Investigation of high-level glaciofluvial terraces and re-evaluation of the established soil stratigraphy for Early and Middle Pleistocene surfaces, central Yukon, Canada     

CRYSTAL A. HUSCROFT  BRENT C. WARD  LIONEL E. JACKSON JR.  CHARLES E. TARNOCAI 《Boreas: An International Journal of Quaternary Research》2006,35(1):96-105

Palaeosols developed on the highest Yukon River glaciofluvial terraces were investigated in order to reconstruct the Plio-Pleistocene evolution of the river valley beyond Late Pleistocene glacial limits. A record of at least two pre-Reid (> 311 kyr) glaciations is chronicled by the presence of two populations of glaciofluvial terraces within the study area. The populations of pre-Reid terraces were identified based on their degree of soil development and elevation. Pre-Reid terraces 200–250 m above river level have preserved morphological and mineralogical features of the Wounded Moose palaeosol, a palaeosol previously associated with pre-Reid surfaces in central Yukon. Clay mineralogy and colour indicate that the Wounded Moose palaeosol developed in part during warm and sub-humid as well as temperate and humid interglacials. A second set of pre-Reid terraces between 110 and 30 m above river level are characterized by the presence of the less-developed Diversion Creek palaeosol, a palaeosol previously associated with only Reid-aged (< 311 kyr) surfaces in central Yukon. In contrast to the Wounded Moose palaeosol, the Diversion Creek palaeosol developed during comparatively cool and humid interglacial conditions. The presence of Diversion Creek palaeosols on pre-Reid outwash terraces suggests that a transition from dominantly warmer to cooler interglacial conditions occurred prior to 311 kyr in Yukon Territory. In addition, the presence of a Diversion Creek palaeosol cannot be used to differentiate stable Reid and stable pre-Reid surfaces across central Yukon.  相似文献   

Zoned chondrules in Semarkona: Evidence for high‐ and low‐temperature processing     

Jeffrey N. Grossman  Conel M. O'D. Alexanders  Jianhua Wang  Adrian J. Brearley 《Meteoritics & planetary science》2002,37(1):49-73

Abstract— At least 15% of the low‐FeO chondrules in Semarkona (LL3.0) have mesostases that are concentrically zoned in Na, with enrichments near the outer margins. We have studied zoned chondrules using electron microprobe methods (x‐ray mapping plus quantitative analysis), ion microprobe analysis for trace elements and hydrogen isotopes, cathodoluminescence imaging, and transmission electron microscopy in order to determine what these objects can tell us about the environment in which chondrules formed and evolved. Mesostases in these chondrules are strongly zoned in all moderately volatile elements and H (interpreted as water). Calcium is depleted in areas of volatile enrichment. Titanium and Cr generally decrease toward the chondrule surfaces, whereas Al and Si may either increase or decrease, generally in opposite directions to one another; Mn follows Na in some chondrules but not in others; Fe and Mg are unzoned. D/H ratios increase in the water‐rich areas of zoned chondrules. Mesostasis shows cathodoluminescence zoning in most zoned chondrules, with the brightest yellow color near the outside. Mesostasis in zoned chondrules appears to be glassy, with no evidence for devitrification. Systematic variations in zoning patterns among pyroxene‐ and olivine‐rich chondrules may indicate that fractionation of low‐ and high‐Ca pyroxene played some role in Ti, Cr, Mn, Si, Al, and some Ca zoning. But direct condensation of elements into hot chondrules, secondary melting of late condensates into the outer portions of chondrules, and subsolidus diffusion of elements into warm chondrules cannot account for the sub‐parallel zoning profiles of many elements, the presence of H₂O, or elemental abundance patterns. Zoning of moderately volatile elements and Ca may have been produced by hydration of chondrule glass without devitrification during aqueous alteration on the parent asteroid. This could have induced structural changes in the glass allowing rapid diffusion and exchange of elements between altered glass and surrounding matrix and rim material. Calcium was mainly lost during this process, and other nonvolatile elements may have been mobile as well. Some unzoned, low‐FeO chondrules appear to have fully altered mesostasis.  相似文献   

The fall,recovery, and classification of the Park Forest meteorite     

S. B. Simon  L. Grossman  R. N. Clayton  T. K. Mayeda  J. R. Schwade  P. P. Sipiera  J. F. Wacker  M. Wadhwa 《Meteoritics & planetary science》2004,39(4):625-634

