Environmental assessment of the arsenic-rich,Rodalquilar gold–(copper–lead–zinc) mining district,SE Spain: data from soils and vegetation     

Roberto Oyarzun  Paloma Cubas  Pablo Higueras  Javier Lillo  Willians Llanos 《Environmental Geology》2009,58(4):761-777

The Rodalquilar mineral deposits (SE Spain) were formed in Miocene time in relation to caldera volcanic episodes and dome emplacement phenomena. Two types of ore deposits are recognized: (1) the El Cinto epithermal, Au–As high sulphidation vein and breccia type; and (2) peripheral low sulphidation epithermal Pb–Zn–Cu–(Au) veins. The first metallurgical plants for gold extraction were set up in the 1920s and used amalgamation. Cyanide leaching began in the 1930s and the operations lasted until the mid 1960s. The latter left a huge pile of ~900,000–1,250,000 m³ of abandoned As-rich tailings adjacent to the town of Rodalquilar. A frustrated initiative to reactivate the El Cinto mines took place in the late 1980s and left a heap leaching pile of ~120,000 m³. Adverse mineralogical and structural conditions favoured metal and metalloid dispersion from the ore bodies into soils and sediments, whereas mining and metallurgical operations considerably aggravated contamination. We present geochemical data for soils, tailings and wild plant species. Compared to world and local baselines, both the tailings and soils of Rodalquilar are highly enriched in As (mean concentrations of 950 and 180 μg g⁻¹, respectively). Regarding plants, only the concentrations of As, Bi and Sb in Asparagus horridus, Launaea arborescens, Salsola genistoides, and Stipa tenacissima are above the local baselines. Bioaccumulation factors in these species are generally lower in the tailings, which may be related to an exclusion strategy for metal tolerance. The statistical analysis of geochemical data from soils and plants allows recognition of two well-differentiated clusters of elements (As–Bi–Sb–Se–Sn–Te and Cd–Cu–Hg–Pb–Zn), which ultimately reflect the strong chemical influence of both El Cinto and peripheral deposits mineral assemblages.  相似文献   

A skeleton design theory for spatial data infrastructure     

Rolf A. de By  Rob Lemmens  Javier Morales 《Earth Science Informatics》2009,2(4):299-313

In this paper, we look into the theory of designing geoservice systems, i.e., SDI networks and their constituent SDI nodes. As the field of SDI is strongly about bridging between geoservice systems, interoperability and harmonisation, it is not surprising that standardisation efforts are of crucial importance in it. These efforts have historically addressed abstract and concrete content models for data and metadata exchange, as well as abstract and concrete behavioural models for computational processes. The list of standards that are in use in the SDI field continues to expand, and reaches out to neighbouring fields such as sensor nets. We argue that given these trends, the resulting levels of standardisation in actual systems, and the complexity of geoservice systems in general, it appears only natural to look into the possibility to define a standardised design theory for SDI and its nodes, which addresses the function base and the communication base. Specifically, we provide an overview of those components that need to be designed, and what are their relationships. We do so in an abstract way, focussing on the concern of information content in this paper, and only hinting at an appropriate theory of realisation based on our skeleton theory.  相似文献   

A rootless suture and the loss of the roots of a mountain chain: The Variscan belt of NW Iberia     

José R. Martínez Catalán  Ricardo Arenas  Jacobo Abati  Sonia Sánchez Martínez  Florentino Díaz García  Javier Fernández Suárez  Pablo González Cuadra  Pedro Castiñeiras  Juan Gómez Barreiro  Alejandro Díez Montes  Emilio González Clavijo  Francisco J. Rubio Pascual  Pilar Andonaegui  Teresa E. Jeffries  James E. Alcock  Rubén Díez Fernández  Alicia López Carmona 《Comptes Rendus Geoscience》2009,341(2-3):114-126

Ophiolites of different Paleozoic ages occur in North-West (NW) Iberia in a rootless suture representing the remnants of the Rheic Ocean. Associated allochthonous terranes in the hanging- and foot-walls of the suture derive from the former margins, whereas the relative autochthon corresponds to the Paleozoic passive margin of northern Gondwana. The Paleozoic tectonic evolution of this part of the circum-Atlantic region is deduced from the stratigraphical, petrological, structural and metamorphic evolution of the different units and their ages. The tectonic reconstruction covers from Cambro-Ordovician continental rifting and the opening of the Rheic Ocean to its Middle to Upper Devonian closure. Then, the Variscan Laurussia–Gondwana convergence and collision is briefly described, from its onset to the late stages of collapse associated with the demise of the orogenic roots.  相似文献   

Dense molecular gas in a sample of LIRGs and ULIRGs: The low-redshift connection to the huge high-redshift starbursts and AGNs     

Javier Graciá-Carpio  Santiago García-Burillo  Pere Planesas 《Astrophysics and Space Science》2008,313(1-3):331-335

