Cyanobacterial blooms in estuarine ecosystems: characteristics and effects on Laeonereis acuta (Polychaeta, Nereididae)     

da Rosa CE  de Souza MS  Yunes JS  Proença LA  Nery LE  Monserrat JM 《Marine pollution bulletin》2005,50(9):956-964

In January of 2003, a cyanobacterial bloom in the Patos' Lagoon (Southern Brazil) (32 degrees 05'S-52 degrees 12'W) was observed. Water samples were taken to identify the composition and abundance of the bloom, as well as the occurrence of toxins. The effects of this occurrence on the estuarine worm Laeonereis acuta (Polychaeta, Nereididae) was also evaluated. Predominance of cyanobacteria, particularly Anabaena trichomes ( approximately 2.5.10(6) individuals per liter) was observed, and low concentrations of microcystins and anticholinesterasic toxins were detected. Augmented levels of lipid hydroperoxides (LPO) and glutathione-S-transferase activity, and lowering of total protein content were also observed in organisms collected during the bloom event. Although non-toxic, the cyanobacterial bloom could augment the cycle of hyper-oxygenation and hypoxia in the water. During hyperoxia, L. acuta, an oxyconformer, should consume more oxygen, thus augmenting the rate of reactive oxygen species generation. A repeated cycle of hyper-oxygenation and hypoxia would finally induce oxidative stress, as evidenced by the high levels of LPO and glutathione-S-transferase activity.  相似文献   

Fate and effects of picric acid and 2,6-DNT in marine environments: toxicity of degradation products     

Nipper M  Carr RS  Biedenbach JM  Hooten RL  Miller K 《Marine pollution bulletin》2005,50(11):1205-1217

The toxicity of transformation products of 2,6-dinitrotoluene (2,6-DNT) and 2,4,6-trinitrophenol (picric acid) were assessed in spiked sandy and fine-grained marine sediments and in seawater. Toxicity of pore water from sediments spiked with 2,6-DNT decreased for the macro-alga, Ulva fasciata, zoospores as biotransformation proceeded, but increased for the copepod, Schizopera knabeni, nauplii. The primary biotransformation product of 2,6-DNT, 2-amino-6-nitrotoluene, was also more toxic than the parent compound to copepod nauplii, but not to alga zoospores, in spiked seawater tests. Two biotransformation products of picric acid, picramic acid and 2,4-DNP, were more toxic than their parent compound. Porewater toxicity from picric acid-spiked sediments decreased significantly at the end of six-months incubation. Fine-grained sediment spiked with either ordnance compound had lower toxicity than its sandy counterpart after six months, suggesting faster microbial transformation in the former and production of less toxic products. Photo-transformation of 2,6-DNT in seawater resulted in a reduction in toxicity.  相似文献   

Concentrations of alkylphenols in sediments from the Pearl River estuary and South China Sea, South China   总被引：2，自引：0，他引：2  

Chen B  Mai BX  Duan JC  Luo XJ  Yang QS  Sheng GY  Fu JM 《Marine pollution bulletin》2005,50(9):993-997

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Development of a system of indicators for sustainable port management   总被引：2，自引：0，他引：2  

Peris-Mora E  Diez Orejas JM  Subirats A  Ibáñez S  Alvarez P 《Marine pollution bulletin》2005,50(12):1649-1660

The 1998 project ECOPORT, “Towards A Sustainable Transport Network”, developed by the Valencia Port Authority (VPA), established the bases for implementing an Environmental Management System (EMS) in industrial harbours. The use of data and information shall always be required to develop an efficient EMS. The objective of the present research (INDAPORT) study is to propose a system of sustainable environmental management indicators to be used by any port authorities. All activities performed within a port area are analysed for any potential environmental impacts and risks.

