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11.
An analysis of the Lowell Observatory photographic plates of Saturn gave the following results: (1) ring A and B show peculiar brightness distributions around the planet, from which we conclude that both are composed of particles in synchronous rotation. (2) The leading side of the particles in ring A is brighter than the trailing side by about 4%, which may indicate an interaction between such particles and the interplanetary medium. (3) Scans of the rings across the major axis show a small (~0.3″) region of enhanced brightness, from which we derive a value ofT s =10h13 . m 8±5 . m 4 for the actual planetary rotational period of Saturn. (4) In order to explain the synchronous rotation, the particles in ring A have to be at least 42 m in diameter.  相似文献   
12.
13.
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4= anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   
14.
Large sheath folds in the basal high-pressure nappes of the Cabo Ortegal complex are described and a kinematic interpretation provided. The principal penetrative and map structures relate to regional D2 deformation, which produced foliations (S2) bearing mineral and stretching lineations (L2) and several types of folds (a-type, sheath-like and ‘folded folds’). The latter structures are subparallel to the trend of the orogen. Their attitude suggests that the units involved shared a common tectonic evolution during progressive ductile deformation of an anisotropic medium. Reconstruction of major geological structures was accomplished through projection of map-scale features onto the ductile flow plane and the plane perpendicular to the ductile flow direction. The structures reconstructed illustrate their development in the deeper structural levels of an orogenic channel subjected to high-pressure metamorphism during the early phases of the Hercynian orogeny in NW Iberia. We argue that orogen-normal tectonic displacements (of up to a few hundreds of kilometers) represent the minor components of the transpression with possibly thousands of kilometers along-strike dextral displacement between the intervening plates (during subduction/collision).  相似文献   
15.
The oxidation of Mn(II) by O2 to Mn(III) or Mn(IV) is thermodynamically favored under the pH and pO2 conditions present in most near surface waters, but the kinetics of this reaction are extremely slow. This work investigated whether reactive oxygen species, produced through illumination of humic substances, could oxidize Mn at an environmentally relavent rate. The simulated sunlight illumination of a solution containing 200 μM Mn(II) and 5 mg/L Aldrich humic acid buffered at pH 8.1 produced ∼19 μM of oxidized Mn (MnOx where x is between one and two) after 45 minutes. The major oxidants reponsible for this reaction appear to be photoproduced superoxide radical anion, O2, and singlet molecular oxygen, 1O2. The dependencies of MnOx formation on Mn(II), humic acid, and H+ concentration were characterized. A kinetic model based largely on published rate constants was established and fit to the experimental data. As expected, analysis of the model indicates that the key reaction rate controlling MnOx production is the rate of decomposition of a MnO2+ complex formed from the reaction of Mn(II) with O2. This rate is strongly dependent on the Mn(II) complexing ligands in solution. The MnOx production in the seawater sample taken from Bodega Bay, USA and spiked with 200 μM Mn(II) was well reproduced by the model. Extrapolations from the model imply that Mn photo-oxidation should be a significant reaction in typical surface seawaters. Calculated rates, 5.8 to 55 pM h−1, are comparable to reported rates of biological Mn oxidation, 0.07 to 89 pM h−1. Four fresh water samples that were spiked with 200 μM Mn(II) also showed significant MnOx production. Based on these results, it appears that Mn photo-oxidation could constitute a significant, and apparently unrecognized geochemical pathway in natural waters.  相似文献   
16.
The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.  相似文献   
17.
The Serra Gelada sea cliffs are carved in Mesozoic carbonate rocks belonging to the External Zones of the eastern Betic Cordillera (Alicante, SE Spain). Several normal faults with vertical slips of more than a hundred metres have played an important role in the origin of this coastline. Some previous studies propose that the present cliff morphology was mainly originated by Quaternary fault activity. However, the integration of geomorphological features, stratigraphical and sedimentological data, together with the results of the tectonic analysis of fractures occurring in Serra Gelada, and a detailed study of seismic reflection profiles carried out in the adjacent continental shelf, indicate that these normal faults were active mainly during the late Miocene. Therefore, the Serra Gelada sea cliffs represent a tectonically controlled long-term landscape. Thus, normal faults have not significantly modified the Serra Gelada relief since then. Furthermore, the northern part of the Serra Gelada cliff may be considered as an inherited pre-Quaternary relict palaeocliff since it has only undergone very little erosive recession.  相似文献   
18.
