A model investigation of the impact of increases in anthropogenic NO x emissions between 1967 and 1980 on tropospheric ozone     

Jane Dignon  Sultan Hameed 《Journal of Atmospheric Chemistry》1985,3(4):491-506

Recent observations suggest that the abundance of ozone between 2 and 8 km in the Northern Hemisphere mid-latitudes has increased by about 12% during the period from 1970 to 1981. Earlier estimates were somewhat more conservative suggesting increases at the rate of 7% per decade since the start of regular observations in 1967. Previous photochemical model studies have indicated that tropospheric ozone concentrations would increase with increases in emissions of CO, CH₄ and NO _x . This paper presents an analysis of tropospheric ozone which suggests that a significant portion of its increase may be attributed to the increase in global anthropogenic NO _x emissions during this period while the contribution of CH₄ to the increase is quite small. Two statistical models are presented for estimating annual global anthropogenic emissions of NO _x and are used to derive the trend in the emissions for the years 1966–1980. These show steady increase in the emissions during this interval except for brief periods of leveling off after 1973 and 1978. The impact of this increase in emissions on ozone is estimated by calculations with a onedimensional (latitudinal) model which includes coupled tropospheric photochemistry and diffusive meridional transport. Steady-state photochemical calculations with prescribed NO _x emissions appropriate for 1966 and 1980 indicate an ozone increase of 8–11% in the Northern Hemisphere, a result which is compatible with the rise in ozone suggested by the observations.  相似文献   

Statistical Methods for Characterizing Ground-Water Quality   总被引：2，自引：0，他引：2  

Jane Harris  Jim C. Loftis  Robert H. Montgomery 《Ground water》1987,25(2):185-193

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Patterns of cell viability in the diatom,Skeletonema costatum,in batch culture and in natural populations     

Jane C. Gallagher 《Estuaries and Coasts》1984,7(1):98-101

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Sm−Nd dating of multiple garnet growth events in an arc-continent collision zone,northwestern U.S. Cordillera     

Stephen R. Getty  Jane Selverstone  Brian P. Wernicke  Stein B. Jacobsen  Elaine Aliberti  Daniel R. Lux 《Contributions to Mineralogy and Petrology》1993,115(1):45-57

Integrated petrologic and Sm–Nd isotopic studies in garnet amphibolites along the Salmon River suture zone, western Idaho, delineate two periods of amphibolite grade metamorphism separated by at least 16 million years. In one amphibolite,P–T studies indicate a single stage of metamorphism with final equilibration at 600°C and 8–9 kbar. The Sm–Nd isotopic compositions of plagioclase, apatite, hornblende, and garnet define a precise, 8-point isochron of 128±3 Ma (MSWD=1.2) interpreted as mineral growth at the metamorphic peak. A⁴⁰Ar/³⁹Ar age for this hornblende indicates cooling through 525°C at 119±2 Ma. In a nearby amphibolite, garnets with a two-stage growth history consist of inclusion-rich cores surrounded by discontinuous, inclusion-free overgrowths. Temporal constraints for core and overgrowth development were derived from Sm–Nd garnet — whole rock pairs in which the garnet fractions consist of varying proportions of inclusion-free to inclusion-bearing fragments. Three garnet fractions with apparent ages of 144, 141, and 136 Ma are thought to represent mixtures between late Jurassic (pre-144 Ma) inherited radiogenic components preserved within garnet cores and early Cretaceous (128 Ma) garnet overgrowths. These observations confirm the resilience of garnet to diffusive exchange of trace elements during polymetamorphism at amphibolite facies conditions. Our geochronologic results show that metamorphism of arc-derived rocks in western Idaho was episodic and significantly older than in arc rocks along the eastern margin of the Wrangellian Superterrane in British Columbia and Alaska. The pre-144 Ma event may be an expression of the late Jurassic amalgamation of marginal oceanic arc-related terranes (e.g., Olds Ferry, Baker, Wallowa) during the initial phases of their collision with North American rocks. Peak metamorphism at 128 Ma reflects tectonic burial along the leading edge of the Wallowa arc terrane during its final penetration and suturing to cratonic North America.  相似文献   

A GIS‐based variable source area hydrology model     

Jane R. Frankenberger  Erin S. Brooks  M. Todd Walter  Michael F. Walter  Tammo S. Steenhuis 《水文研究》1999,13(6):805-822

Effective control of nonpoint source pollution from contaminants transported by runoff requires information about the source areas of surface runoff. Variable source hydrology is widely recognized by hydrologists, yet few methods exist for identifying the saturated areas that generate most runoff in humid regions. The Soil Moisture Routing model is a daily water balance model that simulates the hydrology for watersheds with shallow sloping soils. The model combines elevation, soil, and land use data within the geographic information system GRASS, and predicts the spatial distribution of soil moisture, evapotranspiration, saturation‐excess overland flow (i.e., surface runoff), and interflow throughout a watershed. The model was applied to a 170 hectare watershed in the Catskills region of New York State and observed stream flow hydrographs and soil moisture measurements were compared to model predictions. Stream flow prediction during non‐winter periods generally agreed with measured flow resulting in an average r² of 0·73, a standard error of 0·01 m³/s, and an average Nash‐Sutcliffe efficiency R² of 0·62. Soil moisture predictions showed trends similar to observations with errors on the order of the standard error of measurements. The model results were most accurate for non‐winter conditions. The model is currently used for making management decisions for reducing non‐point source pollution from manure spread fields in the Catskill watersheds which supply New York City's drinking water. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Determination of Te,As, Bi,Sb and Se (TABS) in Geological Reference Materials and GeoPT Proficiency Test Materials by Hydride Generation‐Atomic Fluorescence Spectrometry (HG‐AFS)     

