Formation,fate and leaching of chloroform in coniferous forest soils     

Christian N. Albers  Troels LaierOle S. Jacobsen 《Applied Geochemistry》2010

Chloroform is a common groundwater pollutant but also a natural compound in forest ecosystems. Leaching of natural chloroform from forest soil to groundwater was followed by regular analysis of soil air and groundwater from multilevel wells at four different sites in Denmark for a period of up to 4 a. Significant seasonal variation in chloroform was observed in soil air 0.5 m below surface ranging at one site from 120 ppb by volume in summer to 20 ppb during winter. With depth, the seasonal variation diminished gradually, ranging from 30 ppb in summer to 20 ppb during winter, near the groundwater table. Chloroform in the shallowest groundwater ranged from 0.5–1.5 μg L⁻¹ at one site to 2–5 μg L⁻¹ at another site showing no clear correlation with season. Comparing changes in chloroform in soil air versus depth with on-site recorded meteorological data indicated that a clear relationship appears between rain events and leaching of chloroform. Chloroform in top soil air co-varied with CO₂ given a delay of 3–4 weeks providing evidence for its biological origin. This was confirmed during laboratory incubation experiments which further located the fermentation layer as the most chloroform producing soil horizon. Sorption of chloroform to soils, examined using ¹⁴C–CHCl₃, correlated with organic matter content, being high in the upper organic rich soils and low in the deeper more minerogenic soils. The marked decrease in chloroform in soil with depth may in part be due to microbial degradation which was shown to occur at all depths by laboratory tests using ¹⁴C–CHCl₃.  相似文献   

The Baltic Sea: an outline of its physical oceanography     

G. Kullenberg  T.S. Jacobsen 《Marine pollution bulletin》1981,12(6):183-186

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Versuch der Einbeziehung konvektiver Prozesse in die Theorie der Ekman-Schicht     

Prof. Dr. H. Griesseier  Dipl.-Met. I. Jacobsen 《Meteorology and Atmospheric Physics》1970,19(1):283-298

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Isotope Dilution MC-ICP-MS Rare Earth Element Analysis of Geochemical Reference Materials NIST SRM 610, NIST SRM 612, NIST SRM 614, BHVO-2G, BHVO-2, BCR-2G, JB-2, WS-E, W-2, AGV-1 and AGV-2     

Adam J.R. Kent  Benjamin Jacobsen  David W. Peate  Tod E. Waight  Joel A. Baker 《Geostandards and Geoanalytical Research》2004,28(3):417-429

We present data for the concentrations of eleven rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er, Yb, Lu) in eleven international geochemical reference materials obtained by isotope dilution multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We have analysed both rock powders and synthetic silicate glasses, and the latter provide precise data to support the use of these as reference materials for in situ trace element determination techniques. Our data also provide precise measurements of the abundance of mono-isotopic Pr in both glasses and powders, which allows more accurate constraints on the anomalous redox-related behaviour of Ce during geochemical processes. All materials were analysed in replicate providing data that typically reproduce to better than one percent. Sm/Nd ratios in all these materials also reproduce to better than 0.2% and are accurate to < 0.2% and can thus be used as calibrants for Sm-Nd geochronology. Our analyses agree well with existing data on these reference materials. In particular, for NIST SRM 610, USGS BHVO-2, AGV-1 and AGV-2, our measured REE abundances are typically within < 2% (and mostly 1%) of REE concentrations previously determined by isotope dilution analysis and thermal ionisation mass spectrometry, consistent with the higher degree of precision and accuracy obtained from isotope dilution techniques. Close agreement of results between basaltic glass reference materials USGS BHVO-2G and BCR-2G and the BHVO-2 and BCR-2 powders from which they were created suggests that little fractionation, concentration or dilution of REE contents occurred during glass manufacture.  相似文献   

Direct Sensor Orientation for Large Scale Mapping—Potential, Problems, Solutions     

Nac  Yastikli  Karsten  Jacobsen 《The Photogrammetric Record》2005,20(111):274-284

Georeferencing is one of the most important tasks in photogrammetry. Traditionally it has been achieved indirectly using the well-known method of aerial triangulation. With the availability of integrated GPS and inertial measurement units (IMU), this situation changed. Direct determination of exterior orientation is now possible. Today, direct and integrated sensor orientation is used for a wide range of sensors including lidar and SAR, as well as for digital line scanner systems and aerial cameras. This paper investigates the performance of direct and integrated sensor orientation for large scale mapping using the data-set of the 'Integrated Sensor Orientation' test of the European Organisation for Experimental Photogrammetric Research (OEEPE—now known as EuroSDR). The concept, potential, problems and solutions of direct and integrated sensor orientation are discussed.  相似文献   

