HYTEC results of the MoMas reactive transport benchmark     

Vincent Lagneau  Jan van der Lee 《Computational Geosciences》2010,14(3):435-449

A specific benchmark has been developed by the French research group MoMas in order to improve numerical solution methods applied by reactive transport models, i.e., codes that couple hydrodynamic flow and mass transport in porous media with geochemical reactions. The HYTEC model has been applied to this benchmark exercise, and this paper summarizes some of the principal results. HYTEC is a general-purpose code, applied by industrials and research groups to a wide variety of domains, including soil pollution, nuclear waste storage, cement degradation, water purification systems, storage of CO₂, and valorization of stabilized wastes. The code has been applied to the benchmark test-cases without any specific modification. Apart from the benchmark imposed output, additional information is provided to highlight the behavior of HYTEC specifically and the simulation results in particular.  相似文献   

From Tethys to Eastern Paratethys: Oligocene depositional environments, paleoecology and paleobiogeography of the Thrace Basin (NW Turkey)     

Yeşim İslamoğlu  Mathias Harzhauser  Martin Gross  Gonzalo Jiménez-Moreno  Stjepan Coric  Andreas Kroh  Fred Rögl  Jan van der Made 《International Journal of Earth Sciences》2010,99(1):183-200

The Oligocene depositional history of the Thrace Basin documents a unique paleogeographic position at a junction between the Western Tethys and the Eastern Paratethys. As part of the Tethys, shallow marine carbonate platforms prevailed during the Eocene. Subsequently, a three-staged process of isolation started with the Oligocene. During the Early Rupelian, the Thrace Basin was still part of the Western Tethys, indicated by typical Western Tethyan marine assemblages. The isolation from the Tethys during the Early Oligocene is reflected by oolite formation and endemic Eastern Paratethyan faunas of the Solenovian stage. The third phase reflects an increasing continentalisation of the Thrace Basin with widespread coastal swamps during the Late Solenovian. The mollusc assemblages are predominated by mangrove dwelling taxa and the mangrove plant Avicennia is recorded in the pollen spectra. The final continentalisation is indicated by the replacement of the coastal swamps by pure freshwater swamps and fluvial plains during the Late Oligocene (mammal zone MP 26). This paleogeographic affiliation of the Thrace Basin with the Eastern Paratethys after ~32 Ma contrasts all currently used reconstructions which treat the basin as embayment of the Eastern Mediterranean basin.  相似文献   

Thermal instability of the fluid column in a borehole: application to the Yaxcopoil hole (Mexico)     

Vladimir Cermak  Jan Safanda  Louise Bodri 《International Journal of Earth Sciences》2010,99(6):1437-1451

Observational evidence proved that even when a borehole is in “fully” stabilized conditions, temperature data may exhibit certain unrest resembling irregular oscillations in the order of hundredths or (in the extreme case) even tenths of degree. Temperature was monitored in complicated hydrogeological conditions in the Yaxcopoil-1 hole (Chicxulub impact structure, Mexico). Two experiments are reported: (a) 20-day monitoring when a logger was located in the center of the high temperature gradient anomaly produced by the cold wave slowly propagating downwards and (b) simultaneous three-loggers 18-day monitoring with loggers located above, in and below the anomaly. All observed temperature–time series displayed intermittent oscillations of temperature with sharp gradients and large fluctuations over all observed time scales. While the “upper” and “lower” records revealed quasi-periodic temperature variations, the “central” record shows fast temperature oscillations with strong up-and-down reversals, all with amplitudes up to a few tenths of degree. The observed temperature–time series were processed by recurrence and recurrence interval quantification as well as by spectral analyses. It is shown that fluid in a borehole, subject to thermal gradient, is stable, as far as the gradient remains below a certain critical value. At higher Rayleigh numbers, the periodic character of oscillations typical for “quiescent” regime is superseded by stochastic features. This “oscillatory” convection occurs due to instability of the horizontal boundary layers. In the specific case of the Yaxcopoil hole, the time series above and below the cold wave (characterized by relatively lower temperature gradients between 20 and 50 mK/m) contain a clear low frequency component produced by tidal forcing. This component dominates over the high frequency domain (periods from 10–15 to 1 min), which exhibit a scaling behavior. This pattern conspicuously changes in the center part of the cold wave, where the local temperature gradient exceeds 200 mK/m and where tidal forcing composes only ~3% of the signal.  相似文献   

