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41.
In light of recent studies that show oxygen isotope fractionation in carbonate minerals to be a function of HCO3 and CO32− concentrations, the oxygen isotope fractionation and exchange between water and components of the carbonic acid system (HCO3, CO32−, and CO2(aq)) were investigated at 15°, 25°, and 40°C. To investigate oxygen isotope exchange between HCO3, CO32−, and H2O, NaHCO3 solutions were prepared and the pH was adjusted over a range of 2 to 12 by the addition of small amounts of HCl or NaOH. After thermal, chemical, and isotopic equilibrium was attained, BaCl2 was added to the NaHCO3 solutions. This resulted in immediate BaCO3 precipitation; thus, recording the isotopic composition of the dissolved inorganic carbon (DIC). Data from experiments at 15°, 25°, and 40°C (1 atm) show that the oxygen isotope fractionation between HCO3 and H2O as a function of temperature is governed by the equation:
  相似文献   
42.
High frequency wind and temperature measurements, obtained in March 1995 from a 10-m tower array situated in south-east Kansas, are used to analyze the structure of a shallow density current. This current is approximately 7 m deep and exhibits a current head that is estimated to be about twice the current depth. The event lasted approximately 900 s and its origin appears to be a shallow slope 2–:5 km to the west of the site, where cold air drainage occurs. The onset of the event is marked by a 5 °C temperature decrease at the 3-m level, increased variance of temperature and of wind velocity, and increased dissipation of kinetic energy, measured by a hot-wire anemometer at the 3-m level. The primary contributors to temperature changes following the frontal passage are both horizontal and vertical advections; contributions from flux divergences of temperature and of radiation, and from dew formation, do not appear to be significant. Postulated frontogenesis, prior to the arrival of the apparent equilibrated front of approximately 176-m width at the site, is examined by means of a theoretical model. The time required to equilibrate the front, by means of kinetic energy dissipation within the frontal zone, is determined to be less than 300 s, or less than the estimated travel time from the orographic slope to the observational site. The absence of upstream data is determined, however, to be a limitation of the analysis performed.  相似文献   
43.
The South African midwater trawl fishery targets adult horse mackerel Trachurus capensis. The bulk of the catch is taken by a single freezer-trawler, the biggest fishing vessel operating in South African waters. As fishing takes place off the south coast in ecologically sensitive areas, there are concerns about the potential impacts of this fishing operation on non-target species. Fishing behaviour and bycatch of this fishery from 2004 to 2014 were investigated by analysing observer records with regard to catch composition, volume and temporal and spatial patterns. The midwater trawl fishery was estimated to have caught 25 415 tonnes annually, with a bycatch of 6.9% of the total catch, by weight. There are species overlaps with various fisheries, namely the demersal trawl, small-pelagic, line, shark longline and squid fisheries, yet the total bycatch estimates from this fishery are generally small relative to catches taken in the target fisheries. Bycatch species with the highest average annual catches were chub mackerel Scomber japonicus, redeye roundherring Etrumeus whiteheadi, ribbonfish Lepidopus caudatus and hake Merluccius spp. Large-fauna bycatch species included sunfish Mola mola as well as a number of CITES II- and IUCN-listed species, such as Cape fur seal Arctocephalus pusillus, dusky shark Carcharhinus obscurus, smooth hammerhead shark Sphyrna zygaena and thresher sharks Alopias spp. The 97.9% observer coverage is high and the 6.9% bycatch rate low compared to other South African fisheries; however, due to the large size of the individual hauls (average of 46.3 t), the average sampling rate of 1.56% is low. Our analyses suggest that bycatch in the South African midwater trawl fishery has been lower than in other South African fisheries and similar fisheries elsewhere, but due to the combination of high catch volumes and low sampling rates, estimation errors for rare species are high and there is a substantial risk of incidental unmonitored bycatch of rare large fauna and aggregations of small fauna. This could be mitigated by spatio-temporal management of this fishery, to avoid fishing in high-risk areas, and the introduction of an electronic monitoring programme.  相似文献   
44.
