Structural identification of the C₂₅ highly branched isoprenoid pentaene in the marine diatom Rhizosolenia setigera     

Jaap S. Sinninghe Damst  Stefan Schouten  W. Irene C. Rijpstra  Ellen C. Hopmans  Harry Peletier  Winfried W. C. Gieskes  Jan A. J. Geenevasen 《Organic Geochemistry》1999,30(12):918

2,6,10,14-tetramethyl-7-(3-methylpent-4-enyl)-pentadeca-2,5E,9E,13-tetraene I possessing a C₂₅ highly branched isoprenoid skeleton has been isolated from the marine diatom Rhizosolenia setigera and identified by ¹H and ¹³C NMR spectroscopy.  相似文献   

All-cis hentriaconta-9,15,22-triene in microbial mats formed by the phototrophic prokaryote Chloroflexus     

Marcel T. J. van der Meer  Stefan Schouten  David M. Ward  Jan A. J. Geenevasen  Jaap S. Sinninghe Damst 《Organic Geochemistry》1999,30(12):3850

All-cis hentriaconta-9,15,22-triene (I) has been isolated from Chloroflexus mats, Yellowstone National Park (USA), and identified by GC–(HR)MS analysis of I and its hydrogenated and DMDS-derivatized products and by ¹H and ¹³C NMR spectroscopy.  相似文献   

Modelling storm impacts on beaches, dunes and barrier islands   总被引：10，自引：0，他引：10  

Dano Roelvink  Ad Reniers  Ap van Dongeren  Jaap van Thiel de Vries  Robert McCall  Jamie Lescinski 《Coastal Engineering》2009,56(11-12):1133-1152

A new nearshore numerical model approach to assess the natural coastal response during time-varying storm and hurricane conditions, including dune erosion, overwash and breaching, is validated with a series of analytical, laboratory and field test cases. Innovations include a non-stationary wave driver with directional spreading to account for wave-group generated surf and swash motions and an avalanching mechanism providing a smooth and robust solution for slumping of sand during dune erosion. The model performs well in different situations including dune erosion, overwash and breaching with specific emphasis on swash dynamics, avalanching and 2DH effects; these situations are all modelled using a standard set of parameter settings. The results show the importance of infragravity waves in extending the reach of the resolved processes to the dune front. The simple approach to account for slumping of the dune face by avalanching makes the model easily applicable in two dimensions and applying the same settings good results are obtained both for dune erosion and breaching.  相似文献   

Impact of lateral transport on organic proxies in the Southern Ocean     

Jung-Hyun Kim  Xavier Crosta  Stefan Schouten  Jaap S. Sinninghe Damsté 《Quaternary Research》2009,71(2):246-124

Lateral transport of fine-grained organic carbon particles can complicate the interpretation of paleoclimate records based on organic proxies. Here we investigated the effect of lateral transport on newly developed temperature and soil organic matter proxies, TEX₈₆ and BIT index, respectively, in core MD88-769 recovered from the South East Indian Ridge. Our results show that TEX₈₆ and BIT records in comparison to diatom and foraminifera records were representative for more local climate changes while alkenones and n-alkanes originated from distant areas by oceanic and atmospheric transport, respectively. This suggests that TEX₈₆ and BIT paleoclimate records are primarily influenced by local conditions and less subjected to long-distance lateral transport than other organic proxies in the Southern Ocean.  相似文献   

Occurrence and biomarker potential of 23-methyl steroids in diatoms and sediments     

Sebastiaan W. Rampen  Stefan Schouten  Ellen C. Hopmans  Ben Abbas  Anna A.M. Noordeloos  Jan A.J. Geenevasen  J. Michael Moldowan  Peter Denisevich  Jaap S. Sinninghe Damsté 《Organic Geochemistry》2009,40(2):219-228

23-Methyl sterols have been reported to be synthesized by a few marine algae, but unambiguous identification of 23-methyl steroids in sediments and petroleum is lacking. We report the presence of 23-methylcholesta-5,22E-dien-3β-ol in 14 out of 106 diatom cultures, thereby showing that diatoms, together with dinoflagellates, may be an important environmental source for such steroids. Synthesis of authentic 23-methylcholestanes showed that their mass spectra are identical to those of 24-methylcholestanes, but that they elute earlier on apolar stationary phases during gas chromatography (GC) analysis. Co-injection of the authentic standards with sediment extracts revealed the presence of these compounds in the Skole unit of the Oligocene Menelite Formation, the Miocene Monterey Formation and the Messinian Vena del Gesso Formation. In addition, we tentatively identified 23,24-dimethyl-27-norcholestanes in some of these sediments. Molecular clock calculations suggest that diatoms are a possible source for 23-methyl steroids in sediments and petroleum from the late Jurassic onwards.  相似文献   

