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81.
The higher mid‐latitudes of the Northern Hemisphere are particularly sensitive to climate change as small differences in temperature determine frozen ground status, precipitation phase, and the magnitude and timing of snow accumulation and melt. An international inter‐catchment comparison program, North‐Watch, seeks to improve our understanding of the sensitivity of northern catchments to climate change by examining their hydrological and biogeochemical responses. The catchments are located in Sweden (Krycklan), Scotland (Mharcaidh, Girnock and Strontian), the United States (Sleepers River, Hubbard Brook and HJ Andrews) and Canada (Catamaran, Dorset and Wolf Creek). This briefing presents the initial stage of the North‐Watch program, which focuses on how these catchments collect, store and release water and identify ‘types’ of hydro‐climatic catchment response. At most sites, a 10‐year data of daily precipitation, discharge and temperature were compiled and evaporation and storage were calculated. Inter‐annual and seasonal patterns of hydrological processes were assessed via normalized fluxes and standard flow metrics. At the annual‐scale, relations between temperature, precipitation and discharge were compared, highlighting the role of seasonality, wetness and snow/frozen ground. The seasonal pattern and synchronicity of fluxes at the monthly scale provided insight into system memory and the role of storage. We identified types of catchments that rapidly translate precipitation into runoff and others that more readily store water for delayed release. Synchronicity and variance of rainfall–runoff patterns were characterized by the coefficient of variation (cv) of monthly fluxes and correlation coefficients. Principal component analysis (PCA) revealed clustering among like catchments in terms of functioning, largely controlled by two components that (i) reflect temperature and precipitation gradients and the correlation of monthly precipitation and discharge and (ii) the seasonality of precipitation and storage. By advancing the ecological concepts of resistance and resilience for catchment functioning, results provided a conceptual framework for understanding susceptibility to hydrological change across northern catchments. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
82.
The dynamic strength of an ordinary chondrite   总被引:1,自引:0,他引:1  
Abstract– Dynamic and quasistatic unconfined compression experiments were performed on samples of the L5 ordinary chondrite MacAlpine Hills (MAC) 88118. The dynamic compressive strength measurements are the first of its kind for a stony meteorite, and indicate that the material tested here exhibits significant increase in compressive strength with increasing strain rate. This increase in compressive strength is larger than the increases typically observed in terrestrial rock specimens compressed over a similar range of strain rates. The details of the failure process are investigated by recording images of the experiments in real time. Specifically, the crack growth speeds in the dynamic compression experiments are measured from ultrahigh‐speed images. These speeds are significantly lower than the speeds observed in terrestrial analogs that are typically used in numerical investigations of large‐scale impacts. The implications of these measurements of strength and failure process are explored in the contexts of atmospheric disruption of meteors and impact cratering/disruption of asteroids.  相似文献   
83.
This paper introduces a new modeling framework to understand and improve regional natural disaster risk management in the USA, including the interactions among key stakeholders and between the two important risk management mechanisms of insurance and retrofit. The framework includes a stochastic programming optimization to represent insurer decisions, which interacts with a utility-based model of individual homeowners’ decisions to insure and/or retrofit. Reinsurer and government roles are represented as inputs, and the decision models are integrated with a detailed regional catastrophe loss estimation model. This modeling framework is applied to a full-scale, realistic case study for hurricane risk to residential buildings in Eastern North Carolina. Several alternative system configurations are considered that affect the incentives for adoption of alternative risk management methods. They include providing a government subsidy for insured homeowners to encourage retrofit, providing both a government subsidy and insurance rebate to reduce retrofit costs, and mandating insurance purchase with a cap on insurance premiums. For each configuration, outcomes are presented from the perspectives of all key stakeholders—primary insurer, homeowners (insured and uninsured, in high- and low-risk areas), reinsurers, and the government. Results suggest that it is possible to design policies in which all stakeholders can be better off simultaneously. Retrofit incentives for insured homeowners can be effective in linking and strengthening the benefits of retrofit and insurance. Mandatory insurance coupled with capped profit loading factors and possibly retrofit rebates from the insurer to the homeowner can also reduce overall system risk.  相似文献   
84.