Private industry, the Government of Gabon and two international NGOs collaborated to conduct marine surveys off the coast of Gabon, Central Africa. Surveys addressed multiple objectives of surveillance and monitoring, the documentation of the distribution of and threats to the marine megafauna, and capacity-building among government agents and local early-career scientists. During 22 days of survey effort over a two-year period, observers documented humpback whales Megaptera novaeangliae, bottlenose dolphins Tursiops truncatus, Atlantic humpback dolphins Sousa teuszii and common dolphins Delphinus delphis. Humpback whale presence was limited to the months of July to November. Bottlenose dolphins were present year-round and photo-identification of individuals indicated a closed, resident population, with an abundance estimate of 118 (CV = 21.6%, 95% CI 78–180). Small open-decked fishing vessels with gillnets were observed concentrated around river mouths within 2 km of shore, while commercial trawlers were at least 10 km offshore; all were confirmed to be registered and legal. Observations of marine turtles, flocks of marine birds, and floating logs and other debris were sparse. This multi-stakeholder collaboration to conduct a marine survey can serve as an effective model by which funding and logistic support from private industry paired with technical expertise from NGOs and academic institutions can benefit marine and coastal conservation.  相似文献   
45.
Many least-wealthy, rural, remote and resource-poor small island communities are unlikely to benefit from high-profile global water improvement initiatives. Their small landmasses, geologic composition, geography, social and technological isolation, colonial history, and weak educational and financial resources constitute significant barriers to improving access to safe drinking water. This paper discusses the relatively unique position of such island societies in the international community, providing a case study of the Federated States of Micronesia that integrates data and information pertaining to water resources management and governance, spanning from the island village to national scale. A vision is offered regarding the interaction between small island human and biophysical water systems, manifesting ways to pursue water resource development to improve public health which are constructed to be economically, physically and culturally sustainable.  相似文献   
46.
The basement of the Philippine Mobile Belt (PMB) is mainly composed of ophiolites that are mostly overlain by Paleogene to Miocene turbidites in central Luzon. To clarify the geological development of the PMB with respect to the initial stage of the arc volcanism (eg. Yumul et al., 2003, 2008; Dimalanta and Yumul, 2003; Suzuki et al., 2011), radiolarian dating was examined in siliceous sediments associated with the ophiolites and turbidites. The samples were collected from sites identified with the Zambales and Montalban ophiolites, basic tuff phyllites in NW Din-galan, and their overlying formations.  相似文献   
47.
Abstract Volcanism in the back-arc side region of Central Luzon, Philippines, with respect to the Manila Trench is characterized by fewer and smaller volume volcanic centers compared to the adjacent forearc side-main volcanic arc igneous rocks. The back-arc side volcanic rocks which include basalts, basaltic andesites, andesites and dacites also contain more hydrous minerals (ie, hornblende and biotite). Adakite-like geochemical characteristics of these back-arc lavas, including elevated Sr, depleted heavy rare earth elements and high Sr/Y ratios, are unlikely to have formed by slab melting, be related to incipient subduction, slab window magmatism or plagioclase accumulation. Field and geochemical evidence show that these adakitic lavas were most probably formed by the partial melting of a garnet-bearing amphibolitic lower crust. Adakitic lavas are not necessarily arc–trench gap region slab melts.  相似文献   
48.
Abstract The basement complex of Bohol Island consists of the Southeast Bohol Ophiolite Complex (SEBOC), Cansiwang Melange and Alicia Schist. The SEBOC is a complete, but dismembered ophiolite with outcrops generally trending northeast– southwest and dipping north-west. The harzburgite units of the SEBOC are almost always observed to be thrusted onto the Cansiwang Melange, which in turn is thrusted onto the Alicia Schist. Bouguer gravity values on Bohol range from about +60 mGal in the west to +120 mGal in the east, in the region to the north-east of the SEBOC outcrops. Based on the present distribution of the SEBOC units and their thrust fault relationship with the Cansiwang Melange and Alicia Schist, it is proposed that the SEBOC was emplaced by onramping towards the south-eastward direction. However, the orientation of the Bouguer highs suggests that the thrusting direction of the ophiolite units is towards the south-west and not towards the south-east.  相似文献   
49.
