Predicting copper toxicity in estuarine and marine waters using the Biotic Ligand Model   总被引：6，自引：0，他引：6  

Arnold WR  Santore RC  Cotsifas JS 《Marine pollution bulletin》2005,50(12):1634-1640

The Biotic Ligand Model (BLM) has proven efficient in predicting the toxicity of a variety of metals to freshwater organisms. Consequently, the US EPA has proposed its use for calculating freshwater copper criteria. This study evaluates the BLM for use in estuarine and marine waters. Studies were conducted using the bivalve, Mytilus sp. and 48-h embryo-larval development chronic estimator test methods. These are the most sensitive taxa and test in the US EPA saltwater copper criteria database. Samples from five locations around the USA were tested. There is a strong relationship between measured and BLM predicted copper EC50s (log transformed data, r² = 0.76, p < 0.001, n = 44). The BLM predicted within a factor ±2 of measured EC50s in 41 of 44 cases. However, the BLM tends to predict lower EC50s when measured EC50s are approximately 10 μg Cu/L. This may be due to limitations of the metal-dissolved organic matter interaction model.  相似文献   

Studies of a contaminated brackish marsh in the Hackensack Meadowlands of Northeastern New Jersey: benthic communities and metal contamination     

Weis JS  Skurnick J  Weis P 《Marine pollution bulletin》2004,49(11-12):1025-1035

Cores taken from 16 stations within Eight Day Swamp, a highly contaminated marsh in the Hackensack Meadowlands, were analyzed for metal concentrations and for benthic community structure. Metal levels were compared with the benchmark ERM values, and expressed in terms of toxic units. Mercury was the most important metal in all the samples in terms of its contribution to the total toxic units. The overall abundance and taxa richness in the benthic community were associated with the height of the location relative to the tidal cycle, but were generally not significantly correlated with metal concentrations at the sites. Ordination of the communities showed that the communities that were low-lying (on the mudflat) were most similar to one another, and those that were higher up on the marsh were most similar to one another. However, diversity indices (Shannon-Wiener H' and Simpson's) were significantly associated with concentrations of the metals (except As) and with the sum of the toxic units at a station.  相似文献   

Massive sedimentation of fine sediment with organic matter and enhanced benthic-pelagic coupling by an artificial dyke in semi-enclosed Chonsu Bay, Korea     

Lee JS  Kim KH  Shim J  Han JH  Choi YH  Khang BJ 《Marine pollution bulletin》2012,64(1):153-163

To assess the impact of an artificial dyke in Chonsu Bay (CBD) on the organic carbon (C(org)) cycle, we measured excess (210)Pb activities, C(org) and nitrogen content in sediment cores. The C(org) oxidation rates (C(ox)) on the surface sediment and benthic nutrient fluxes were also quantified with an in situ benthic chamber. The higher excess (210)Pb inventory, C(org) and nitrogen in cores near the CBD indicated lateral transport and local, massive deposition of particulate matter due to tidal circulation altered by artificial dyke construction. The C(ox) in sediment near the CBD was about twice as high as that out of the bay, suggesting the importance of benthic remineralization of organic matter. The benthic fluxes of dissolved inorganic nitrogen and phosphate were four to six times higher than those outside the bay, corresponding to 141% and 131% respectively, of the requirements for primary production.  相似文献   

Trace metals in seawater and copepods in the ocean outfall area off the northern Taiwan coast   总被引：3，自引：0，他引：3  

Fang TH  Hwang JS  Hsiao SH  Chen HY 《Marine environmental research》2006,61(2):224-243

The distribution, partitioning and concentrations of trace metals (Cd, Cr, Cu, Fe, Mn, Pb and Zn) in seawater, including dissolved and particulate phases, and in copepods in the ocean outfall area off the northern coast of Taiwan were investigated. Normalization of metal concentrations to the background metal concentration to yield relative enrichment factors (EF), which were used to evaluate the contamination of dissolved and particulate trace metals in seawater around the ocean outfall. The EF results indicated that the outfall area was significantly contaminated by dissolved Fe and Zn, and by particulate Fe, Cr, Cu, Pb and Zn. In addition, most trace metals were chiefly in the particulate phase. The average percentage of total metal concentrations (dissolved plus particulate phases) bound by suspended particulate matter followed the sequence Al(95%) = Mn(95%) > Pb(88%) > Cu(86%) > Fe(72%) > Zn(32%) > Cr(17.5%) > Cd(3.4%). Therefore, metal contamination is better evaluated in solid phase than in the dissolved phase. The concentration ranges of trace metals in the copepods, Temora turbinata, Oncaea venusta and Euchaeta rimana, near the outfall were: Cd, 0.23-1.81 microg g(-1); Cr, 16.5-195 microg g(-1); Cu, 14-160 microg g(-1); Fe, 256-7255 microg g(-1); Mn, 5.5-80.8 microg g(-1); Pb, 2.6-56.2 microg g(-1); Zn, 132-3891 microg g(-1); and Al, 0.21-1.13%. Aluminum, and probably Fe, seemed to be the major elements in copepods. The concentrations of trace metals in copepods, especially Temora turbinata, near the outfall were generally higher than those obtained in the background station. The mean increase in bioconcentration factor of metals in copepods ranged from 4 to 7 and followed the sequence Al(6.4) > Cu(6.2) > Fe(6.0) > Zn(5.7) > Pb(5.6) > Cr(5.5) > Cd(5.1) > Mn(4.7). Therefore, marine copepods in the waters of northern Taiwan can accumulate trace metals over background concentrations and act as contamination indicators.  相似文献   

温度对热液玄武岩变化中贱金属活性的影响：兼论脊状热液流体...     

