Laboratory sulfurisation of the marine microalga Nannochloropsis salina     

Francois Gelin  Marika D. Kok  Jan W. de Leeuw  Jaap S. Sinninghe Damst 《Organic Geochemistry》1998,29(8):1837-1848

To understand more fully the mode of preservation of organic matter in marine sediments, laboratory sulfurisation of intact cells of the cultured microalga Nannochloropsis salina was performed using inorganic polysulfides in seawater at 50°C. Solvent extractable and non-extractable materials were analysed by GC–MS and Py–GC–MS, respectively, to study the incorporation of sulfur into the microalgal organic matter. No GC-amenable sulfur-containing compounds were found in the extracts apart from some minor thiophenes with a phytanyl carbon skeleton. The residue after extraction and hydrolysis contained abundant macromolecular sulfur-containing moieties as revealed by the presence of dominant C₂₈–C₃₂ thiols, thiophenes, thianes and thiolanes in the flash pyrolysates. These products are thought to be formed from moieties derived from sulfurisation of C₂₈–C₃₂ diols and alkenols, characteristic lipids of N. salina. C₁–C₂ alkylated thiophenes were also found in the pyrolysates and probably result from moieties formed upon sulfurisation of carbohydrates. The highly resistant biomacromolecule (algaenan) synthesised by N. salina remains unaffected by sulfurisation. The non-hydrolysable residue isolated from the sulfurised N. salina thus comprises algaenan and (poly)sulfide-bound long alkyl chains. The sulfurisation experiments show that both selective preservation of algaenans and lipid and carbohydrate “vulcanisation” can be involved in the preservation of algal organic matter in marine environments.  相似文献   

Constraints on the application of the MBT/CBT palaeothermometer at high latitude environments (Svalbard,Norway)     

Francien Peterse  Jung-Hyun Kim  Stefan Schouten  Dorthe Klitgaard Kristensen  Nalân Koç  Jaap S. Sinninghe Damsté 《Organic Geochemistry》2009,40(6):692-699

Branched glycerol dialkyl glycerol tetraethers (GDGTs) are membrane lipids of unknown bacteria that are ubiquitous in soil and peat. Two indices based on the distribution of these lipids in soils, the Cyclization of Branched Tetraethers (CBT) and the Methylation of Branched Tetraethers (MBT) indices have been shown to correlate with soil pH, and mean annual air temperature (MAT) and soil pH, respectively, and can be used to reconstruct MAT in palaeoenvironments. To verify the extent to which branched GDGTs in marine sediments reflect the distribution pattern on land and whether these proxies are applicable for palaeoclimate reconstruction in high latitude environments with a MAT of <0 °C, we compared the branched GDGT distribution in Svalbard soils and nearby fjord sediments. Although branched GDGT concentrations in the soil are relatively low (0.02–0.95 μg/g dry weight (dw)) because of the cold climate and the short growing season, reconstructed MATs based on the MBT/CBT proxy are ca. ?4 °C, close to the measured MAT (ca. ?6 °C). Concentrations of branched GDGTs (0.01–0.20 μg/g dw) in fjord sediments increased towards the open ocean and the distribution was strikingly different from that in soil, i.e. dominated by GDGTs with one cyclopentane moiety. This resulted in MBT/CBT-reconstructed MAT values of 11–19 °C, well above measured MAT. The results suggest that at least part of the branched GDGTs in marine sediments in settings with a low soil organic matter (OM) input may be produced in situ. In these cases, the application of the MBT/CBT palaeothermometer will generate unrealistic MAT reconstructions. The MBT/CBT proxy should therefore only be used at sites with a substantial input of soil OM relative to the amount of marine OM, i.e. at sites close to the mouth of rivers with a catchment area where sufficient soil formation takes place and the soil thus contains substantial amounts of branched GDGTs.  相似文献   

A review of EU bio-economic models for fisheries: The value of a diversity of models     

Raúl Prellezo  Paolo AccadiaJesper L. Andersen  Bo S. AndersenErik Buisman  Alyson LittleJ. Rasmus Nielsen  Jan Jaap PoosJeff Powell  Christine Röckmann 《Marine Policy》2012,36(2):423-431

The lessons learned from a review of thirteen existing European bio-economic models used in the evaluation of EU policies are presented. How these models compare and differ in terms of their biological and economic components, the integration between the components, which indicators are selected and how they are used, are described and analysed. The article concludes that the multitude of construction differences reflects the necessity of adapting the modelling approach to answer different questions. Since real life questions in fisheries are so diverse, answering them requires a diversity of models.  相似文献   