Abstract— On the night of March 26, 2003, a large meteorite broke up and fell upon the south suburbs of Chicago. The name Park Forest, for the village that is at the center of the strewnfield, has been approved by the nomenclature committee of the Meteoritical Society. Satellite data indicate that the bolide traveled from the southwest toward the northeast. The strewnfield has a southeast‐northwest trend; however, this is probably due to the effects of strong westerly winds at high altitudes. Its very low ⁵⁶Co and very high ⁶⁰Co activities indicate that Park Forest had a preatmospheric mass that was at least ～900 kg and could have been as large as ～7 times 10³ kg, of which only ～30 kg have been recovered. The average compositions of olivine and low‐Ca pyroxene, Fa_{24.7 ± 1.1} and Fs_{20.8 ± 0.7}, respectively, and its bulk oxygen isotopic composition, δ¹⁸O = +4.68%o, δ¹⁷O = +3.44%o, show that Park Forest is an L chondrite. The ferromagnesian minerals are well equilibrated, chondrules are easily recognized, and maskelynite is mostly ≤50 μm across. Based on these observations, we classify Park Forest as type 5. The meteorite has been strongly shocked, and based on the presence of maskelynite, mosaicism and planar deformation features in olivine, undulatory extinction in pyroxene, and glassy veins, the shock stage is S5. The meteorite is a monomict breccia, consisting of light‐colored, angular to rounded clasts in a very dark host. The light and dark lithologies have essentially identical mineral and oxygen isotopic compositions. Their striking difference in appearance is due to the presence of a fine, pervasive network of sulfide veins in the dark lithology, resulting in very short optical path lengths. The dark lithology probably formed from the light lithology in an impact that formed a sulfide‐rich melt and injected it into cracks.  相似文献   

Valence of titanium and vanadium in pyroxene in refractory inclusion interiors and rims   总被引：2，自引：0，他引：2  

S.B. Simon  S.R. Sutton  L. Grossman 《Geochimica et cosmochimica acta》2007,71(12):3098-3118

The clinopyroxene in coarse-grained refractory inclusions contains significant amounts of Ti and V, two elements that are multivalent over the range of temperatures and oxygen fugacities under which the inclusions formed. The Ti³⁺/Ti⁴⁺ ratios and the valence of V of these pyroxenes are valuable recorders of nebular conditions. The former can be calculated stoichiometrically from electron probe analyses, but only for relatively Ti-rich grains (i.e., >∼4 wt% ). For Ti-poor pyroxene, and for measurement of V valence, another technique is needed. We have, for the first time, applied K-edge X-ray absorption near edge structure (XANES) spectroscopy to the measurement of Ti and V valence in meteoritic clinopyroxene in refractory inclusions. Use of MicroXANES, a microbeam technique with high (μm-scale) spatial resolution, allowed measurement of Ti and V valence along traverses across (a) Ti-, V-rich “spikes” in pyroxene in Type B1 inclusions; (b) typical grains in a Type B2 inclusion; and (c) the pyroxene layer of the Wark-Lovering rim sequence on the outsides of two inclusions. Measurements of Ti³⁺/(Ti³⁺ + Ti⁴⁺), or Ti³⁺/Ti^tot, by XANES agree with values calculated from electron probe analyses to within ∼0.1, or ∼2σ. The results show that Ti³⁺/Ti^tot increases sharply at the spikes, from 0.46 ± 0.03 to 0.86 ± 0.06, but the V valence, or V²⁺/(V²⁺ + V³⁺), does not change, with V²⁺ ≈ V³⁺. We found that pyroxene in both Types B1 and B2 inclusions has Ti³⁺/Ti^tot and V²⁺/V^tot ratios between 0.4 and 0.7, except for the spikes. These values indicate, to first order, formation at similar, highly reducing oxygen fugacities that are consistent with a solar gas. The pyroxene in the rim on an Allende fluffy Type A coarse-grained refractory inclusion, TS24, has an average Ti³⁺/Ti^tot of 0.51 ± 0.08 and an average V²⁺/V^tot of 0.61 ± 0.06, determined by XANES. These values are within the range of those of pyroxene in the interiors of inclusions, indicating that the rims also formed under highly reducing conditions. Measurements of Ti³⁺/Ti^tot of pyroxene in the rim of a Leoville compact Type A inclusion, 144A, by both XANES and electron probe give a wide range of results. Of our 72 XANES analyses of this rim, 66% have Ti³⁺/Ti^tot of 0.40-0.71, and the remaining analyses range from 0 to 0.38. In data from Simon et al. [Simon J. I., Young E. D., Russell S. S., Tonui E. K., Dyl K. A., and Manning C. E. (2005) A short timescale for changing oxygen fugacity in the solar nebula revealed by high-resolution ²⁶Al-²⁶Mg dating of CAI rims. Earth Planet. Sci. Lett.238, 272-283.] for this sample, 7 electron probe analyses yield calculated Ti³⁺/Ti^tot values that are positive and 15 do not. In the probe analyses that have no calculated Ti³⁺, Ca contents are anticorrelated and Al contents directly correlated with the total cations per 6 oxygens, and the data fall along trends calculated for addition of 1-7% spinel to pyroxene. It appears likely that electron probe analyses of pure pyroxene spots have Ti³⁺/Ti^tot values that are typical of refractory inclusions, in agreement with the majority of the XANES results. The average of the XANES data for 144A, 0.41 ± 0.14, is within error of that for TS24. The rim of 144A probably formed under reducing conditions like those expected for a solar gas, and was later heterogeneously altered, resulting in an uneven distribution of secondary, FeO-, Ti-bearing alteration products in the rim, and accounting for the measurements with low Ti³⁺/Ti^tot values.  相似文献   