The impact of volcanic eruptions on forest ecosystems can be investigated using dendrochronological records. While long-range effects are usually mediated by decreased air temperatures, resulting in frost rings or reduced maximum latewood density, local effects include abrupt suppression of radial growth, occasionally followed by greater than normal growth rates. Annual rings in Mexican mountain pine (Pinus hartwegii Lindl.) on Nevado de Colima, at the western end of the Mexican Neovolcanic Belt, indicate extremely low growth in 1913 and 1914, following the January 1913 Plinian eruption of Volcán de Fuego, 7.7 km to the south. That event, which is listed among the largest explosive eruptions since A.D. 1500, produced ashflow deposits up to 40 m thick and blanketed our study area on Nevado de Colima with a tephra fallout 15–30 cm deep. Radial growth reduction in 1913–14 was ≥30% in 73% of the sampled trees. We geostatistically investigated the ecological impact of the eruption by mapping the decrease in xylem increment and found no evidence of a spatial structure in growth reduction. Little information has been available to date on forest species as biological archives of past environments in the North American tropics, yet this historical case study suggests that treeline tropical sites hold valuable records of prehistoric phenomena, including volcanic eruptions.  相似文献   
19.
A nationwide multidate GIS database was generated in order to carry out the quantification and spatial characterization of land use/cover changes (LUCC) in Mexico. Existing cartography on land use/cover at a 1:250,000 scale was revised to select compatible inputs regarding the scale, the classification scheme and the mapping method. Digital maps from three different dates (the late 1970s, 1993 and 2000) were revised, evaluated, corrected and integrated into a GIS database. In order to improve the reliability of the database, an attempt was made to assess the accuracy of the digitalisation procedure and to detect and correct unlikely changes due to thematic errors in the maps. Digital maps were overlaid in order to generate LUCC maps, transition matrices and to calculate rates of conversion. Based upon this database, rates of deforestation between 1976 and 2000 were evaluated as 0.25 and 0.76% per year for temperate and tropical forests, respectively.  相似文献   
20.
The elemental (concentration of organic carbon, atomic H/C and C/N ratios), isotopic (δ13C values of organic matter) and molecular (predominant n-alkane chain length and carbon preference index (CPI)) organic components were measured for 600 samples taken from a 107-m long core from the Padul Basin (Andalusia, Spain). The record runs from the Lower Pleistocene (ca. 1 Ma B.P.) to the mid-Holocene (ca. 4.5 ka B.P.) with, in general, little diagenesis (removal of components). Two markedly different hydrogeological scenarios were interpreted: (1) From ca. 1 Ma to ca. 400 ka B.P. run-off recharge was significant and water depths were greater (lacustrine scenario). From ca. 400 to 4.5 ka B.P., the Padul Basin became a peat bog s.s. with the major water input coming from groundwater inflow. From ca. 400 to ca. 180 ka B.P. alternating episodes with either predominant grasses, trees or aquatic macrophytes which were linked to wet/dry phases, took place. An important deglaciation episode has been interpreted to occur between ca. 180 and 170 ka B.P. The global climatic changes occurring from ca. 170 to 25 ka B.P. were not recorded in the proxies, though they do show important variations linked to the Last Glacial Maximum and the beginning of the Holocene (ca. 25–10 ka B.P.): (2) Cold phases coexisting with dry periods produced the recession of forests and the development of grasses. After these periods, as both temperature and precipitation increased, forests expanded and the water level, linked to thaw, rose, especially at ca. 20 ka B.P. Few changes occurred during the Holocene, although there were short alternations between wet and dry episodes. Overall, the techniques applied proved to be excellent palaeoenvironmental proxies for studying the basin’s palaeoclimatological and palaeohydrological evolution.  相似文献   
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