Identification and distribution of intact polar branched tetraether lipids in peat and soil   总被引：1，自引：0，他引：1  

Francien Peterse  Ellen C. Hopmans  Stefan Schouten  Anchélique Mets  W. Irene C. Rijpstra  Jaap S. Sinninghe Damsté 《Organic Geochemistry》2011,42(9):1007-1015

Branched glycerol dialkyl glycerol tetraether lipids (GDGTs) are membrane lipids of soil bacteria that occur ubiquitously in soil, but their occurrence as intact polar lipids (IPLs) has not been well studied. Here, we report the identification and distribution of IPL-branched GDGTs throughout a depth profile of a Swedish peat bog. In addition to two reported glycosidic IPL branched GDGTs, we identified IPL branched GDGTs with a hexose-glycuronic acid, phospho-hexose, or hexose-phosphoglycerol head group, based on mass spectrometry. A selected reaction monitoring (SRM) assay was developed to monitor changes in head group distribution with depth. The abundance of the IPL branched GDGTs increased below the water table, suggesting that they were primarily produced in this part of the peat. This was supported by the concentrations of core lipid and IPL-derived branched GDGTs, which also substantially increased below the water table. However, individual IPL trends differed, which may be due to changes in the microbial community composition with depth or to different degradation rates for the different IPL branched GDGTs. The SRM method was also applied to two different soil types, which showed that similar IPL branched GDGTs as those in peat were present, albeit with different distributions.  相似文献   

The geological deformation of sediments     

Jaap J. M. Van Der Meer 《第四纪科学杂志》1996,11(2):171-172

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Micromorphological characteristics of glacimarine sediments: implications for distinguishing genetic processes of massive diamicts     

Aoibheann A. Kilfeather  Colm Ó Cofaigh  Julian A. Dowdeswell  Jaap J. M. van der Meer  David J. A. Evans 《Geo-Marine Letters》2010,30(2):77-97

Glacimarine diamicts are produced by diverse processes, and genetic differentiation is often problematic using macro-sedimentological criteria alone. Micromorphology offers a potentially helpful tool in such investigations. Macroscopically massive diamict samples of known glacimarine origin, from the Polar North Atlantic, Antarctica and north Irish Sea, were prepared for micromorphological analysis to (1) identify microstructures unique to different modes of sedimentation and (2) interpret genetic processes from those structures. The samples comprised examples of debris-flow, iceberg-turbate and suspension settling deposits from late Quaternary glacier-influenced marine environments: tidewater glacier, sub- or pro-ice shelf and continental slopes in front of ice stream termini. Results show two significant features of debris-flow sediments: a bimodal grain fabric of near-horizontal and -vertical grains, and laminated clay and silt coatings on sand and pebble grains. Coatings are best developed in sediments with finer grain-size distributions and in debris-flow sediments which have had relatively long run-out distances on trough-mouth fans, suggesting continuous rotation of grains in a buoyant, turbulent aqueous environment. This is significant because it precludes debris-flow delivery by plug flow. The micromorphology of iceberg turbate has not been described previously. It contains structures similar to those described in tills, so that unambiguous identification of these sediments seems unlikely based on micromorphological criteria alone. Suspension sediments range from fine-grained massive diamicts containing microfossils to more heterogeneous coarser sediments characterised by abrupt textural variations, from ice-distal and ice-proximal glacimarine environments respectively. The ice-proximal sediments contain fine vertical lineations marking the trajectories of dropstones through wet matrix. These dropstone tracks have not been reported in previous studies.  相似文献   

The impact of climate change on the river rhine: A scenario study   总被引：3，自引：0，他引：3  

