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161.
Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS 14C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time.  相似文献   
162.
The Palisades Site is an extensive silt-loam bluff complex on the central Yukon River preserving a nearly continuous record of the last 2 myr. Volcanic ash deposits present include the Old Crow (OCt; 140,000 yr), Sheep Creek (SCt; 190,000 yr), PA (2.02 myr), EC (ca. 2 myr), and Mining Camp (ca. 2 myr) tephras. Two new tephras, PAL and PAU, are geochemically similar to the PA and EC tephras and appear to be comagmatic. The PA tephra occurs in ice-wedge casts and solifluction deposits, marking the oldest occurrence of permafrost in central Alaska. Three buried forest horizons are present in association with dated tephras. The uppermost forest bed occurs immediately above the OCt; the middle forest horizon occurs below the SCt. The lowest forest bed occurs between the EC and the PA tephras, and correlates with the Dawson Cut Forest Bed. Plant taxa in all three peats are common elements of moist taiga forest found in lowlands of central Alaska today. Large mammal fossils are all from common late Pleistocene taxa. Those recovered in situ came from a single horizon radiocarbon dated to ca. 27,000 14C yr B.P. The incongruous small mammal assemblage in that horizon reflects a diverse landscape with both wet and mesic environments.  相似文献   
163.
Oxygen air-water gas exchange was measured using floating chambers in two shallow tidal estuaries of differing bathymetry and local terrain, near Waquoit Bay, Massachusetts (United States). The specific chamber design permitted measurements of gas flux in 15 min, allowing analysis of the relationship with wind speed and tidal stage. Exchange coefficients ranged from 0.5 to 2.5 g O2·m?2 h?1 atm?1 (equivalent to piston velocities of 1.5 to 7 cm h?1) for wind speeds of 0.3 to 9 m s?1 at 10 m elevation. While the relationships for each estuary appear linear (significant linear regressions with wind speed were shown for each estuary, and the slopes were different at the 99.5% confidence level), the range of speeds differed at the two sites and an exponential function of wind speed was consistent with the combined data from both estuaries. A power function of wind speed was not an acceptable model. The exchange coefficients for our estuaries are from 57% to as low as 9% of that predicted by previously published generic equations. Because the atmospheric correction can be significant in shallow, metabolically active coastal waters, we suggest that empirically determined relationships for gas exchange versus wind for a specific estuary are preferable to the predictions of the general equations. While the floating chamber method should be used cautiously, at low winds speeds (below 8 m s?1) and in slowly flowing waters, it provides a convenient approach for quantifying these site-specific differences. The differences, especially those between shallow sheltered systems and the open waters best fit by some published relationships, are ecologically important and do not appear yet to be measurable by other methods.  相似文献   
164.
165.
Late summer hypoxia (<3 ppm oxygen) in western Long Island Sound (WLIS) is a persistent environmental and management issue whose controlling processes are poorly understood. Measured rates of sediment and water-column oxygen consumption in the bottom water suggest that a condition of no oxygen should be attained on the time scale of 13–30 d. Observations, however, indicate the onset of hypoxia is of the order 150 d. Therefore, horizontal and/or vertical transport of oxygen into the area of hypoxia must play an important role. Hypoxia decreases benthic activity and the sediment flux of222Rn. The resulting horizontal gradient in bottom water222Rn was measured and used to estimate the effective horizontal transport rate (>5–50 m2 s?1), which is considerably slower than previous estimates. Scale analysis of the hypoxia process indicates that horizontal transport rates alone can explain the slow progression of hypoxia in XLIS but that vertical processes may also be capable of delaying the onset of hypoxia especially under conditions of weak stratification or weak intermediate layer oxygen consumption. This scale analysis indicates a delicately balanced process that is sensitive to both climatologically-driven variability in the rates of horizontal and vertical transport as well as the biologically-driven rates of oxygen consumption. An improved ability to predict and/or control hypoxia must be based on a better understanding of temporal and spacial variations in circulation, mixing, and stratification as well as the biological processes in the water column and the sediments.  相似文献   
166.
UV Laser Ablation ICP-MS: Some Applications in the Earth Sciences   总被引:4,自引:0,他引:4  
This study reports a series of applications of UV laser ablation ICP-MS in the geological sciences. The advantages and disadvantages of the PQ "S" option and the use of nitrogen in the carrier gas are discussed. A general problem common to all ablation techniques is the calibration technique and experiments involving synthetic calibration samples are covered. Zircon geochemistry and geochronology by LA-ICP-MS are discussed and data are presented for REE, Hf and U for a standard zircon (91500) as well as a series of zircons from Zimbabwe. The potential of using Ce and Eu anomalies in petrologic studies is illustrated by zircons from a fractionated gabbroic-granite in the Urals. The potential of the LA-ICP-MS method to utilise standard X-ray fluorescence glass discs is demonstrated as a useful semi-quantitative tool in determining REE patterns. LA-ICP-MS is a powerful tool in the analysis of the platinum group elements (and Re) and some examples are given in the successful application of the technique to partitioning in iron meteorites.  相似文献   
167.
The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.  相似文献   
168.
The (re)making of the western 'geographical tradition': some missing links   总被引:1,自引:0,他引:1  
Summary A brief investigation of certain missing links in the narration of the history of geography focuses on the need to consider the contribution of non-western geographical and scientific knowledges to the making of 'European discovery' and therefore to the development of a putatively western geographical tradition.  相似文献   
169.
James Taylor 《Area》1997,29(2):160-171
Summary This paper discusses the relationship between advertising and 'race', using as its foundation the replication of a study conducted in the US which used content analysis to examine the representation of Black characters in television advertisements. The replication facilitates a comparison of the British and American cases, revealing significant differences in the frequency and perceived importance of such representations. It can also help draw out the specificities of the UK situation. The paper attempts to convey the complexity of the interplay between advertising and racialisation, and emphasises that while such quantitative, textual studies offer a useful basis for further research, they are limited by their failure to address the motivations of producers and how advertisements are read by different groups in different places.  相似文献   
170.
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