measured OP concentrations were variable, they were significantly different for each treatment and a range of concentration-dependent effects were observed. The LC(50) for chronic OP exposure (8 weeks) was 29+/-6 microg l(-1), and both sexes demonstrated concentration and duration dependent increases in VTG mRNA expression. Exposure to 28+/-20 microg l(-1) OP (median+/-95% CI) for 6 months inhibited development of male nuptial colouration and sperm duct glands. These findings are discussed in relation to environmental concentrations of alkylphenols and ecological concerns. 相似文献
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A program for computation of the gravity and magnetic anomalies associated with two-dimensional structures has been adapted for use in an interactive mode using a storage-screen CRT linked to a remote computer via standard telephone lines. This new program aids the user in developing a structural model that satisfies both magnetic and gravity observations. Examples are included to demonstrate the increased efficiency of interpretation using this low-cost graphics approach and to illustrate the detail of the model resulting from the compromise necessary to satisfy both potential-field data sets. 相似文献
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Toshiro Saino Alexander Bychkov Chen-Tung Arthur Chen Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4
This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean
Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific
Synthesis Group, with the aim of quantifying CO2 drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual
variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and
differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the
future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief
overview of the papers from view points of CO2 drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales
is made, followed by suggestions for the directions of future research.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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