Science and User Needs for Observing Global Mass Transport to Understand Global Change and to Benefit Society     

Roland Pail  Rory Bingham  Carla Braitenberg  Henryk Dobslaw  Annette Eicker  Andreas Güntner  Martin Horwath  Eric Ivins  Laurent Longuevergne  Isabelle Panet  Bert Wouters  IUGG Expert Panel 《Surveys in Geophysics》2015,36(6):743-772

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Crude Oil Metabolites in Groundwater at Two Spill Sites          下载免费PDF全文

Barbara A. Bekins  Isabelle M. Cozzarelli  Melinda L. Erickson  Ross A. Steenson  Kevin A. Thorn 《Ground water》2016,54(5):681-691

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.  相似文献   

Arsenic Cycling in Hydrocarbon Plumes: Secondary Effects of Natural Attenuation          下载免费PDF全文

Isabelle M. Cozzarelli  Madeline E. Schreiber  Melinda L. Erickson  Brady A. Ziegler 《Ground water》2016,54(1):35-45

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe‐hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude‐oil‐contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe‐hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe‐hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.  相似文献   

Insights from numerical modeling on the hydrodynamics of non-radial flow in faulted media     

Silvain Rafini  Marie Larocque 《Advances in water resources》2009

The objective of this work is to explore the use of flow dimensions as a tool for characterizing hydraulic conditions in faulted media. Transient flow is numerically simulated in synthetic vertically-faulted reservoirs. Analysis of the obtained time series following the Generalized Radial Flow (GRF) model displays combined radial and fractional signals with a flow dimension n=1.5$n=1.5$. Investigating the transient geometry of the frontal equipotential surface shows that fractional flow occurrence is due to abnormal fault diffusion as a consequence of water supply from the matrix under specific conditions. An original hydrodynamical explanation for fractional flow in vertically faulted media is suggested, along with a reinterpretation of the bilinear regime. It is shown that the GRF theory remains valid in such discontinuum as the fundamental relationship between n and the cross-flow area is satisfied. These results provide insights in the use of the flow dimension as a hydraulic diagnostic tool in faulted media.  相似文献   

Late Glacial and Holocene temperature changes at Egelsee,Switzerland, reconstructed using subfossil chironomids     

Isabelle Larocque-Tobler  Oliver Heiri  Michael Wehrli 《Journal of Paleolimnology》2010,43(4):649-666

A temperature reconstruction using chironomids was attempted at Egelsee, Switzerland, a site where pollen and macrofossil records showed a correspondence between vegetation and climatic changes inferred by other proxies in Europe. The general pattern of temperature changes inferred from chironomids during the Late Glacial [i.e. cold temperatures between ca. 16,500 and 14,800 cal BP, close to present-day temperature between 15,000 and 13,000 cal BP and colder temperatures during the Younger Dryas (YD)], and the major temperature changes of the Holocene (i.e. the Younger Dryas–Holocene transition and the Late Holocene cooling trend) at Egelsee, were mirrored in other European climate reconstructions using various proxies. However, the amplitude of temperature changes during the YD was smaller than reconstructed by other proxies at various sites, and the 8,200 years BP event was not apparent. These differences between records were probably due to the dominance of Corynocera ambigua, with percentages reaching 60% in parts of the Egelsee sequence. This taxon was not present in any of the 103 lakes used for the transfer function and its absence may have yielded less accurate inferences. Its presence in samples only associated with cold inferences at Egelsee suggests that this taxon is a cold indicator. However, it was also found in warm Danish lakes and the factors that determine the presence of C. ambigua remain unexplained. Most samples had a poor fit to temperature and instead, dissolved organic carbon seemed to be a factor influencing the chironomid assemblages during the Holocene. These results illustrate the need to better understand the ecology of chironomids and to disentangle the various factors that affect chironomid communities through time. Ultimately, such information will lead to more accurate temperature reconstructions.  相似文献   

Sediment Yield During Late Glacial and Holocene periods in the Lac Chambon Watershed,Massif Central,France     

Jean-Jacques Macaire  Gilles Bossuet  Alain Choquier  Constantin Cocirta  Patrick de Luca  Andr Dupis  Isabelle Gay  Eric Mathey  Pascal Guenet 《地球表面变化过程与地形》1997,22(5):473-489

A sediment budget for the Late Glacial and Holocene periods was calculated for the Lac Chambon watershed which is located in a formerly glaciated temperate crystalline mountain area. It appears that over 15 500 years: (1) 69 per cent of eroded particles have been displaced by gravity processes and then stored within the watershed, compared to 31 per cent that have been displaced by running water and evacuated outward; (2) the mean mechanical erosion due to gravity processes on the slopes amounted to 16·1 ±6 m and only developed on a quarter of the watershed surface, whereas the mean mechanical erosion due to running water amounted 1·24 ± 0·37 m and involved the whole watershed surface. The mean sediment yields due to gravity processes on slopes were 2300 ± 1360, 1770 ± 960 and 380 ± 100 m³ km⁻³ a⁻¹, respectively, for basalts, and basic and acidic trachyandesites. Values of sediment yield due to running water were 49±15, 120±36 and 79±24 m³ km⁻² a⁻¹, respectively, during the Bôlling–Allerôd, the Younger Dryas and the Pre-Boreal–Boreal periods. They were 56±17 and 166±50 m³ km⁻² a⁻¹ during the Sub-Atlantic period before and after 1360 a BP , respectively. These values reflect variations in the natural environment and the impact of human-induced deforestation. © 1997 by John Wiley & Sons, Ltd.  相似文献   