Abstract: Soil water retention curves (SWRCs) provide an important means of describing the response of unsaturated soils during drying / wetting processes in terms of variations of degree of saturation, water content or void ratio with suction. A key consideration in generating these curves is how to measure the suction. Frequently the filter paper technique is adopted, especially when high suctions are developed, e.g. with plastic clays. As each measurement takes at least a week with this technique, it can take months or years to generate a full SWRC in drying and wetting. Developments in laboratory tensiometers now allow matrix suctions up to about 1.5 MPa to be measured. With such a device it is possible to develop SWRCs for granular soils such as silts and clays in hours or days by continuous measurement. This paper describes an experimental set-up that was developed to measure changes in volume, water content and matrix suction during drying of three granular soils. Limitations of the apparatus and usefulness of the curves are discussed.  相似文献   
85.
Abstract— The polycyclic aromatic nitrogen heterocycle (PANH) quinoline (C9H7N) was frozen at 20 K in interstellar ice analogs containing either pure water or water mixed with methanol or methane and exposed to ultraviolet (UV) radiation. Upon warming, the photolysis products were analyzed by high‐performance liquid chromatography and nanoscale liquid chromatography‐electrospray ionization mass spectrometry. A suite of hydroxyquinolines, which were formed by the addition of oxygen atoms to quinoline, was observed as the primary product in all the ices. Quinoline N oxide was not formed, but five hydroxyquinoline isomers were produced with no clear dominance of one isomer. Reduction products, formed by hydrogen atom addition, were also created. Ices created at 20 K with H2O: quinoline ratios of 10:1 to 100:1 showed similar product distributions to those at 122 K, with no apparent temperature or concentration dependence. Increasing the UV dose led to a decrease in overall yield, indicating that quinoline and its products may be photo‐destroyed. Methylquinolines were formed upon photolysis of the methanol‐ and methane‐containing ices. In addition, possible methoxyquinolines or quinoline methylene alcohols were formed in the methanol‐containing ice, while methylhydroxyquinolines were created in the methane‐containing ice. This work indicates that oxidation of PANHs could occur in icy extraterrestrial environments and suggests that a search for such compounds in carbonaceous meteorites could illuminate the possible link between interstellar ice chemistry and meteoritic organics. Given the importance of oxidized and alkylated PANHs to biochemistry, the formation and delivery of such molecules to the early Earth may have played a role in the origin and evolution of life.  相似文献   
86.
87.
The CI1 Orgueil meteorite is a highly aqueously altered carbonaceous chondrite. It has been extensively studied, and despite its extensive degree of aqueous alteration and some documented instances of contamination, several indigenous organic compounds including amino acids, carboxylic acids, and nucleobases have been detected in its carbon‐rich matrix. We recently developed a novel gas chromatographic method for the enantiomeric and compound‐specific isotopic analyses of meteoritic aliphatic monoamines in extracts and have now applied this method to investigate the monoamine content in Orgueil. We detected 12 amines in Orgueil, with concentrations ranging from 1.1 to 332 nmol g?1 of meteorite and compared this amine content in Orgueil with that of the CM2 Murchison meteorite, which experienced less parent‐body aqueous alteration. Methylamine is four times more abundant in Orgueil than in Murchison. As with other species, the amine content in Orgueil extracts shows less structural diversity than that in Murchison extracts. We measured the compound‐specific stable carbon isotopic ratios (δ13C) for 5 of the 12 monoamines detected in Orgueil and found a range of δ13C values from –20 to +59‰. These δ13C values fall into the range of other meteoritic organic compounds, although they are 13C‐depleted relative to their counterparts extracted from the Murchison meteorite. In addition, we measured the enantiomeric composition for the chiral monoamines (R)‐ and (S)‐sec‐butylamine in Orgueil, and found it was racemic within experimental error, in contrast with the l ‐enantiomeric excess found for its amino acid structural analog isovaline. The racemic nature of sec‐butylamine in Orgueil was comparable to that previously observed in Murchison, and to other CM2 and CR2 carbonaceous chondrites measured in this work (ALH 83100 [CM1/2], LON 94101 [CM2], LEW 90500 [CM2], LAP 02342 [CR2], and GRA 95229 [CR2]). These results allow us to place some constraints on the effects of aqueous alteration observed over the monoamine concentrations in Orgueil and Murchison, and to evaluate the primordial synthetic relationships between meteoritic monoamines and amino acids.  相似文献   
88.