An environmental analysis of port activities has been carried out with the objective of designing the indicators system. Twenty-one corresponding activities have been identified for large industrial ports. Subsequently, the same methodology developed to date will be later applied to other Spanish and European ports. The study has been developed by using an original system and a methodology, which simultaneously use stage diagrams and systemic models (material and energy flow charts). Multi-criteria analysis techniques were used to evaluate potential impacts (identification of factors and evaluation of impacts).  相似文献   

Toxicological and chemical assessment of ordinance compounds in marine sediments and porewaters     

Nipper M  Carr RS  Biedenbach JM  Hooten RL  Miller K 《Marine pollution bulletin》2002,44(8):789-806

Toxicological and chemical studies were performed with a silty and a sandy marine sediment spiked with 2,6-dinitrotoluene (2,6-DNT), 2,4,6-trinitrophenylmethylnitramine (tetryl), or 2,4,6-trinitrophenol (picric acid). Whole sediment toxicity was analyzed by the 10-day survival test with the amphipod Ampelisca abdita, and porewater toxicity tests assessed macro-algae (Ulva fasciata) zoospore germination and germling growth, sea urchin (Arbacia punctulata) embryological development, and polychaete (Dinophilus gyrociliatus) survival and reproduction. Whole sediments spiked with 2,6-DNT were not toxic to amphipods. The fine-grained sediment spiked with tetryl was also not acutely toxic. The tetryl and picric acid LC50 values in the sandy sediment were 3.24 and 144 mg/kg dry weight, respectively. The fine-grained sediment spiked with picric acid generated a U-shaped concentration-response curve in the amphipod test, with increased survival both in the lowest and highest concentration. Grain-size distribution and organic carbon content strongly influenced the behavior of ordnance compounds in spiked sediments. Very low concentrations were measured in some of the treatments and irreversible binding and biodegradation are suggested as the processes responsible for the low measurements. Porewater toxicity varied with its sedimentary origin and with ordnance compound. The sea urchin embryological development test tended to be the least sensitive. Tetryl was the most toxic chemical in all porewater tests, and picric acid the least toxic. Samples spiked with 2,6-DNT contained a degradation product identified as 2-methyl-3-nitroaniline (also known as 2-amino-6-nitrotoluene), and unidentified peaks, possibly degradation products, were also seen in some of the picric acid- and tetryl-spiked samples. Degradation products may have played a role in observed toxicity.  相似文献   

Organic carbon flow in the Ob, Yenisey Rivers and Kara Sea of the Arctic region     

Krishnamurthy RV  Machavaram M  Baskaran M  Brooks JM  Champs MA 《Marine pollution bulletin》2001,42(9):726-732

Stable carbon isotope and elemental C/N ratios of the organic fraction of a set of samples along a transect in the Ob and Yenisey Rivers into the Kara Sea in the Arctic were measured. Previously, the concentrations of 239,240Pu and 137Cs in these same samples had been determined. The coupled measurements were carried out to assess possible connectivity between organic carbon flow into the Kara Sea and transport of radioactive nuclides in this marine environment. Organic carbon flow into the Kara Sea is influenced significantly by terrigenous sources carried by the Ob and Yenisey Rivers. The carbon isotope-organic carbon relationship provides evidence that a rich source of terrigenous carbon exists in the riverine system. A weak, but significant relationship between stable carbon isotope ratio and 137Cs suggests that most of the 137Cs is derived from riverine particles, as compared to Pu which is also derived from in situ scavenging within the water column.  相似文献   

Jupiter: Aerosol Chemistry in the Polar Atmosphere     

Wong AS  Lee AY  Yung YL  Ajello JM 《The Astrophysical journal》2000,534(2):L215-L217