Geochemistry of highly saline fluids in siliciclastic sequences: genetic implications for post-Variscan fluid flow in the Moravosilesian Palaeozoic of the Czech Republic   总被引：1，自引：1，他引：0  

Jan Kučera  Philippe Muchez  Marek Slobodník  Walter Prochaska 《International Journal of Earth Sciences》2010,99(2):269-284

Ubiquitous post-Variscan dolomites occur in Zn–Pb–Cu veins at the Nízký Jeseník Mountains and the Upper Silesian Basin (Lower and Upper Carboniferous siliciclastics at the eastern part of the Bohemian Massif). Crush–leach, stable isotope (oxygen and carbon) and microthermometry analysis of the fluid inclusions in dolomites enable understanding the geochemistry, origin and possible migration pathways of the fluids. Homogenisation temperatures of fluid inclusions range between 66 and 148°C, with generally higher temperatures in the Nízký Jeseník Mountains area than in the Upper Silesian Basin. The highest homogenisation temperatures (up to 148°C) have been found near major regional faults and the lowest in a distant position or at higher stratigraphic levels. Highly saline (16.6–28.4 eq. wt% NaCl) H₂O–NaCl–CaCl₂ ± MgCl₂ fluids occur in inclusions. Na–Cl–Br systematics of trapped fluids and a calculated oxygen isotopic fluid composition between ?0.9 and +3.0‰ V-SMOW indicate that the fluid was derived from evaporated seawater. Stable isotopic modelling has been used to explain stable isotopic trends. Isotopic values (δ¹³C = ?6.0/+2.0‰ V-PDB, δ¹⁸O = +15.5/+22.5‰ V-SMOW of dolomites) resulted from fractionation and crystallisation within an open system at temperatures between 80 and 160°C. Rock-buffering explains the isotopic composition at low w/r ratios. Organic matter maturation caused the presence of isotopically light carbon in the fluids and fluid–rock interactions largely controlled the fluid chemistry (K, Li, Br and Na contents, K/Cl, I/Cl and Li/Cl molar ratios). The fluid chemistry reflects well the interaction between the fluid and underlying limestones as well as with clay- and organic-rich siliciclastics. No regional trends in temperature or fluid geochemistry favour a fluid migration model characterised by an important vertical upward migration along major faults. A permeable basement and fractured sedimentary sequence enhanced the general nature of the fluid system. Fluid characteristics are comparable with the main post-Variscan fluid flow systems in the Polish (Cracow-Silesian ore district) and German sedimentary basins.  相似文献   

Distribution, geometry, age and origin of overdeepened valleys and basins in the Alps and their foreland     

Frank Preusser  Jürgen M. Reitner  Christian Schlüchter 《Swiss Journal of Geoscience》2010,103(3):407-426

Overdeepened valleys and basins are commonly found below the present landscape surface in areas that were affected by Quaternary glaciations. Overdeepened troughs and their sedimentary fillings are important in applied geology, for example, for geotechnics of deep foundations and tunnelling, groundwater resource management, and radioactive waste disposal. This publication is an overview of the areal distribution and the geometry of overdeepened troughs in the Alps and their foreland, and summarises the present knowledge of the age and potential processes that may have caused deep erosion. It is shown that overdeepened features within the Alps concur mainly with tectonic structures and/or weak lithologies as well as with Pleistocene ice confluence and partly also diffluence situations. In the foreland, overdeepening is found as elongated buried valleys, mainly oriented in the direction of former ice flow, and glacially scoured basins in the ablation area of glaciers. Some buried deeply incised valleys were generated by fluvial down-cutting during the Messinian crisis but this mechanism of formation applies only for the southern side of the Alps. Lithostratigraphic records and dating evidence reveal that overdeepened valleys were repeatedly occupied and excavated by glaciers during past glaciations. However, the age of the original formation of (non-Messinian) overdeepened structures remains unknown. The mechanisms causing overdeepening also remain unidentified and it can only be speculated that pressurised meltwater played an important role in this context.  相似文献   

Editorial: Tjerk Peters (1936–2009)     

Edwin Gnos  Urs Eggenberger  Christian de Capitani 《Swiss Journal of Geoscience》2010,103(1):1-2