Biodegradation in contaminated aquifers: incorporating microbial/molecular methods   总被引：2，自引：0，他引：2  

Weiss JV  Cozzarelli IM 《Ground water》2008,46(2):305-322

In order to evaluate natural attenuation in contaminated aquifers, there has been a recent recognition that a multidisciplinary approach, incorporating microbial and molecular methods, is required. Observed decreases in contaminant mass and identified footprints of biogeochemical reactions are often used as evidence of intrinsic bioremediation, but characterizing the structure and function of the microbial populations at contaminated sites is needed. In this paper, we review the experimental approaches and microbial methods that are available as tools to evaluate the controls on microbially mediated degradation processes in contaminated aquifers. We discuss the emerging technologies used in biogeochemical studies and present a synthesis of recent studies that serve as models of integrating microbiological approaches with more traditional geochemical and hydrogeologic approaches in order to address important biogeochemical questions about contaminant fate.  相似文献   

Autecology of Limnomysis benedeni Czerniavsky, 1882 (Crustacea: Mysida) in Lake Constance, Southwestern Germany     

Ren Gergs  Almut J. Hanselmann  Isabelle Eisele  Karl-Otto Rothhaupt 《Limnologica》2008,38(2):139-146

The Ponto-Caspian mysid Limnomysis benedeni was first recorded in Lake Constance in summer 2006, and a stable population developed at the site of discovery. Although this mysid is common in the Rhine and Danube rivers, little is known about its ecology and impact in systems of invasion. We investigated the autecology of L. benedeni in habitat-choice and food experiments. In the habitat-choice experiments, highly structured habitats, i.e., stones covered with zebra mussels (Dreissena polymorpha), macrophytes, and especially stonewort, were strongly preferred. In food experiments, L. benedeni fed mostly on food sources with a small particle size, e.g., biofilm on leaf litter, biodeposited material of zebra mussels, epilithon, and phytoplankton. We also compared the L. benedeni population data from Lake Constance with that from rivers. In Lake Constance, female L. benedeni were nearly 30% larger and carried more than three times more eggs in spring (9.4±0.6 mm and 28.4±5.7 eggs) than in summer (6.7±0.8 mm and 8.7±2.9 eggs). The mysids present in spring might be the generation that over-wintered; in summer, this generation was probably replaced by a new generation of smaller individuals. The large brood size and the detritivorous feeding strategy might allow L. benedeni to colonize Lake Constance rapidly.  相似文献   

Paleogeography of Lake Agassiz and regional post-glacial uplift history of the Flin Flon region, central Manitoba and Saskatchewan     

Isabelle McMartin 《Journal of Paleolimnology》2000,24(3):293-315

Detailed mapping and elevation measurements of glacial lake shorelines in the Flin Flon region has permitted the reconstruction of 6 well-defined levels of Lake Agassiz formed around 8.3 ka to 7.9 ka ¹⁴C BP. The Stonewall, The Pas, Gimli, Grand Rapids, Drunken Point and Ponton paleo-water planes have been tilted upward to the northeast in the Holocene, with gradients decreasing, from the highest to the lowest level, from about 0.34 m km^-1 to 0.22 m km^-1 in the study area. The Setting level, lower than the Ponton but less well defined, is also documented here for the first time. This mapping conclusively refutes the view, entrenched in the literature from the 1890's to the 1960's, that there has been negligible differential uplift in the region following final drainage of Lake Agassiz. The finding has major consequences regarding correlation of glacial lakes across the mid-continent, the post-glacial history of large lakes in the region, and for interpretation of earth rheology and its implications for ice sheet reconstruction.  相似文献   

Investigating peat hydrological properties using field and laboratory methods: application to the Lanoraie peatland complex (southern Quebec,Canada)   总被引：1，自引：0，他引：1  

E. Rosa  M. Larocque 《水文研究》2008,22(12):1866-1875

Flow dynamics within a peatland are governed by hydraulic parameters such as hydraulic conductivity, dispersivity and specific yield, as well as by anisotropy and heterogeneity. The aim of this study is to investigate hydraulic parameters variability in peat through the use of different field and laboratory methods. An experimental site located in the Lanoraie peatland complex (southern Quebec, Canada) was used to test the different approaches. Slug and bail tests were performed in piezometer standpipes to investigate catotelm hydraulic conductivity. Combined Darcy tests and tracer experiments were conducted on cubic samples using the modified cube method (MCM) to assess catotelm hydraulic conductivity, anisotropy and dispersivity. A new laboratory method is proposed for assessing acrotelm hydraulic conductivity and gravity drainage using a laboratory experimental tank. Most of slug tests' recovery curves were characteristic of compressible media, and important variability was observed depending on the initial head difference. The Darcy experiments on cubic samples provided reproducible results, and anisotropy (K_h > K_v) was observed for most of samples. All tracer experiments displayed asymmetrical breakthrough curves, suggesting the presence of retardation and/or dual porosity. Hydraulic conductivity estimates performed using the experimental tank showed K variations over a factor of 44 within the upper 40 cm of the acrotelm. The results demonstrate that the intrinsic variability associated with the different field and laboratory methods is small compared with the spatial variability of hydraulic parameters. It is suggested that a comprehensive assessment of peat hydrological properties can be obtained through the combined use of complementary field and laboratory investigations. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献