200 years of mining activities at La Paz/San Luis Potosí/Mexico - Consequences for environment and geochemical exploration     

Javier Castro-Larragoitia  Utz Kramar  Harald Puchelt 《Journal of Geochemical Exploration》1997,58(1):81-91

The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km² of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm.  相似文献   

Relationship between solar radiation and the development and morphology of small cirque glaciers (Maladeta Mountain massif, Central Pyrenees, Spain)     

Javier Chueca  Asunción Julián 《Geografiska Annaler: Series A, Physical Geography》2004,86(1):81-89

Abstract Spatial and temporal variations in radiative fluxes influence glacier mass‐balance in mountain areas. The primary goal of this study was to assess differences in solar radiation on three glacial cirques located in the Maladeta Mountain massif (Central Spanish Pyrenees), and analyse their implications on glacier development and morphology. A quantitative approach is adopted to obtain the values of solar radiation (direct, diffuse and global radiation), combining several field data parameters (measured at 55 control‐points) with the solar radiation modelling package Ecosim. The data obtained confirm that the morphologies of the glacial bodies developed in the three cirques have a good correlation with the spatial variation on solar radiation inputs, favouring also the conservation (Aneto and Coronas cirques) or total vanishing (Llosás cirque) of the glacial remnants analysed here. The study shows how strongly in this Alpine‐Mediterranean context solar radiation — firstly as a function of latitude and time of year, and locally as a function of topographic slope, aspect and shadowing — controls the mass‐balance and the spatial distribution of melting in small glaciers, having an effect on the development of their morphologies.  相似文献   

Generalized plasticity state parameter‐based model for saturated and unsaturated soils. Part 1: Saturated state     

Diego Manzanal  José Antonio Fernández Merodo  Manuel Pastor 《国际地质力学数值与分析法杂志》2011,35(12):1347-1362

The behavior of granular materials is known to depend on its loose or dense nature, which in turns depends both on density and confining pressure. Many models developed in the past require the use of different sets of constitutive parameters for the same material under different confining pressures. The purpose of this paper is to extend a basic generalized plasticity model for sands proposed by Pastor, Zienkiewicz and Chan by modifying the main ingredients of the model flow—rule, loading–unloading discriminating direction and plastic modulus—to include a dependency on the state parameter. The proposed model is tested against the available experimental data on three different sands, using for each of them a single set of material parameters, finding a reasonably good agreement between experiments and predictions. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Generalized plasticity state parameter‐based model for saturated and unsaturated soils. Part II: Unsaturated soil modeling     

Diego Manzanal  Manuel Pastor  José Antonio Fernández Merodo 《国际地质力学数值与分析法杂志》2011,35(18):1899-1917

The aim of this paper is to extend the generalized plasticity state parameter‐based model presented in part 1 to reproduce the hydro‐mechanical behavior of unsaturated soils. The proposed model is based on two pairs of stress–strain variables and a suitable hardening law taking into account the bonding—debonding effect of suction and degree of saturation. A generalized state parameter for unsaturated state is proposed to reproduce soil behavior using a single set of material parameters. Generalized plasticity gives a suitable framework to reproduce not only monotonic stress path but also cyclic behavior. The hydraulic hysteresis during a drying—wetting cycle and the void ratio effect on the hydraulic behavior is introduced. Comparison between model simulations and a series of experimental data available, both cohesive and granular, are given to illustrate the accuracy of the enhanced generalized plasticity equation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Flood forecasting in the upper Uruguay River basin     

A. S. Fernández Bou  R. Ventura De Sá  M. Cataldi 《Natural Hazards》2015,79(2):1239-1256

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A high-pressure infrared and Raman spectroscopic study of BaCO3: the aragonite,trigonal and Pmmn structures     

Jered Chaney  Javier D. Santillán  Elise Knittle  Quentin Williams 《Physics and Chemistry of Minerals》2015,42(1):83-93

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Evaluation of regional ocean circulation models for the Mediterranean Sea at the Strait of Gibraltar: volume transport and thermohaline properties of the outflow     

