Interaction between different water bodies in a small catchment in the Paris basin (Brévilles,France): Tracing of multiple Sr sources through Sr isotopes coupled with Mg/Sr and Ca/Sr ratios     

Agnès Brenot  Nicole BaranEmmanuelle Petelet-Giraud  Philippe Négrel 《Applied Geochemistry》2008

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Field application of calcite Dispersed Alkaline Substrate (calcite-DAS) for passive treatment of acid mine drainage with high Al and metal concentrations     

Tobias S. Rötting  Manuel A. Caraballo  José A. Serrano  Carlos Ayora  Jesús Carrera 《Applied Geochemistry》2008

Passive treatment systems are widely used for remediation of acid mine drainage (AMD), but existing designs are prone to clogging or loss of reactivity due to Al- and Fe-precipitates when treating water with high Al and heavy metal concentrations. Dispersed alkaline substrate (DAS) mixed from a fine-grained alkaline reagent (e.g. calcite sand) and a coarse inert matrix (e.g. wood chips) had shown high reactivity and good hydraulic properties in previous laboratory column tests. In the present study, DAS was tested at pilot field scale in the Iberian Pyrite Belt (SW Spain) on metal mine drainage with pH near 3.3, net acidity 1400–1650 mg/L as CaCO₃, and mean concentrations of 317 mg/L Fe (95% Fe(II)), 311 mg/L Zn, 74 mg/L Al, 20 mg/L Mn, and 1.5–0.1 mg/L Cu, Co, Ni, Cd, As and Pb. The DAS-tank removed an average of 870 mg/L net acidity as CaCO₃ (56% of inflow), 25% Fe, 93% Al, 5% Zn, 95% Cu, 99% As, 98% Pb, and 14% Cd, but no Mn, Ni or Co. Average gross drain pipe alkalinity was 181 mg/L as CaCO₃, which increased total Fe removal to 153 mg/L (48%) in subsequent sedimentation ponds. Unfortunately, the tank suffered clogging problems due to the formation of a hardpan of Al-rich precipitates. DAS lifetime could probably be increased by lowering Al-loads.  相似文献   

Characterisation of aerosol from Santiago,Chile: an integrated PIXE–SEM–EDX study     

D. Morata  M. Polvé  A. Valdés  M. Belmar  M. I. Dinator  M. Silva  M. A. Leiva  T. Aigouy  J. R. Morales 《Environmental Geology》2008,56(1):81-95

Santiago de Chile is a big city with huge air quality problems, being one of the most polluted cities in the world. This is aggravated during winter by the topography and meteorological conditions of the city. Although public policies have been developed to minimise the atmospheric aerosol pollution, there is a lack of adequate knowledge and poor characterisation of these aerosols (in its PM_2.5 and PM₁₀ fractions). In this study we sampled atmospheric particles during winter in two distinct areas of Santiago: downtown (Teatinos Street) and in a more residential area (Macul). Major (Si, Al, Fe, Ca and K) and some trace element (S, Cl, Ti, P, Cr, Cu and Zn) compositions were obtained by proton-induced X-ray emission (PIXE). Morphological, type and chemical characterisation was also performed using scanning electron microscopy (SEM) coupled with an energy dispersive X-ray microanalysis system (SEM–EDX). Besides the carbon particles, the contribution of which can be quite important in the atmospheric aerosol, especially in downtown, unambiguously lithogenic (i.e. of geological origin) particles and elements are the second highest contributors. Enrichment factor calculation, together with particle identification and element correlation allow the origin of some elements and particles to be traced, revealing anthropogenic origins for some of them that are specific to the Santiago area.  相似文献   

Influence of surface heterogeneities of building granite on its thermal response and its potential for the generation of thermoclasty     

Miguel Gómez-Heras  Bernard J. Smith  Rafael Fort 《Environmental Geology》2008,56(3-4):547-560

Surface properties, especially albedo, and aspect are widely accepted as strong influences on the surface thermal response of building stone to insolation. However, the influence that adjacent areas of stone with very different surface properties may have on the thermal response of a patch of stonework, and the ways in which spatial variation in thermal characteristics might enhance stone decay has received relatively little attention. This paper examines the differential thermal response of granite used in construction that results from the presence of dark coloured micro-granular enclaves within a leucocratic host. Surface temperatures and temperature differences between enclaves exhibiting mico-spalling, enclaves with no spalling and the surrounding stone were measured for different aspects and seasons on a 20th century building in Madrid. These data were used to calculate a number of “indices” related to short-term temperature cycling and temperature gradients that have the theoretical capability of generating irreversible deformation of the stone. These indices suggest that micro-spalling of enclaves, compared to a lack of similar decay on the host-rock, is related to their differential thermal response to insolation, most importantly the lower albedo and thermal conductivity values of the enclaves. However, these factors are not sufficient on their own to trigger spalling, and breakdown was only observed where enclaves also experienced repeated, short-term surface temperature cycling caused by, for example, temporary shading by adjacent vegetation. These rapid temperature reversals are identified as a key contributory factor to the thermally driven decay observed on some of the enclaves.  相似文献   