The sample of nearby LIRGs and ULIRGs for which dense molecular gas tracers have been measured is building up, allowing for the study of the physical and chemical properties of the gas in the variety of objects in which the most intense star formation and/or AGN activity in the local universe is taking place. This characterisation is essential to understand the processes involved, discard others and help to interpret the powerful starbursts and AGNs at high redshift that are currently being discovered and that will routinely be mapped by ALMA. We have studied the properties of the dense molecular gas in a sample of 17 nearby LIRGs and ULIRGs through millimeter observations of several molecules (HCO⁺, HCN, CN, HNC and CS) that trace different physical and chemical conditions of the dense gas in these extreme objects. In this paper we present the results of our HCO⁺ and HCN observations. We conclude that the very large range of measured line luminosity ratios for these two molecules severely questions the use of a unique molecular tracer to derive the dense gas mass in these galaxies.  相似文献   

A regional monthly precipitation simulation model based on an L-moment smoothed statistical regionalization approach     

Javier González  Juan B. Valdés 《Journal of Hydrology》2008,348(1-2):27-39

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Diversity patterns along and across the Chilean margin: a continental slope encompassing oxygen gradients and methane seep benthic habitats     

Javier Sellanes  Carlos Neira  Eduardo Quiroga  & Núria Teixido 《Marine Ecology》2010,31(1):111-124

In the present study we review datasets available for the Chilean margin to assess the relationship between environmental (or habitat) heterogeneity and benthic diversity. Several factors, such as the presence of different water masses, including the oxygen-deficient Equatorial Sub-surface Waters (ESSW) at the continental shelf and upper slope, and the Antarctic Intermediate Waters (AIW) at mid slope depths appear to control the bathymetric distribution of benthic communities. The presence of methane seeps and an extended oxygen minimum zone (OMZ) add complexity to the benthic distribution patterns observed. All these factors generate environmental heterogeneity, which is predicted to affect the diversity patterns both along and across the Chilean continental margin. The response to these factors differs among different faunal size groups: meio-, macro-, and megafauna. Physiological adaptations to oxygen deficiency and constraints related to body size of each group seem to explain the larger-scale patterns observed, while sediment/habitat heterogeneity ( e.g. at water mass boundaries, hardgrounds, biogeochemical patchiness, sediment organic content, grain size) may influence the local fauna diversity patterns.  相似文献   

Cenomanian events in the deep western Basque Basin: the Leioa section     

Julio Rodriguez-Lázaro  Ana Pascual  Javier Elorza 《Cretaceous Research》1998,19(6):673-700

Analysis of the microfaunas (foraminifera, ostracods) and the stable isotope values (δ¹³C, δ¹⁸O) of the Leioa section, as representative of the deep Basque Basin, has allowed us to propose a detailed palaeoenvironmental reconstruction of this region during the Cenomanian, as well as to register global chronostratigraphic reference levels to facilitate interregional correlations. During the Cenomanian, part of the basin, the Plentzia Trough, was occupied by intermediate water masses, as deduced by the relative percentages of planktonic (Rotalipora) and benthonic foraminifera. A noticeable change is observed at the middle-late Cenomanian transition: the replacement of the dominance of keeled (rota-liporids) by incipiently-keeled (dicarinellids, praeglobotruncanids) planktonic foraminifera, indicative of the new influence of the upper intermediate waters. The temporary effect of shallow waters is deduced in one interval of the latest early Cenomanian and two more of the middle Cenomanian, as indicated by the dominance of globular planktonic foraminifera (hedbergellids). These water masses were moderately to strongly hypoxic (<4 to <2 ml/l of disolved oxygen) after the ostracod platycopid signal and benthonic foraminiferal hypoxic indicators. The dysaerobia may have been particulary strong (almost anoxia?) during part of the middle Cenomanian. Micronutrient availability was also restricted during several intervals of the middle Cenomanian, as indicated by the sudden decrease in the species diversity of the calcitic benthonics during the period when increased trends of the δ¹³C isotopic signals are observed. The combination of both hypoxia and nutrient depletion produced drastic changes in the microfaunal assemblages, with emigrations and local extinctions, showing benthonic perturbations from the time indicated by the base of theRotalipora reicheliZone onwards. From the beginning until the end of the middle Cenomanian, eleven of these perturbations are recorded as regional bioevents, using as bioevent-markers, intervals where microfauna was absent (including benthic-free intervals, B-FI; benthonic calcitic-free intervals, BC-FI; and ostracod-free intervals, O-FI). These changes led to the renewal of the microfaunas; benthonic foraminifera renewed their specific stocks during the early to early middle Cenomanian, with planktonic foraminifera and ostracods undergoing renewal at the end of the middle Cenomanian. Isotope values of δ¹⁸O and δ¹³C are consistent with the palaeoenvironmental changes detected by the microfaunas; their maximum and minimum shifts coincide with the bioevents. The double-peaked positive shift of δ¹³C for the mid-Cenomanian of northwest Europe (Jenkynset al., 1994; Paulet al., 1994a) has been recognized in this series of the Basque Basin. The palaeoenvironmental perturbations deduced in the Cenomanian of the Leioa section are attributed essentially to palaeoceanographic changes, where intermediate water masses profoundly influenced the planktonic and benthonic ecosystems. The influence of other local causes, such as volcanic activity at that time, or tectonics between the Iberian and European plates, are more difficult to prove. Several of the bioevents defined in the middle Cenomanian of this basin could probably be global in nature, and thus may be useful for establishing interregional correlations.  相似文献   