Exogenous delivery of amino acids and other organic molecules to planetary surfaces may have played an important role in the origins of life on Earth and other solar system bodies. Previous studies have revealed the presence of indigenous amino acids in a wide range of carbon‐rich meteorites, with the abundances and structural distributions differing significantly depending on parent body mineralogy and alteration conditions. Here we report on the amino acid abundances of seven type 3–6 CK chondrites and two Rumuruti (R) chondrites. Amino acid measurements were made on hot water extracts from these meteorites by ultrahigh‐performance liquid chromatography with fluorescence detection and time‐of‐flight mass spectrometry. Of the nine meteorites analyzed, four were depleted in amino acids, and one had experienced significant amino acid contamination by terrestrial biology. The remaining four, comprised of two R and two CK chondrites, contained low levels of amino acids that were predominantly the straight chain, amino‐terminal (n‐ω‐amino) acids β‐alanine, and γ‐amino‐n‐butyric acid. This amino acid distribution is similar to what we reported previously for thermally altered ureilites and CV and CO chondrites, and these n‐ω‐amino acids appear to be indigenous to the meteorites and not the result of terrestrial contamination. The amino acids may have been formed by Fischer–Tropsch‐type reactions, although this hypothesis needs further testing.  相似文献   
89.
The prediction of near-shore morphology on the time scale of a storm event and the length scale of a few surf zone widths is an active area of research. Intense wave breaking drives offshore-directed currents (undertow) carrying sediment seawards, resulting in offshore bar migration. In contrast, higher order nonlinear properties, such as wave asymmetry (velocity skewness) and velocity asymmetry, are drivers for shoreward transport. These wave processes are included in phase-resolving models such as Boussinesq-type wave models (e.g., TRITON). Short-wave averaging in the wave model yields wave-induced forces (e.g., radiation stress gradients) and a wave asymmetry term. The wave-induced forces are used in a hydrostatic model (e.g., Delft3D flow module) to drive the current and undertow, resulting in a 3D velocity profile. The wave model and hydrostatic model are coupled online with a morphodynamic model (e.g., Delft3D morphology module). The latter computes, based on the 3D flow profile and the wave asymmetry term, the sediment transport and performs the bathymetry updates. The updates are transferred directly back to the hydrodynamic models. The coupling of the wave model TRITON and the Delft3D modules is validated by comparing against extensive laboratory data sets (LIP and Boers) and a field case (Duck94), and show a good performance for the hydrodynamics and a reasonable/fair performance for the bar movements.  相似文献   
90.
Abstract— The polycyclic aromatic hydrocarbon (PAH) anthracene was oxidized by exposure to ultraviolet (UV) radiation in H2O ice under simulated astrophysical conditions, forming several anthracene ketones (9‐anthrone, 1,4‐anthraquinone, and 9,10‐anthraquinone) and alcohols (1‐anthrol and 2‐anthrol). Two of the ketones produced have been detected in the Murchison meteorite but, to our knowledge, there has been no search for the alcohols or other oxidized anthracenes in meteorites. These results seem consistent with the possibility that interstellar ice photochemistry could have influenced the inventory of aromatics in meteorites. Since quinones are also fundamental to biochemistry, their formation in space and delivery to planets is relevant to studies relating to the habitability of planets and the evolution of life.  相似文献   
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