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Metal fluxes to the sediments of the Moulay Bousselham lagoon,Morocco   总被引：2，自引：0，他引：2  

Asmae Mhamdi Alaoui  Mohamed Choura  Mohamed Maanan  Bendahhou Zourarah  Marc Robin  Maria Freitas Conceição  César Andrade  Mehdi Khalid  Christian Carruesco 《Environmental Earth Sciences》2010,61(2):275-286

The metal content in surface sediments (0–2 cm, 26 samples), in a sediment core (120, 1 cm slices), taken from Moulay Bousselham (Morocco) was investigated. Concentrations of Al, Fe, Mn, Pb, Zn, Cu, Ni, Cr, Cd, As, and Hg were evaluated in surface and cored sediments of Moulay Bousselham lagoon. Significantly high concentrations in μg g⁻¹ dw of Pb (31.7–6.2), Zn (758.9–167), Cu (310.7–22), Ni (96–10.5), Cr (113–18.9), Cd (0.84–0.02), As (1–0.1), and Hg (0.61–0.02) were found in sediment samples from Moulay Bousselham lagoon. Calculated enrichment factors [EF_Me = (Me/Al)_sample/(Me/Al)_background], using Al as a normalizer, and correlation matrices showed that metal pollution in Merja Zerga of Moulay Bousselham lagoon was the product of anthropogenic sources, while the metal content in Merja Kehla was of natural origins. The results suggest that a major change in the sedimentary regime of the lagoon, associated with internal trapping and re-distribution of heavy metal, has been occurring in the past few decades. The cause would appear to be the construction of a Nador Canal at the lagoon. Probable effects concentrations (PEC) were often exceeded for heavy metals in the lagoon sediments, especially for Zn, Cu, Ni, and Cr, and four stations, stations MZ-11, MZ-12, MZ-13, MZ-14, MZ-16, and MZ-17, had multiple metals at presumptively toxic levels. These comparisons suggest that sediment metal levels in the river are clearly high and probably pose an environmental risk at some stations. The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake. Metal concentrations found in Moulay Bousselham lagoon were comparable to aquatic systems classified as contaminated from other regions of the world.  相似文献   

Remotely sensed soil moisture integration in an ecosystem carbon flux model. The spatial implication     

Willem W. Verstraeten  Frank Veroustraete  Wolfgang Wagner  Tom Van Roey  Walter Heyns  Sara Verbeiren  Jan Feyen 《Climatic change》2010,103(1-2):117-136

While remote sensing is able to provide spatially explicit datasets at regional to global scales, extensive application to date has been found only in the reporting and verification of ecosystem carbon fluxes under the Kyoto Protocol. One of the problems is that new remote sensing datasets can be used only with models or data assimilation schemes adapted to include a data input interface dedicated to the type and format of these remote sensing datasets. In this study, soil water index data (SWI), derived from the ERS scatterometer (10-daily time period with a spatial resolution of 50 km), are integrated into the ecosystem carbon balance model C-Fix to assess 10-daily Net Ecosystem Productivity (NEP) patterns of Europe from the remote sensing perspective on an approximate 1-by-1 km² pixel scale using NDVI-AVHRR data. The modeling performance of NEP obtained with and without the assimilation of remotely sensed soil moisture data in the carbon flux model C-Fix is evaluated with EUROFLUX data. Results show a general decrease of the RRMSE of up to 11 with an average of 3.46. C-Fix is applied at the European scale to demonstrate the potential of this ecosystem carbon flux model, based on remote sensing inputs. More specifically, the strong impact of soil moisture on the European carbon balance in the context of the Kyoto Protocol (anthropogenic carbon emissions) is indicated at the country level. Results suggest that several European countries shift from being a carbon sink (i.e., NEP > 1) to being a carbon source (i.e., NEP < 0) whether or not short-term water availability (i.e., soil moisture) is considered in C-Fix NEP estimations.  相似文献   

European temperature records of the past five centuries based on documentary/instrumental information compared to climate simulations     

Eduardo Zorita  Anders Moberg  Lotta Leijonhufvud  Rob Wilson  Rudolf Brázdil  Petr Dobrovolný  Jürg Luterbacher  Reinhard Böhm  Christian Pfister  Dirk Riemann  Rüdiger Glaser  Johan Söderberg  Fidel González-Rouco 《Climatic change》2010,101(1-2):143-168