Piecewise 1D laterally constrained inversion of resistivity data   总被引：1，自引：0，他引：1  

Esben Auken  ers V. Christiansen  Bo H. Jacobsen  Nikolaj Foged  Kurt I. Sørensen 《Geophysical Prospecting》2005,53(4):497-506

In a sedimentary environment, layered models are often capable of representing the actual geology more accurately than smooth minimum structure models. Furthermore, interval thicknesses and resistivities are often the parameters to which non‐geophysicist experts can relate and base decisions on when using them in waste site remediation, groundwater modelling and physical planning. We present a laterally constrained inversion scheme for continuous resistivity data based on a layered earth model (1D). All 1D data sets and models are inverted as one system, producing layered sections with lateral smooth transitions. The models are regularized through laterally equal constraints that tie interface depths and resistivities of adjacent layers. Prior information, e.g. originating from electric logs, migrates through the lateral constraints to the adjacent models, making resolution of equivalences possible to some extent. Information from areas with well‐resolved parameters will migrate through the constraints in a similar way to help resolve the poorly constrained parameters. The estimated model is complemented by a full sensitivity analysis of the model parameters, supporting quantitative evaluation of the inversion result. Examples from synthetic 2D models show that the model recognition of a sublayered 2D wedge model is improved using the laterally constrained inversion approach when compared with a section of combined 1D models and when compared with a 2D minimum structure inversion. Case histories with data from two different continuous DC systems support the conclusions drawn from the synthetic example.  相似文献   

Nd and Sr isotopic variations of Early Paleozoic oceans   总被引：4，自引：0，他引：4  

Lisette S. Keto  Stein B. Jacobsen 《Earth and Planetary Science Letters》1987,84(1)

We report¹⁴³Nd/¹⁴⁴Nd and⁸⁷Sr/⁸⁶Sr isotopic data for Lower Paleozoic phosphatic brachiopod and conodont fossils. The data appear to represent the isotopic values of Early Paleozoic seawaters. We show that different paleoceanic water masses can be distinguished on the basis of their ε_Nd signatures. Two sides of what is classically considered one circulating Iapetus Ocean have different ε_Nd signatures from at least the Middle Cambrian until the Late Middle Ordovician. We infer two ocean basins between North America and Baltica separated by an island and/or shoal circulation barrier. Thus, it appears necessary to redefine the area of the Iapetus Ocean. The ε_Nd signature of the redefined smaller Iapetus Ocean ranges from −5 to −9 and the ε_Nd signature of the larger, coeval Panthalassa Ocean, including part of what was formerly called the Iapetus Ocean, ranges from −10 to −20. The first time that the ε_Nd values are identical in these two water masses is coincident with the onset of the Taconic Orogeny of North America. The paleogeographic geometry we infer from this work is consistent with paleogeographic reconstructions having the Baltica continent at very high latitudes in the Early/Middle Ordovician. The ε_Nd and faunal distribution support temperature-controlled conodont faunal provinciality. A rough mean age for exposed continental crust in the Early Paleozoic can be obtained from the average ε_Nd value of Early Paleozoic Oceans. The data suggest that the mean age of the crust as a function of time has remained essentially constant or even decreased during the past 500 Ma, and suggest substantial additions of new crust to the continents through the Phanerozoic.  相似文献   

Sm−Nd dating of multiple garnet growth events in an arc-continent collision zone,northwestern U.S. Cordillera     

Stephen R. Getty  Jane Selverstone  Brian P. Wernicke  Stein B. Jacobsen  Elaine Aliberti  Daniel R. Lux 《Contributions to Mineralogy and Petrology》1993,115(1):45-57