Seew.  JS 徐建力 《华东地质学院学报》1990,13(3):8-11

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地面穿透雷达提高了人们对地表层的认识     

梅.  JS  吴其斌 《国土资源信息化》1992,(4):11-13

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Genomic cloning and expression of vitellogenin gene from the self-fertilizing fish Rivulus marmoratus (Cyprinodontiformes, Rivulidae)     

Kim IC  Chang SY  Williams TD  Ja Kim Y  Yoon YD  Lee YS  Park EH  Lee JS 《Marine environmental research》2004,58(2-5):687-691

We cloned the vitellogenin gene from the self-fertilizing fish Rivulus marmoratus, and sequenced 12,326 bp. The number of exons of R. marmoratus and rainbow trout vitellogenin genes were different, and also the splicing junctions are different throughout most of the exons and introns but the amino acid similarity of R. marmoratus vitellogenin gene to other species was rather high. In promoter region of R. marmoratus vitellogenin gene, there were several E2 binding sites and the estrogen response element (ERE). We discuss here the gene structure and expression of R. marmoratus vitellogenin gene.  相似文献   

Evaluating prey capture by larval mummichogs (Fundulus heteroclitus) as a potential biomarker for contaminants     

Weis JS  Samson J  Zhou T  Skurnick J  Weis P 《Marine environmental research》2003,55(1):27-38

We evaluated larval prey capture as a "behavioral biomarker" of contamination by examining feeding behavior of larval mummichogs (Fundulus heteroclitus) from many different sites, including a severely contaminated "Superfund" site, moderately contaminated sites, and reference areas. Prey capture ability was related to sediment contaminant levels. The levels of contaminants at a site were highly correlated with each other, so that the impact of individual contaminants was confounded. The number of captures of brine shrimp by mummichog larvae from all sites was highly variable, but significant negative correlations of prey capture were seen with mercury, lead, zinc, cadmium, and PCBs. As observed previously with adults, polyaromatic hydrocarbons (PAHs) did not appear to impair prey capture ability. The only site in which prey capture rates of 8-day old larvae were severely affected was the most highly contaminated Superfund site, Berry's Creek, NJ. This implies that larval prey capture is not as sensitive a behavioral biomarker for contamination as adult behavior studied previously.  相似文献   

The impact of oil-derived products on the behaviour and biochemistry of the eleven-armed asteroid Coscinasterias muricata (Echinodermata)   总被引：1，自引：0，他引：1  

Georgiades ET  Holdway DA  Brennan SE  Butty JS  Temara A 《Marine environmental research》2003,55(3):257-276

The present study examines the impact of exposure to oil-derived products on the behaviour and physiology of the Australian 11-armed asteroid Coscinasterias muricata. Asteroids were exposed to dilutions of water-accommodated fraction (WAF) of Bass Strait stabilised crude oil, dispersed oil or burnt oil (n = 8) for 4 days whereby, prey-localisation behaviour was examined immediately after exposure, and following 2, 7, and 14 days depuration in clean seawater. The prey-localisation behaviour of asteroids exposed to WAF and dispersed oil was significantly affected though recovery was apparent following 7 and 14 days depuration, respectively. In contrast, there was no significant change in the prey-localisation behaviour of asteroids exposed to burnt oil. Behavioural impacts were correlated with the total petroleum hydrocarbon concentrations (C6-C36) in each exposure solution, WAF (1.8 mg l(-1)), dispersed oil (3.5 mg l(-1)) and burnt oil (1.14 mg l(-1), respectively. The total microsomal cytochrome P450 content was significantly lower (P(Dunnett test) < 0.01) in asteroids exposed to dispersed oil than in any other asteroids, whilst asteroid alkaline phosphatase activity was not significantly affected (P(ANOVA) = 0.11). This study further documents the deleterious impact of dispersed oil to marine organisms and supports further research in the area of in situ burning as a less damaging oil spill response measure towards benthic macro-invertebrates.  相似文献   

基于数字高程模型的公路勘察设计     

周薇  戴一鸣  张兴国 《国土资源导刊(湖南)》2007,4(4):50-51,52

根据公路勘测设计的特点,阐述了数字高程模型(DEM)的概念和特点以及数字高程模型的建模方式,讨论了适应于公路勘查设计的数字高程模型数据采集方法等问题,总结了数字高程模型在公路勘察设计中的应用。  相似文献