Two European temperature reconstructions for the past half-millennium, January-to-April air temperature for Stockholm (Sweden) and seasonal temperature for a Central European region, both derived from the analysis of documentary sources and long instrumental records, are compared with the output of climate simulations with the model ECHO-G. The analysis is complemented by comparisons with the long (early)-instrumental record of Central England Temperature (CET). Both approaches to study past climates (simulations and reconstructions) are burdened with uncertainties. The main objective of this comparative analysis is to identify robust features and weaknesses in each method which may help to improve models and reconstruction methods. The results indicate a general agreement between simulations obtained with temporally changing external forcings and the reconstructed Stockholm and CET records for the multi-centennial temperature trend over the recent centuries, which is not reproduced in a control simulation. This trend is likely due to the long-term change in external forcing. Additionally, the Stockholm reconstruction and the CET record also show a clear multi-decadal warm episode peaking around AD 1730, which is absent in the simulations. Neither the reconstruction uncertainties nor the model internal climate variability can easily explain this difference. Regarding the interannual variability, the Stockholm series displays, in some periods, higher amplitudes than the simulations but these differences are within the statistical uncertainty and further decrease if output from a regional model driven by the global model is used. The long-term trend of the CET series agrees less well with the simulations. The reconstructed temperature displays, for all seasons, a smaller difference between the present climate and past centuries than is seen in the simulations. Possible reasons for these differences may be related to a limitation of the traditional ‘indexing’ technique for converting documentary evidence to temperature values to capture long-term climate changes, because the documents often reflect temperatures relative to the contemporary authors’ own perception of what constituted ‘normal’ conditions. By contrast, the amplitude of the simulated and reconstructed inter-annual variability agrees rather well.  相似文献   

The Lateglacial and early Holocene vegetation and environment in the Dovre mountains,central Norway,as signalled in two Lateglacial nunatak lakes     

Aage Paus  Gaute Velle  Jan Berge 《Quaternary Science Reviews》2011,30(13-14):1780-1796

By using heavy coring equipment in two high-altitudinal lakes (1253 and 1316 m a.s.l.) at Dovre, Central Norway, 1–1.5 m of unsorted coarsely minerogenic sediments were retrieved below the Holocene organic sediments. The minerogenic sequence contained well-preserved pollen and chironomid remains, revealing new and detailed palaeoenvironmental knowledge of the mountains in Central Norway during the last 5–6000 years of the Lateglacial (LG) period. However, the LG chronology is based on biostratigraphical correlations and not on ¹⁴C-dates, due to low organic content in the minerogenic sediments. The emerging LG nunataks, probably indicating a thin and multi-domed Scandinavian ice-sheet, was rapidly inhabited by immigrating species which could explain the present centric distributions of certain arctic-alpine plants. The LG vegetation development included a pre-interstadial dominated by mineral-soil pioneers, an interstadial dominated by shrubs and dwarf-shrubs, and the Younger Dryas cold period with recurring dominance of pioneers. Pollen and stomata of Pinus and Picea indicate their local LG presence at Dovre. LG climate oscillations are indicated by pollen stratigraphy and for the later part of LG also by chironomids. These oscillations could correspond to Heinrich event 1, GI-1d, GI-1b, and the Younger Dryas cold events. The LG interstadial reached July mean temperatures of more than 7–8 °C, similar to the present. Chironomids colonized the lake already during the onset of the interstadial, albeit at very low richness and abundances. Starting from YD, there are sufficient chironomid head capsules to perform a temperature reconstruction. The Holocene warming of about 2 °C initiated a vegetation closure from snow beds and dwarf-shrub tundra to shrubs and forests. Birch-forests established about 10 ka cal BP, slightly earlier than pine forests. Alnus expanded ca 9.2 ka cal BP and a thinning of the local forests occurred from ca 7 ka cal BP. Two short-lasting climate deteriorations found in the pollen record and the chironomid record may represent the Preboreal Oscillation and the 8.2 event. The Holocene Thermal Maximum is indicated around ca 7.8–7.3 ka cal BP showing a chironomid-inferred July mean of at least 11 °C. This is ca 3 °C warmer than today.  相似文献