Facies analyses and volcanic setting of the giant Neves Corvo massive sulfide deposit,Iberian Pyrite Belt,Portugal     

Carlos J. P. Rosa  Jocelyn McPhie  Jorge M. R. S. Relvas  Zélia Pereira  Tomás Oliveira  Nelson Pacheco 《Mineralium Deposita》2008,43(4):449-466

In the Iberian Pyrite Belt, volcanic rocks are relatively scarce, accounting for approximately only 25% of the geologic record, with the remaining 75% consisting of sedimentary units. This association is very clear in the host succession to the Neves Corvo massive sulfide deposit in Portugal. The Neves Corvo host succession comprises the products of explosive and effusive rhyolitic eruptions intercalated with mudstone that records a submarine below-wave-base environment and provides precise biostratigraphic age constraints. The first and second volcanic events involved eruptions at local intrabasinal vents. The first event generated thick beds of fiamme breccia that are late Famennian in age. The fiamme were originally pumice clasts produced by explosive eruptions and were subsequently compacted. The second event was the late Strunian (latest Famennian) effusion of rhyolitic lava that was pervasively quench-fragmented. The third and final event is younger than the massive sulfide deposits poorly represented in the mine area and minor compared with the two other events. The integration of biostratigraphic data with the volcanic facies architecture indicates that the Neves Corvo ore deposits are similar in age to the late Strunian rhyolitic lava. Although regionally the Iberian Pyrite Belt is essentially a sedimentary succession, ore formation at Neves Corvo can be closely linked to discrete volcanic events that produced a relatively narrow range of volcanic facies.  相似文献   

Time relationships between volcanism–plutonism–alteration–mineralization in Cu-stratabound ore deposits from the Michilla mining district,northern Chile: a <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronological approach     

Verónica Oliveros  Dania Tristá-Aguilera  Gilbert Féraud  Diego Morata  Luis Aguirre  Shoji Kojima  Fernando Ferraris 《Mineralium Deposita》2008,43(1):61-78

The Michilla mining district comprises one of the most important stratabound and breccia-style copper deposits of the Coastal Cordillera of northern Chile, hosted by the Middle Jurassic volcanic rocks of the La Negra Formation. ⁴⁰Ar/³⁹Ar analyses carried out on igneous and alteration minerals from volcanic and plutonic rocks in the district allow a chronological sequence of several magmatic and alteration events of the district to be established. The first event was the extrusion of a thick lava series of the La Negra Formation, dated at 159.9 ± 1.0 Ma (2σ) from the upper part of the series. A contemporaneous intrusion is dated at 159.6 ± 1.1 Ma, and later intrusive events are dated at 145.5 ± 2.8 and 137.4 ± 1.1 Ma, respectively. Analyzed alteration minerals such as adularia, sericite, and actinolite apparently give valid ⁴⁰Ar/³⁹Ar plateau and miniplateau ages. They indicate the occurrence of several alteration events at ca. 160–163, 154–157, 143–148, and 135–137 Ma. The first alteration event, being partly contemporaneous with volcanic and plutonic rocks, was probably produced in a high thermal gradient environment. The later events may be related either to a regional low-grade hydrothermal alteration/metamorphism process or to plutonic intrusions. The Cu mineralization of the Michilla district is robustly bracketed between 163.6 ± 1.9 and 137.4 ± 1.1 Ma, corresponding to dating of actinolite coexisting with early-stage chalcocite and a postmineralization barren dyke, respectively. More precisely, the association of small intrusives (a dated stock from the Michilla district) with Cu mineralization in the region strongly suggests that the main Michilla ore deposit is related to a magmatic/hydrothermal event that occurred between 157.4 ± 3.6 and 163.5 ± 1.9 Ma, contemporaneous or shortly after the extrusion of the volcanic sequence. This age is in agreement with the Re–Os age of 159 ± 16 Ma obtained from the mineralization itself (Tristá-Aguilera et al., Miner Depos, 41:99–105,2006).  相似文献   

IAG Newsletter     

Gyula Tóth 《Journal of Geodesy》2017,91(1):113-116

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IAG Newsletter     

Gyula Tóth 《Journal of Geodesy》2017,91(2):229-232

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Quantifying deformation in North Borneo with GPS     

Mohamad?Asrul?MustafarEmail authorView author&#;s OrcID profile  Wim?J.?F.?Simons  Felix?Tongkul  Chalermchon?Satirapod  Kamaludin?Mohd?Omar  Pieter?N.?A.?M.?Visser 《Journal of Geodesy》2017,91(10):1241-1259

The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.  相似文献   

IAG Newsletter     

Gyula Tóth 《Journal of Geodesy》2017,91(5):573-577

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