Effects of long term oxic degradation on the U37K′, TEX86 and BIT organic proxies     

Carme Huguet  Jung-Hyun Kim  Gert J. de Lange  Jaap S. Sinninghe Damsté  Stefan Schouten 《Organic Geochemistry》2009,40(12):1188-1194

One of the primary prerequisites for the application of organic proxies is that they should not be substantially affected by diagenesis. However, studies have shown that oxic degradation of biomarker lipids can affect their relative distribution. We tested the diagenetic stability of the $U_{37}^{K^{\prime }}$ and TEX₈₆ palaeothermometers upon long term oxygen exposure. For this purpose, we studied the distributions of alkenones and glycerol dialkyl glycerol tetraethers (GDGTs) in different sections of turbidites at the Madeira Abyssal Plain (MAP) that experienced different degrees of oxygen exposure. Sediments were deposited anoxically on the shelf and then transported by turbidity currents to the MAP, which has oxic bottom water. This resulted in partial degradation of the turbidite organic matter as a result of long term exposure to oxic bottom water. Concentrations of GDGTs and alkenones were reduced by one to two orders of magnitude in the oxidized parts of the turbidites compared to the unoxidized parts, indicating substantial degradation. High-resolution analysis of the Pleistocene F-turbidite showed that the $U_{37}^{K^{\prime }}$ index of long chain alkenones increased only slightly (0.01, corresponding to <0.5 °C) in the oxidized part of the turbidite, suggesting minor preferential degradation of the C_37:3 alkenone, in agreement with previous studies. TEX₈₆ values showed a small increase (0.02, corresponding to ～2 °C) in the F-turbidite, like $U_{37}^{K^{\prime }}$, while for other Pliocene/Miocene turbidites it either remained unchanged or decreased substantially (up to 0.06, corresponding to ～6 °C). Previous observations showed that the BIT index, a proxy for the contribution of soil organic matter to total organic carbon, was always substantially higher in the oxidized part in all the turbidites, as a result of preferential degradation of marine-derived GDGTs. This relative increase in soil-derived GDGTs affects TEX₈₆, as the isoprenoid GDGT distribution on the continent can be quite different from that in the marine environment. Our results indicate that the organic proxies are affected by long term oxic degradation to different extents; this should be taken into account when applying these proxies in palaeoceanographic studies of sediments which have been exposed to prolonged oxic degradation.  相似文献   

Decoupled warming and monsoon precipitation in East Asia over the last deglaciation     

Francien Peterse  Maarten A. Prins  Christiaan J. Beets  Simon R. Troelstra  Hongbo Zheng  Zhaoyan Gu  Stefan Schouten  Jaap S. Sinninghe Damsté 《Earth and Planetary Science Letters》2011,301(1-2):256-264

Our understanding of the continental climate development in East Asia is mainly based on loess–paleosol sequences and summer monsoon precipitation reconstructions based on oxygen isotopes (δ¹⁸O) of stalagmites from several Chinese caves. Based on these records, it is thought that East Asian Summer Monsoon (EASM) precipitation generally follows Northern Hemisphere (NH) summer insolation. However, not much is known about the magnitude and timing of deglacial warming on the East Asian continent. In this study we reconstruct continental air temperatures for central China covering the last 34,000 yr, based on the distribution of fossil branched tetraether membrane lipids of soil bacteria in a loess–paleosol sequence from the Mangshan loess plateau. The results indicate that air temperature varied in phase with NH summer insolation, and that the onset of deglacial warming at ~ 19 kyr BP is parallel in timing with other continental records from e.g. Antarctica, southern Africa and South-America. The air temperature increased from ~ 15 °C at the onset of the warming to a maximum of ~ 27 °C in the early Holocene (~ 12 kyr BP), in agreement with the temperature increase inferred from e.g. pollen and phytolith data, and permafrost limits in central China.Comparison of the tetraether membrane lipid-derived temperature record with loess–paleosol proxy records and stalagmite δ¹⁸O records shows that the strengthening of EASM precipitation lagged that of deglacial warming by ca. 3 kyr. Moreover, intense soil formation in the loess deposits, caused by substantial increases in summer monsoon precipitation, only started around 12 kyr BP (ca. 7 kyr lag). Our results thus show that the intensification of EASM precipitation unambiguously lagged deglacial warming and NH summer insolation, and may contribute to a better understanding of the mechanisms controlling ice age terminations.  相似文献   