Abstract Amphibolites unconformably overlain by a metasedimentary sequence of quartz-muscovite-feldspar-kyanite schists, metagraywackes and epidote-bearing amphibolites occur in the northern portion of the south-western Zamboanga metamorphic basement complex, western Mindanao. These amphibolites (here identified as the Mount Dansalan amphibolites) display relict magmatic textures inherited from cumulate gabbro protoliths. Bulk-rock major and trace-element data are consistent with this hypothesis. Together with the chemistry of relict igneous clinopyroxenes, they indicate a magmatic arc-related signature for the gabbro protoliths. Geochemical data allow us to identify various sources for the associated metasediments: the gabbro themselves for the metagraywackes and a continental basement for the quartz-muscovite-feldspar-kyanite schists. Both sources contributed to the genesis of the epidote-amphibolite metasediments. The compositions of the metamorphic mineral assemblages suggest that the rocks have undergone metamorphism at temperatures ranging from 550°C to 700°C and pressures probably in the range of 5–9 kbar. 40K–40Ar isotopic study of amphibole separates from the Mount Dansalan samples document a metamorphic event dated at 24.6 ± 1.4, 22.2 ± 1.4 and 21.2 ± 1.2 Ma. Our results are in agreement with plate tectonic models which describe the south-western Zamboanga metamorphic basement as a continental terrane. However, its evolution was not as simple as it was usually considered. In particular the basement incorporated slivers of magmatic arc crust, which cannot be unambiguously related to any of the Tertiary arcs documented in the area.  相似文献   
50.
Abstract— Watson, which was found in 1972 in South Australia, contains the largest single silicate rock mass seen in any known iron meteorite. A comprehensive study has been completed on this unusual meteorite: petrography, metallography, analyses of the silicate inclusion (whole rock chemical analysis, INAA, RNAA, noble gases, and oxygen isotope analysis) and mineral compositions (by electron microprobe and ion microprobe). The whole rock has a composition of an H-chondrite minus the normal H-group metal and troilite content. The oxygen isotope composition is that of the silicates in the HE iron meteorites and lies along an oxygen isotope fractionation line with the H-group chondrites. Trace elements in the metal confirm Watson is a new HE iron. Whole rock Watson silicate shows an enrichment in K and P (each ~2X H-chondrites). The silicate inclusion has a highly equilibrated igneous (peridotite-like) texture with olivine largely poikilitic within low-Ca pyroxene: olivine (Fa20), opx (Fs17Wo3), capx (Fs9Wo41) (with very fine exsolution lamellae), antiperthite feldspar (An1–Or5) with <1 μm exsolution lamellae (An1–3Or>40), shocked feldspar with altered stoichiometry, minor whitlockite (also a poorly characterized interstitial phosphate-rich phase) and chromite, and only traces of metal and troilite. The individual silicate minerals have normal chondritic REE patterns, but whitlockite has a remarkable REE pattern. It is very enriched in light REE (La is 720X C1, and Lu is 90X C1, as opposed to usual chonditic values of ~300X and 100–150X, respectively) with a negative Eu anomaly. The enrichment of whole rock K is expressed both in an unusually high mean modal Or content of the feldspar, Or13, and in the presence of antiperthite. Whole rock trace element data for the silicate mass support the petrography. Watson silicate was an H-chondrite engulfed by metal and melted at > 1550 °C. A flat refractory lithophile and flat REE pattern (at ~1x average H-chondrites) indicate that melting took place in a relatively closed system. Immiscible metal and sulfide were occluded into the surrounding metal host. Below 1100 °C, the average cooling rate is estimated to have been ~1000 °C/Ma; Widmanstätten structure formed, any igneous zoning in the silicates was equilibrated, and feldspar and pyroxene exsolution took place. Cooling to below 300 °C was completed by 3.5 Ga B. P. At 8 Ma, a shock event took place causing some severe metal deformation and forming local melt pockets of schreibersite/metal. This event likely caused the release of Watson into interplanetary space. The time of this event, 8Ma, corresponds to the peak frequency of exposure ages of the H-chondrites. This further confirms the link between HE irons and the H-chondrites, a relationship already indicated by their common oxygen isotope source. Watson metal structures are very similar to those in Kodaikanal. Watson, Kodaikanal and Netschaëvo form the young group of HE meteorites (ages 3.7 ± 0.2 Ga). They appear to represent steps in a chain of events that must have taken place repeatedly on the HE parent body or bodies from which they came: chondrite engulfed in metal (Netschaëvo); chondrite melted within metal (Watson); and finally melted silicate undergoing strong fractionation with the fractionated material emplaced as globules within metal (Kodaikanal). Watson fills an important gap in understanding the sequence of events that took place in the evolution of the IIE-H parent body(ies). This association of H-chondrite with HE metal suggests a surface, or near surface process-a suggestion made by several other researchers.  相似文献   
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