Jaap Kwadijk  Jan Rotmans 《Climatic change》1995,30(4):397-425

This paper concerns the impact of human-induced global climate change on the River Rhine discharge. For this purpose a model for climate assessment, named ESCAPE, is coupled to a water balance model, named RHINEFLOW. From climate scenarios, changes in regional annual water availability and seasonal discharge in the River Rhine Basin are estimated. The climate scenarios are based on greenhouse gases emissions scenarios. An assessment is made for best guess seasonal discharge changes and for changes in frequencies of low and high discharges in the downstream reaches of the river. In addition, a quantitative estimation of the uncertainties associated with this guess is arrived at.The results show that the extent and range of uncertainty is large with respect to the best guess changes. The uncertainty range is 2–3 times larger for the Business-as-Usual than for the Accelerated Policies scenarios. This large range stems from the doubtful precipitation simulations from the present General Circulation Models. This scenario study showed the precipitation scenarios to be the key-elements within the present range of reliable climate change scenarios.For the River Rhine best guess changes for annual water availability are small according to both scenarios. The river changes from a present combined snow-melt-rain fed river to an almost entirely rain fed river. The difference between present-day large average discharge in winter and the small average discharge in autumn should increase for all scenarios. This trend is largest in the Alpine part of the basin. Here, winter discharges should increase even for scenarios forecasting annual precipitation decreases. Summer discharge should decrease. Best guess scenarios should lead to increased frequencies of both low and high flow events in the downstream (Dutch) part of the river. The results indicate changes could be larger than presently assumed in worst case scenarios used by the Dutch water management authorities.  相似文献   

Dredging for edible cockles (Cerastoderma edule) on intertidal flats: short-term consequences of fisher patch-choice decisions for target and non-target benthic fauna     

Kraan  Casper; Piersma  Theunis; Dekinga  Anne; Koolhaas  Anita; van der Meer  Jaap 《ICES Journal of Marine Science》2007,64(9):1735-1742

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New indices and calibrations derived from the distribution of crenarchaeal isoprenoid tetraether lipids: Implications for past sea surface temperature reconstructions   总被引：3，自引：0，他引：3  

Jung-Hyun Kim  Jaap van der Meer  Peer Helmke  Francesca Sangiorgi  Ellen C. Hopmans 《Geochimica et cosmochimica acta》2010,74(16):4639-4654

Several studies have shown that there is a strong relationship between the distribution of crenarchaeotal isoprenoid glycerol dibiphytanyl glycerol tetraethers (GDGTs) and sea surface temperature (SST). Based on this, a ratio of certain GDGTs, called TEX₈₆ (TetraEther indeX of tetraethers consisting of 86 carbon atoms), was developed as a SST proxy. In this study, we determined the distribution of crenarchaeotal isoprenoid GDGTs in 116 core-top sediments mostly from (sub)polar oceans and combined these data with previously published core-top data. Using this extended global core-top dataset (n = 426), we re-assessed the relationship of crenarchaeal isoprenoid GDGTs with SST. We excluded data from the Red Sea from the global core-top dataset to define new indices and calibration models, as the Red Sea with its elevated salinity appeared to behave differently compared to other parts of the oceans. We tested our new indices and calibration models on three different paleo datasets, representing different temperature ranges. Our results indicate that the crenarchaeol regio-isomer plays a more important role for temperature adaptation in (sub)tropical oceans than in (sub)polar oceans, suggesting that there may be differences in membrane adaptation of the resident crenarchaeotal communities at different temperatures. We, therefore, suggest to apply two different calibration models. For the whole calibration temperature range (−3 to 30 °C), a modified version of TEX₈₆ with a logarithmic function which does not include the crenarchaeol regio-isomer, called , is shown to correlate best with SST: (r² = 0.86, n=396, p <0.0001). Application of on sediments from the subpolar Southern Ocean results in realistic absolute SST estimates and a similar SST trend compared to a diatom SST record from the same core. , which is defined as the logarithmic function of TEX₈₆, yields the best correlation with SST, when the data from the (sub)polar oceans are removed: (r² = 00.87, n = 255, p < 0.0001). Furthermore, gives the best correlation for mescosm data with temperatures ranging between 10 and 46 °C. For Quaternary sediments from the tropical Arabian Sea, both and yield similar trends and SST estimates. However, the extrapolation of calibration on a sediment record from a greenhouse world ocean predicts more reliable absolute SST estimates and relative SST changes in agreement with estimates based on the δ¹⁸O of planktonic foraminifera. Based on the comparison of and derived SSTs using the core top data, we recommend applying above 15 °C and below 15 °C. In cases where paleorecords encompass temperatures both below and above 15 °C, we suggest to use .  相似文献   

Glacial-Geological/Geomorphological Research in West Greenland Used to Test an Ice-Sheet Model     

Frank G. M. van Tatenhove  Jaap J. M. van der Meer  Philippe Huybrechts 《Quaternary Research》1995,44(3)

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