Absence of seasonal patterns in MBT-CBT indices in mid-latitude soils   总被引：1，自引：0，他引：1  

Johan W.H. Weijers  Beth Bernhardt  Francien Peterse  Josef P. Werne  Jennifer A.J. Dungait  Jaap S. Sinninghe Damsté 《Geochimica et cosmochimica acta》2011,75(11):3179-3190

The degree of methylation and cyclization of bacteria-derived branched glycerol dialkyl glycerol tetraether (GDGT) membrane lipids in soils depends on temperature and soil pH. Expressed in the methylation index of branched tetraethers (MBT) and cyclization ratio of branched tetraethers (CBT), these relationships are used to reconstruct past annual mean air temperature (MAT) based on the distribution of branched GDGTs in ancient sediments; the MBT-CBT proxy. Although it was shown that the best correlation of this proxy is with annual MAT, it remains unknown whether a seasonal bias in temperature reconstructions could occur, such as towards a seasonal period of ‘optimal growth’ of the, as yet, unidentified soil bacteria which produce branched GDGTs. To investigate this possibility, soils were sampled from eight different plots in the USA (Minnesota and Ohio), The Netherlands (Texel) and the UK (Devon) in time series over 1 year and analyzed for their branched GDGT content. Further analyses of the branched GDGTs present as core lipids (CLs; the presumed fossil pool) and intact polar lipids (IPLs; the presumed extant pool) were undertaken for two of the investigated soil plots. The amount of IPL-derived branched GDGTs is low relative to the branched GDGT CLs, i.e. only 6-9% of the total branched GDGT pool. In all soils, no clear change was apparent in the distribution of branched GDGT lipids (either core or IPL-derived) with seasonal temperature change; the MBT-CBT temperature proxy gave similar temperature estimates year-round, which generally matched the mean annual soil temperature. In addition to a lack of coherent changes in relative distributions, concentrations of the branched GDGTs did not show clear changes over the seasons. For IPL-derived GDGTs these results suggest that their turnover time in soils is in the order of 1 year or more. Thus, our study does not provide evidence for seasonal effects on the distribution of branched GDGTs in soils, at least at mid-latitudes, and therefore, no direct evidence for a bias of MBT-CBT reconstructed temperatures towards a certain season of optimal growth of the source bacteria. If, however, there is a slight seasonal preference of branched GDGT production, which can easily be obscured by natural variability due to the heterogeneity of soils, then a seasonal bias may potentially still develop over time due to the long turnover time of branched GDGTs.  相似文献   

Variations in abundances and distributions of isoprenoid chromans and long-chain alkylbenzenes in sediments of the Mulhouse Basin: a molecular sedimentary record of palaeosalinity     

Jaap S. Sinninghe Damst  Brendan J. Keely  Susannah E. Betts  Marianne Baas  James R. Maxwell  Jan W. de Leeuw 《Organic Geochemistry》1993,20(8)

The abundances and distribution patterns of mono-, di- and trimethylated 2-methyl-2-(4,8,12-trimethyltridecyl) chromans (MTTCs) and long-chain alkylbenzenes in extracts of marl (66 samples), anhydrite (15) and halite (1) strata of the Salt IV Formation of the Oligocene Mulhouse Basin are reported. The distributions of the methylated MTTCs indicate salinity changes of the upper part of a density stratified water column of the basin. These variations are explained by a tectonically or climatically induced change in the supply of water of relative lower salinity to form a layer overlying the deeper water brine. Hence, it is suggested that mesohaline (3.5–15%) conditions in the surface waters were established as a result of periodic incursions of marine water and subsequent evaporation. Conversely, during periods when the surface water was derived mainly from fresh water from the hinterland, lower average salinity in the surface layer resulted. The distributions of long-chain alkylbenzenes also appear to record these changes.  相似文献   

Comment on “Lipids of marine Archaea: Patterns and provenance in the water column and sediments” by Turich et al. (2007)     

Stefan Schouten  Marcel T.J. van der Meer  Ellen C. Hopmans  Jaap S. Sinninghe Damsté 《Geochimica et cosmochimica acta》2008,72(21):5342-5346

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