Integrated petrologic and Sm–Nd isotopic studies in garnet amphibolites along the Salmon River suture zone, western Idaho, delineate two periods of amphibolite grade metamorphism separated by at least 16 million years. In one amphibolite,P–T studies indicate a single stage of metamorphism with final equilibration at 600°C and 8–9 kbar. The Sm–Nd isotopic compositions of plagioclase, apatite, hornblende, and garnet define a precise, 8-point isochron of 128±3 Ma (MSWD=1.2) interpreted as mineral growth at the metamorphic peak. A⁴⁰Ar/³⁹Ar age for this hornblende indicates cooling through 525°C at 119±2 Ma. In a nearby amphibolite, garnets with a two-stage growth history consist of inclusion-rich cores surrounded by discontinuous, inclusion-free overgrowths. Temporal constraints for core and overgrowth development were derived from Sm–Nd garnet — whole rock pairs in which the garnet fractions consist of varying proportions of inclusion-free to inclusion-bearing fragments. Three garnet fractions with apparent ages of 144, 141, and 136 Ma are thought to represent mixtures between late Jurassic (pre-144 Ma) inherited radiogenic components preserved within garnet cores and early Cretaceous (128 Ma) garnet overgrowths. These observations confirm the resilience of garnet to diffusive exchange of trace elements during polymetamorphism at amphibolite facies conditions. Our geochronologic results show that metamorphism of arc-derived rocks in western Idaho was episodic and significantly older than in arc rocks along the eastern margin of the Wrangellian Superterrane in British Columbia and Alaska. The pre-144 Ma event may be an expression of the late Jurassic amalgamation of marginal oceanic arc-related terranes (e.g., Olds Ferry, Baker, Wallowa) during the initial phases of their collision with North American rocks. Peak metamorphism at 128 Ma reflects tectonic burial along the leading edge of the Wallowa arc terrane during its final penetration and suturing to cratonic North America.  相似文献   

Palaeomagnetic distortion modelling and possible recovery by inversion     

Mads Faurschou Knudsen  Bo Holm Jacobsen Niels Abrahamsen 《Physics of the Earth and Planetary Interiors》2003,135(1):55-73

A robust finite-element technique is presented for computation of both the internal demagnetization effects and magnetic terrain effects in bodies with arbitrary shape and arbitrary susceptibility distribution. This method facilitates a flexible analysis of the palaeomagnetic deflection problem. Tests on geologically realistic settings of highly magnetic rocks demonstrate that deflections of several degrees may occur even for relatively simple two-dimensional models. Similarly, the magnetic intensity may well be biased by 5-15% by demagnetization effects. The present paper focuses on deflections and intensity variations inside the magnetized body, where we find a systematic shallowing of inclination for bodies with a horizontal elongation. Because the bodies sampled at a typical palaeomagnetic site will have a dominant direction of elongation, the magnetic deflection effect will tend to impose a systematic bias which doesn’t average out. An inversion-based procedure for elimination of the deflection effect is presented. It requires that the magnetic body is quite homogeneous and that its surface geometry is known, as may be the case for historical lava flows. Tests demonstrate that in order to recover both ambient palaeofield direction and the effective susceptibility at blocking temperature it is necessary to sample near strong topographic elements in the magnetic body. Since the surface geometry rarely is known it is proposed as an alternative to inversion that an effective susceptibility is assessed and a horizontal slab correction is applied for samples taken far from topographical features. When shape geometry is unknown and no correction applied, palaeomagnetic conclusions must take into account the possible bias from internal demagnetization and magnetic terrain effects.  相似文献   

Crustal root beneath the highlands of southern Norway resolved by teleseismic receiver functions   总被引：1，自引：0，他引：1  

L. Svenningsen  N. Balling  B. H. Jacobsen  R. Kind  K. Wylegalla  J. Schweitzer 《Geophysical Journal International》2007,170(3):1129-1138

Teleseismic data have been collected with temporary seismograph stations on two profiles in southern Norway. Including the permanent arrays NORSAR and Hagfors the profiles are 400 and 500 km long and extend from the Atlantic coast across regions of high topography and the Oslo Rift. A total of 1071 teleseismic waveforms recorded by 24 temporary and 8 permanent stations are analysed. The depth-migrated receiver functions show a well-resolved Moho for both profiles with Moho depths that are generally accurate within ±2 km.
For the northern profile across Jotunheimen we obtain Moho depths between 32 and 43 km (below sea level). On the southern profile across Hardangervidda, the Moho depths range from 29 km at the Atlantic coast to 41 km below the highland plateau. Generally the depth of Moho is close to or above 40 km beneath areas of high mean topography (>1 km), whereas in the Oslo Rift the crust locally thins down to 32 km. At the east end of the profiles we observe a deepening Moho beneath low topography. Beneath the highlands the obtained Moho depths are 4–5 km deeper than previous estimates. Our results are supported by the fact that west of the Oslo Rift a deep Moho correlates very well with low Bouguer gravity which also correlates well with high mean topography.
The presented results reveal a ca . 10–12 km thick Airy-type crustal root beneath the highlands of southern Norway, which leaves little room for additional buoyancy-effects below Moho. These observations do not seem consistent with the mechanisms of substantial buoyancy presently suggested to explain a significant Cenozoic uplift widely believed to be the cause of the high topography in present-day southern Norway.  相似文献