Eduardo Teixeira Mansur  Sarah‐Jane Barnes  Dany Savard  Peter C. Webb 《Geostandards and Geoanalytical Research》2020,44(1):147-167

The study of Te, As, Bi, Sb and Se (TABS) has increased over the past years due to their use in the development of low‐carbon energy technologies. However, there is a scarcity of mass fraction values of TABS in geological reference materials. This underlines the difficulty in undertaking routine determinations of these elements. The mass fractions of TABS were determined in geological reference materials using hydride generation‐atomic fluorescence spectrometry (HG‐AFS), calibrated with standard solutions. Comparisons with literature values were used to validate the method. Samples from the GeoPT proficiency test were also analysed. For most elements, there are no assigned or even provisional values for many of the GeoPT and reference materials because of the wide range of results reported. For mass fractions above the quantification limit of the method, our results are in good agreement with the median of GeoPT results. Thus, we propose GeoPT median values as informational values for these elements. In contrast, at mass fractions < 0.5 µg g^?1 median values of Se from GeoPT are systematically higher than our results. Our Se results are in agreement with the reference materials down to 0.02 µg g^?1, which suggest that many of the results for Se reported in GeoPT testing are too high.  相似文献   

Strategic priorities for assessing ecological impacts of marine renewable energy devices in the Pentland Firth (Scotland,UK)     

Mark A. Shields  Lora Jane Dillon  David K. Woolf  Alex T. Ford 《Marine Policy》2009

The Pentland Firth, located between the north coast of mainland Scotland (UK) and the Orkney Islands, is recognised as an excellent location for the utilisation of tidal stream technology. Potential ecological impacts associated with tidal stream technology may ultimately depend on device design, array size and deployment location. Available ecological data for the Pentland Firth is summarised and strategic priorities for assessing ecological impacts are provided. Baseline data on marine species and habitats in the Pentland Firth is severely lacking and consequently the integrity of any environmental impact assessment could be compromised by this lack of data.  相似文献   

Using an inverse modelling approach with equifinality control to investigate the dominant controls on snowmelt nutrient export     

Diogo Costa  John Pomeroy  Helen Baulch  Jane Elliott  Howard Wheater 《水文研究》2019,33(23):2958-2977

There is great interest in modelling the export of nitrogen (N) and phosphorus (P) from agricultural fields because of ongoing challenges of eutrophication. However, the use of existing hydrochemistry models can be problematic in cold regions because models frequently employ incomplete or conceptually incorrect representations of the dominant cold regions hydrological processes and are overparameterized, often with insufficient data for validation. Here, a process‐based N model, WINTRA, which is coupled to a physically based cold regions hydrological model, was expanded to simulate P and account for overwinter soil nutrient biochemical cycling. An inverse modelling approach, using this model with consideration of parameter equifinality, was applied to an intensively monitored agricultural basin in Manitoba, Canada, to help identify the main climate, soil, and anthropogenic controls on nutrient export. Consistent with observations, the model results suggest that snow water equivalent, melt rate, snow cover depletion rate, and contributing area for run‐off generation determine the opportunity time and surface area for run‐off–soil interaction. These physical controls have not been addressed in existing models. Results also show that the time lag between the start of snowmelt and the arrival of peak nutrient concentration in run‐off increased with decreasing antecedent soil moisture content, highlighting potential implications of frozen soils on run‐off processes and hydrochemistry. The simulations showed TDP concentration peaks generally arriving earlier than NO₃ but also decreasing faster afterwards, which suggests a significant contribution of plant residue Total dissolved Phosphorus (TDP) to early snowmelt run‐off. Antecedent fall tillage and fertilizer application increased TDP concentrations in spring snowmelt run‐off but did not consistently affect NO₃ run‐off. In this case, the antecedent soil moisture content seemed to have had a dominant effect on overwinter soil N biogeochemical processes such as mineralization, which are often ignored in models. This work demonstrates both the need for better representation of cold regions processes in hydrochemical models and the model improvements that are possible if these are included.  相似文献   

A new project to monitor land subsidence in the northern Venice coastland (Italy)   总被引：1，自引：0，他引：1  

Luigi Tosi  Pietro Teatini  Laura Carbognin  Jane Frankenfield 《Environmental Geology》2007,52(5):889-898

The paper deals with the implementation of a levelling and Global Positioning System (GPS) network to control land subsidence in the coastal area north of the Venice Lagoon. About 480 km of levelling lines with 527 benchmarks, 45 of which suited for Differential GPS measurements, were established in 2004. A complete survey of the net was carried out in 2004 soon after its establishment. The 2004 records have been compared with previous scattered data obtained by the use of levelling surveys, DGPS and SAR interferometry. The results show a trend in land settlement that increases from the lagoon margin to the north and jeopardize the Venice coastland. Groundwater withdrawals for domestic, agricultural, and health spas uses, peat oxidation of reclaimed marshlands for farming, natural consolidation of the Holocene deposits, and tectonics of the pre-Quaternary basement are the causes of land subsidence in the study area. Since most of the area lies below the mean sea level and on account of the expected sea level rise due to global change, a detailed monitoring of land displacements in the near future will be of paramount importance to plan necessary works for coastland protection.  相似文献   

Catchment urbanization increases benthic microalgal biomass in streams under controlled light conditions     

Jane A. Catford  Christopher J. Walsh  John Beardall 《Aquatic Sciences - Research Across Boundaries》2007,69(4):511-522

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