Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H₂CO) extended source in Comet C/1995 O1 (Hale-Bopp)     

Nicolas Fray  Yves Bénilan  Dominique Bockelée-Morvan  Jacques Crovisier 《Icarus》2006,184(1):239-254

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.  相似文献   

The influence of tropical Pacific forcing on the Arctic Oscillation     

Xiaojing Jia  Hai Lin  Jacques Derome 《Climate Dynamics》2009,32(4):495-509

The potential role of tropical Pacific forcing in driving the seasonal variability of the Arctic Oscillation (AO) is explored using both observational data and a simple general circulation model (SGCM). A lead–lag regression technique is first applied to the monthly averaged sea surface temperature (SST) and the AO index. The AO maximum is found to be related to a negative SST anomaly over the tropical Pacific three months earlier. A singular value decomposition (SVD) analysis is then performed on the tropical Pacific SST and the sea level pressure (SLP) over the Northern Hemisphere. An AO-like atmospheric pattern and its associated SST appear as the second pair of SVD modes. Ensemble integrations are carried out with the SGCM to test the atmospheric response to different tropical Pacific forcings. The atmospheric response to the linear fit of the model’s empirical forcing associated with the SST variability in the second SVD modes strongly projects onto the AO. Idealized thermal forcings are then designed based on the regression of the seasonally averaged tropical Pacific precipitation against the AO index. Results indicate that forcing anomalies over the western tropical Pacific are more effective in generating an AO-like response while those over the eastern tropical Pacific tend to produce a Pacific-North American (PNA)-like response. The physical mechanisms responsible for the energy transport from the tropical Pacific to the extratropical North Atlantic are investigated using wave activity flux and vorticity forcing formalisms. The energy from the western tropical Pacific forcing tends to propagate zonally to the North Atlantic because of the jet stream waveguide effect while the transport of the energy from the eastern tropical Pacific forcing mostly concentrates over the PNA area. The linearized SGCM results show that nonlinear processes are involved in the generation of the forced AO-like pattern.  相似文献   

TNOs are Cool: A Survey of the Transneptunian Region     

Thomas G. Müller  Emmanuel Lellouch  Hermann Böhnhardt  John Stansberry  Antonella Barucci  Jacques Crovisier  Audrey Delsanti  Alain Doressoundiram  Elisabetta Dotto  René Duffard  Sonia Fornasier  Olivier Groussin  Pedro J. Gutiérrez  Olivier Hainaut  Alan W. Harris  Paul Hartogh  Daniel Hestroffer  Jonathan Horner  Dave Jewitt  Mark Kidger  Csaba Kiss  Pedro Lacerda  Luisa Lara  Tanya Lim  Michael Mueller  Raphael Moreno  Jose-Luis Ortiz  Miriam Rengel  Pablo Santos-Sanz  Bruce Swinyard  Nicolas Thomas  Audrey Thirouin  David Trilling 《Earth, Moon, and Planets》2009,105(2-4):209-219

Over one thousand objects have so far been discovered orbiting beyond Neptune. These trans-Neptunian objects (TNOs) represent the primitive remnants of the planetesimal disk from which the planets formed and are perhaps analogous to the unseen dust parent-bodies in debris disks observed around other main-sequence stars. The dynamical and physical properties of these bodies provide unique and important constraints on formation and evolution models of the Solar System. While the dynamical architecture in this region (also known as the Kuiper Belt) is becoming relatively clear, the physical properties of the objects are still largely unexplored. In particular, fundamental parameters such as size, albedo, density and thermal properties are difficult to measure. Measurements of thermal emission, which peaks at far-IR wavelengths, offer the best means available to determine the physical properties. While Spitzer has provided some results, notably revealing a large albedo diversity in this population, the increased sensitivity of Herschel and its superior wavelength coverage should permit profound advances in the field. Within our accepted project we propose to perform radiometric measurements of 139 objects, including 25 known multiple systems. When combined with measurements of the dust population beyond Neptune (e.g. from the New Horizons mission to Pluto), our results will provide a benchmark for understanding the Solar debris disk, and extra-solar ones as well.  相似文献   

Magnesite growth rates as a function of temperature and saturation state   总被引：1，自引：1，他引：0  

Giuseppe D. Saldi  Guntram Jordan  Jacques Schott  Eric H. Oelkers 《Geochimica et cosmochimica acta》2009,73(19):5646-5657

Magnesite growth rates and step velocities have been measured systematically as a function of temperature from 80 to 105 °C and saturation state in 0.1 M NaCl solutions using hydrothermal atomic force microscopy (HAFM). The observations indicate that at these conditions magnesite precipitation is dominated by the coupling of step generation via spiral growth at screw dislocations and step advancement away from these dislocations. As these two processes occur in series the slowest of these dominates precipitation rates. At 100 °C magnesite growth rates (r) determined by HAFM are consistent with