Javier Soto-Navarro  Samuel Somot  Florence Sevault  Jonathan Beuvier  Francisco Criado-Aldeanueva  Jesús García-Lafuente  Karine Béranger 《Climate Dynamics》2015,44(5-6):1277-1292

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Assessing the ‘two water worlds’ hypothesis and water sources for native and exotic evergreen species in south‐central Chile          下载免费PDF全文

P. Hervé‐Fernández  C. Oyarzún  C. Brumbt  D. Huygens  S. Bodé  N. E. C. Verhoest  P. Boeckx 《水文研究》2016,30(23):4227-4241

Recent studies using water‐stable isotopes (δ¹⁸O and δ²H) have suggested an ecohydrological separation of water flowing to streams or recharging groundwater and water used by trees, known as the ‘two water worlds’ (TWW) hypothesis. In this study, we measured water isotopic composition in precipitation [open field and throughfall, i.e. local meteoric water line (LMWL)] and the mobile water compartment (i.e. stream and soil solution), bulk soil water and xylem water over a period of 1.5 years in two headwater catchments: NF, covered with old growth native evergreen forest (Aetoxicon punctatum, Laureliopsis philippiana and Eucriphya cordifolia), and EP, covered with 4 and 16‐year‐old Eucalyptus nitens stands. Our results show that precipitation, stream and soil solution plot approximately along the LMWL, while xylem waters from all studied tree species plot below the LMWL, supporting the TWW hypothesis. However, we also found evidence of ecohydrological connectivity during the wet season, likely controlled by the amount of antecedent precipitation. These observations hold for all investigated tree species. On both sites, a different precipitation source for stream and xylem water was observed. However, in EP, bulk soil showed a similar precipitation source as xylem water from both E. nitens stands. This suggests that E. nitens may use water that is recharging the bulk soil compartment. We conclude that under a rainy temperate climate, the TWW hypothesis is temporal and does not apply during wet seasons. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Bismuth‐melt trails trapped in cassiterite–quartz veins     

Frederico Sousa Guimares  Alexandre Raphael Cabral  Bernd Lehmann  Francisco Javier Rios  Moiss Augusto Bacellar vila  Marco Paulo de Castro  Glucia Nascimento Queiroga 《地学学报》2019,31(4):358-365

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.  相似文献   

Upper Cretaceous marine‐continental transition (Leonese Area,NW Spain) defined from integrated outcrop and seismic stratigraphy     

Antonio Herrero‐Hernndez  Fernando Gmez‐Fernndez  Francisco Javier Lpez‐Moro 《Geological Journal》2015,50(1):39-55

The Upper Cretaceous succession of the Leonese Area (NW Spain) comprises mixed clastic and carbonate sediments. This succession is divided into two lithostratigraphic units, the Voznuevo Member and the Boñar Formation, which represent fluvial, shoreface, intertidal, subtidal and open‐shelf sedimentary environments. Regional seismic interpretation and sequence stratigraphic analysis have allowed the study of lateral and vertical changes in the sedimentary record and the definition of third‐order levels of stratigraphic cyclicity. On the basis of these data, the succession can be divided into two second‐order depositional sequences (DS‐1 and DS‐2), incorporating three system tracts in a lowstand to transgressive to highstand system tract succession (LST–TST–HST). These sequences are composed of fluvial systems at the base with palaeocurrents that flowed westward and south‐westward. The upper part of DS‐1 (Late Albian–Middle Turonian) shows evidence of intertidal to subtidal and offshore deposits. DS‐2 (Late Turonian–Campanian) comprises intertidal to subtidal, tidal flat, shallow marine and lacustrine deposits and interbedded fluvial deposits. Two regressive–transgressive cycles occurred in the area related to eustatic controls. The evolution of the basin can be explained by base‐level changes and associated shifts in depositional trends of successive retrogradational episodes. By using isobath and isopach maps, the main palaeogeographic features of DS‐1 and DS‐2 were constrained, namely coastline positions, the existence and orientation of corridors through which fluvial networks were channelled and the location of the main depocentres of the basin. Sedimentation on the Upper Cretaceous marine platform was mainly controlled by (i) oscillations of sea level and (ii) the orientation of Mesozoic faults, which induced sedimentation along depocentres. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献