Implementing Europe's climate targets at the regional level     

Brigitte Wolkinger  Andrea Damm  Stefan Schleicher  Andreas Tuerk  Wolf Grossman 《Climate Policy》2013,13(6):667-689

Having agreed upon a binding emissions reduction path by 2020, the EU plays a leading role in international climate policy. The EU currently pursues a dual approach through an Emissions Trading Scheme (ETS) at the EU level and also via national targets in sectors not covered by the ETS. The latter include the buildings sector, transportation, agriculture, and waste. Emissions from these sectors are mainly subject to policies at provincial and local levels. A method is presented for elaborating and implementing a long-term climate policy process up to 2030 for the regional (provincial) level. Building on regional GHG inventory data, a set of indicators for each sector is developed in order to arrive at a target path consistent with the deduced regional GHG reduction requirement. Policy measures and their implementation are then settled subsequent to this process. Quantitative regional targets are found to be a prerequisite for the formation of regional climate policy as they increase participant responsibility and commitment. A five-step process of stakeholder participation ensures effective implementation of regional climate action plans. Insights from an exemplary European region are drawn upon, and policy issues are discussed in both quantitative and institutional terms.  相似文献   

XANES and Mg isotopic analyses of spinels in Ca‐Al‐rich inclusions: Evidence for formation under oxidizing conditions     

J. M. Paque  S. R. Sutton  S. B. Simon  J. R. Beckett  D. S. Burnett  L. Grossman  H. Yurimoto  S. Itoh  H. C. Connolly Jr. 《Meteoritics & planetary science》2013,48(10):2015-2043

Ti valence measurements in MgAl₂O₄ spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti⁺⁴. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti⁺³‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti⁺⁴‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ²⁵Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ²⁵Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ²⁵Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti⁺⁴ concentrations in spinel.  相似文献   

An (U‐Th)/He age for the shallow‐marine Wetumpka impact structure,Alabama, USA     

Jo‐Anne WARTHO  Matthijs C. VAN SOEST  David T. KING JR.  Lucille W. PETRUNY 《Meteoritics & planetary science》2012,47(8):1243-1255

Abstract– Single crystal (U‐Th)/He dating was applied to 24 apatite and 23 zircon grains from the Wetumpka impact structure, Alabama, USA. This small approximately 5–7.6 km impact crater was formed in a shallow marine environment, with no known preserved impact melt, thus offering a challenge to common geochronological techniques. A mean (U‐Th)/He apatite and zircon age of 84.4 ± 1.4 Ma (2σ) was obtained, which is within error of the previously estimated Late Cretaceous impact age of approximately 83.5 Ma. In addition, helium diffusion modeling of apatite and zircon grains during fireball/contact, shock metamorphism, and hydrothermal events was undertaken, to show the influence of these individual thermal processes on resetting (U‐Th)/He ages in the Wetumpka samples. This study has shown that the (U‐Th)/He geochronological technique has real potential for dating impact structures, especially smaller and eroded impact structures that lack impact melt lithologies.  相似文献   

MIT's Computer Resource Lab:     

LYNA L. WIGGINS  JOSEPH FERREIRA JR. 《International journal of geographical information science》2013,27(4):299-307

Abstract

The paper describes the curriculum on geographic information systems developed in the Department of Planning at the Massachusetts Institute of Technology for those studying for the Master in City Planning degree. Particular emphasis is given to the part played by the Computer Resources Lab in serving the needs of the architecture and planning departments, the interactions between teaching and research, and those between the course and professional practice. The required courses are outlined and the wide range of recommended courses, drawn from a number of departments in the Institute, are listed- The authors emphasize the necessity of their being at the forefront of research if they are lo maintain the flow of hardware and software from contacts and donations on which their research and teaching depend.  相似文献   

Comparison of the structure and accuracy of two land change models     

Robert Gilmore Pontius JR  Jeffrey Malanson 《International journal of geographical information science》2013,27(6):745-748

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菲律宾Zambales蛇绿岩套的再研究：对其特提斯来源的启示     

Karlo L. QUEA?O  Carla B. DIMALANTA  Graciano P. YUMUL JR.  Decibel V. FAUSTINO-ESLAVA  Edanjarlo J. MARQUEZ  Noelynna T. RAMOS  Keisuke ISHIDA  Shigeyuki SUZUKI  Ricky C. SALAPARE  Michael Peter M. SANCHEZ  Juan Miguel R. GUOTANA  Rose Ann B. CONCEPCION 《地球学报》2012,33(S1):58-58

A number of geological studies have already been conducted on the Zambales Ophiolite Complex (ZOC), a north-south trending complete ophiolite sequence exposed in the western portion of Central Luzon, Philippines. Previous works recognized the ZOC as being made up of two blocks, the Acoje and the Coto, acting as an arc-back arc pair sometime during the Eocene.  相似文献