Aromatic compounds have been considered a likely candidate for enhanced aerosol formation in the polar region of Jupiter. We develop a new chemical model for aromatic compounds in the Jovian auroral thermosphere/ionosphere. The model is based on a previous model for hydrocarbon chemistry in the Jovian atmosphere and is constrained by observations from Voyager, Galileo, and the Infrared Space Observatory. Precipitation of energetic electrons provides the major energy source for the production of benzene and other heavier aromatic hydrocarbons. The maximum mixing ratio of benzene in the polar model is 2x10-9, a value that can be compared with the observed value of 2+2-1x10-9 in the north polar auroral region. Sufficient quantities of the higher ring species are produced so that their saturated vapor pressures are exceeded. Condensation of these molecules is expected to lead to aerosol formation.  相似文献   

Monitoring persistent organic pollutants in leatherback turtles (Dermochelys coriacea) confirms maternal transfer     

Stewart KR  Keller JM  Templeton R  Kucklick JR  Johnson C 《Marine pollution bulletin》2011,62(7):1396-1409

To assess threats to endangered species, it is critical to establish baselines for contaminant concentrations that may have detrimental consequences to individuals or populations. We measured contaminants in blubber and fat from dead leatherback turtles and established baselines in blood and eggs in nesting turtles. In fat, blubber, blood and eggs, the predominant PCBs were 153 + 132, 187 + 182, 138 + 163, 118, and 180 + 193. Total PCBs, 4,4′-DDE, total PBDEs and total chlordanes were significantly and positively correlated between blood and eggs, suggesting maternal transfer. Significant positive relationships also existed between fat and blubber in stranded leatherbacks. Less lipophilic PCBs appeared to more readily transfer from females to their eggs. PBDE profiles in the four tissues were similar to other wildlife populations but different from some turtle studies. Concentrations were lower than those shown to have acute toxic effects in other aquatic reptiles, but may have sub-lethal effects on hatchling body condition and health.  相似文献   

The extent and historical trend of metal pollution recorded in core sediments from the artificial Lake Shihwa, Korea   总被引：1，自引：0，他引：1  

Ra K  Bang JH  Lee JM  Kim KT  Kim ES 《Marine pollution bulletin》2011,62(8):1814-1821

The vertical distribution of trace metals in sediment cores was investigated to evaluate the extent and the historical record of metal pollution over 30 years in the artificial Lake Shihwa in Korea. A marked increase of trace metals after 1980 was observed due to the operation of two large industrial complexes and dike construction for a reclamation project. There was a decreasing trend of metal concentrations with the distance from the pollution source. The enrichment factor and pollution load index of the metals indicated that the metal pollution was mainly derived from Cu, Zn and Cd loads due to anthropogenic activities. The concentrations of Cr, Ni, Cu, Zn, As and Pb in the upper part of all core sediments exceeded the ERL criteria of NOAA. Our results indicate that inadequate planning and management of industrialization and a large reclamation project accomplished by dike construction have continued to strongly accelerate metal pollution in Lake Shihwa.  相似文献   

Assessment of phosphogypsum impact on the salt-marshes of the Tinto river (SW Spain): role of natural attenuation processes   总被引：2，自引：0，他引：2  

Pérez-López R  Castillo J  Sarmiento AM  Nieto JM 《Marine pollution bulletin》2011,62(12):2787-2796

About 120 Mton of phosphogypsum from the fertiliser industry were stack-piled on the salt-marshes of the Tinto river (Spain). This paper investigates the capacity of salt-marshes to attenuate contamination due to downward leaching from phosphogypsum. Solids and pore-waters were characterized at different depths of the pile to reach the marsh-ground. In superficial zones, metals were highly mobile, and no reduced sulphur was found. However, pollutant concentration decreased in the pore-water in deeper oxygen-restricted zones. Metal removal occurred by precipitation of newly formed sulphides, being this process main responsible for the contamination attenuation. Pyrite-S was the main sulphide component (up to 2528 mg/kg) and occurred as framboids, leading to high degrees of pyritization (up to 97%). The sulphidization reaction is Fe-limited; however, excess of acid-volatile sulphide over other metals cause precipitation of other sulphides, mainly of Cu and As. This decrease in metal mobility significantly minimises the impact of phosphogypsums on the salt-marshes.  相似文献