SIPVADE: A New Computer Programme with Seventeen Statistical Tests for Outlier Detection in Evaluation of International Geochemical Reference Materials and its Application to Whin Sill Dolerite WS-E from England and Soil-5 from Peru   总被引：1，自引：0，他引：1  

Surendra P. Verma  Leonides Javier Orduña-Galván  Mima Guevara 《Geostandards and Geoanalytical Research》1998,22(2):209-234

A new computer programme was written in programming language TURBOC, which enables us to apply a procedure involving seventeen statistical tests (a total of sixty five single or multiple outlier versions of these tests) for outlier detection in univariate sample at a high confidence level of 99% (significance level α= 0.01). The outlying observations should be evaluated first for technical reasons and then rejected manually from the data base until no more outliers are detected and the final statistical parameters are computed from the remaining data. This programme has been used successfully to process two reference material data bases: WS-E from England and Soil-5 from Peru. The final mean values for WS-E are more reliable (characterized by smaller standard deviations and narrower confidence limits) than those obtained earlier using a different statistical approach. The application of a large number of statistical tests to Soil-5 also resulted in smaller standard deviation values for most elements than the method involving a limited number of such tests. For WS-E, some laboratories seem to have produced multiple data that were detected as statistical outliers. A close analysis of the distribution of outliers as a function of laboratory, country and analytical method leads to a technical justification for these outlying observations, probably in terms of inadequate QA/QC practices. Use of geochemical criteria indicates that the new mean values in WS-E might be closer to the "true" concentrations. This procedure of outlier detection and elimination is therefore recommended in the study of the existing RM.  相似文献   

The Detritic Compartment in a Posidonia oceanica Meadow: Litter Features, Decomposition Rates, and Mineral Stocks     

Javier  Romero  Gérard  Pergent  Christine  Pergent-Martini  Miguel-Angel  Mateo Cécile  Regnier 《Marine Ecology》1992,13(1):69-83

Abstract. The ecosystem associated to the Mediterranean seagrass Posidonia oceanica shows a clear distinction in two subcompartments regarding turnover time: aboveground and belowground. Aboveground parts (leaves) are highly dynamic, and most of the leaf material is decomposed or exported in less than one year, representing a net loss of nutrients. In contrast, belowground biomass (roots and rhizomes) has a turnover time of the order of centuries, with a consequent accumulation of organic matter in the sediment. The accumulation rates for the single elements rank in the order C > N > P. This ecosystem may be considered as a sink for biogenic elements.  相似文献   

ENSO as a natural experiment to understand environmental control of meiofaunal community structure   总被引：2，自引：0，他引：2  

Javier Sellanes  & Carlos Neira 《Marine Ecology》2006,27(1):31-43

The sediments of the Bay of Concepción and the adjacent shelf underlie one of the most productive upwelling areas in the SE Pacific margin. Reports on factors controlling meiofaunal community structure in these kinds of organic‐rich and oxygen‐deficient habitats are scarce in the literature. In this study, five sites along a transect from the mid‐Bay of Concepción (27 m) to the outer shelf (120 m) were studied on fives dates (May, August, November 1997, and March and May 1998) in order to assess the dynamic relationships between sedimentary organic matter and metazoan meiofauna. The sampling period coincided with the 1997–1998 El Niño event. Sediment parameters investigated were the redox potential discontinuity depth, photosynthetic pigment concentrations (chlorophyll a and phaeopigments), organic carbon, nitrogen, total lipids, carbohydrates, and proteins. In general, lowest values of meiofauna abundance and biomass were found within the naturally eutrophic Bay of Concepción and towards the shelf break, while maximum values occurred at intermediate depths. During the whole period, the meiofaunal abundance was negatively correlated with the concentration of most of the biochemical components of organic matter, as well as with the sediment phaeopigment content. However, positive correlations were found with chlorophyll a derived indices and with bottom‐water oxygen content. Most of the sediment parameters displayed a seasonal cycle, but towards the beginning of 1998, an effect of the 1997–1998 El Niño was evident. Typical austral‐summer (i.e. oxygen‐deficient) conditions did not develop, and sedimentary parameters reflected a decreased input of phytodetritus. Along the transect, the magnitude of this effect on meiofauna varied among sites. An overall positive response, in terms of meiofaunal abundance was observed, probably due to the amelioration of low oxygen conditions in the sediment.  相似文献