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81.
Inclement weather creates a chronic hazard for Canadian travellers. Past studies indicate that road collision rates increase during precipitation, although the magnitude of theincrease varies from study to study, partly as a result of variations in weather and driving conditions,but also because of differences in methods. The goal of the current study is to improve ourunderstanding of the links between weather and travel risk in mid-sized Canadian cities by using astandardized method for analyzing data from six cities with different climates: Halifax-Dartmouth,Ottawa, Québec, Hamilton, Waterloo Region, and Regina. The study has four interrelated objectives: (1) Toconduct a sensitivity analysis to determine the extent to which risk estimates vary depending onthe criteria used to define precipitation events and `normal' conditions; (2) To compare therelative risk of collision and injury during precipitation relative to `normal' conditions; (3) Todetermine the extent to which weather-related risks vary fordifferent Canadian cities; and (4) To explore any differences in collision characteristics between events and controls, especially as theyvary from city to city. Results are based on a matched-pair analysis, using six-hour time blocks over afour-year period, 1995 to 1998. Results indicate only modest sensitivity to the criteria used to define precipitation events and `normal' conditions. On average, precipitation is associated with a 75 percentincrease in traffic collisions and a 45 percent increase in related injuries, as compared to `normal'seasonal conditions, but risk levels vary depending on the characteristics of the weather event.Both sensitivity to specific weather conditions and weather-related accident profiles vary from city tocity in ways that are not easily explained. 相似文献
82.
Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C60, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C70 was detected, nor was C60 found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C60 in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation. 相似文献
83.
Given the present commitment of the developed countries according to the Kyoto Protocol, most published scenarios demonstrate that global greenhouse gases concentrations would not be stabilized at any level. In order to stabilize these concentrations, a deeper global involvement is needed. Taking Israel as an example of a `recently-developed' country, we assess the role that such countries could play by assuming voluntary commitments in strengthening global involvement. This case as a model may encourage a global scheme for curbing carbon emissions, in which the more developed countries assume a stronger role and the less developed countries participate according to the principle of common but differentiated responsibility. The scheme builds on the inverse relation that exists between the per capita gross domestic product and the rate of increase of emissions due to economic growth. According to this theoretical scheme, the voluntary commitments assumed by the `recently-developed' countries encourage the more developed countries to deepen their involvement by assuming more stringent reductions of emissions at home and transferring technological and financial means to the less developed countries. The proposed scheme would enable non-Annex I countries, both `recently-developed' countries and less developed countries, to participate much earlier in the net mitigation of greenhouse gases. 相似文献
84.
The Archean Shawmere anorthosite lies within the granulite facies portion of the Kapuskasing Structural Zone (KSZ), Ontario,
and is crosscut by numerous linear alteration veins containing calcite + quartz ± dolomite ± zoisite ± clinozoisite ± margarite ±paragonite ± chlorite.
These veins roughly parallel the trend of the Ivanhoe Lake Cataclastic Zone. Equilibria involving clinozoisite + margarite + quartz ± calcite
± plagioclase show that the vein minerals were stable at T < 600 °C, XCO2 < 0.4 at P ≈ 6 kbar. The stabilities of margarite and paragonite in equilibrium with quartz are also consistent with T < 600 °C and XCO2 < 0.4 at 6 kbar. Additional assemblages consisting of calcite + clinochlore + quartz + talc + margarite indicate T < 500 °C with XCO2 > 0.9. Thus, vein formation, while clearly retrograde, spanned a range of temperatures, and fluid compositions evolved from
H2O-rich to CO2-rich. The calcite in the retrograde veins has δ18O values that range from 8.4 to 11.2‰ (average = +9.7 ± 0.9‰) and δ13C values that range from −3.9 to −1.6‰ (average = −3.1 ± 0.6‰). These values indicate that the fluids from which calcite precipitated
underwent extensive exchange with the anorthosite and other crustal lithologies. The fluids may have been initially derived
either from devolatilization of metamorphic rocks or crystallization of igneous rocks in the adjacent Abitibi subprovince.
Vein quartz contains CO2-rich fluid inclusions (final melting T = −57.0 to −58.7 °C) that range in size from 5 to 17 μm. Measured homogenization temperatures (T h) range from −44.0 to 14.5 °C, however for most inclusions (46 of S1), T h = −44.0 to −21.1 °C (ρCO2 ≈ 1.13 to 1.05 g/cm3). At 400 to 600 °C, these densities correspond to pressures of 3.5 to 7 kbar, which is the best estimate of pressures of
vein formation. It has been argued that some high density CO2-rich fluid inclusions found in the KSZ were formed during peak metamorphism and thus document the presence of a CO2-rich fluid during peak granulite facies metamorphism (Rudnick et al. 1984). The association of high density CO2-rich fluid inclusions with clearly retrograde veins documents the formation of similar composition and density inclusions
after the peak of metamorphism. Thus, the coincidence of entrapment pressures calculated from fluid inclusion density measurements
with peak metamorphic pressures alone should not be considered strong evidence for peak metamorphic inclusion entrapment.
All fluid inclusion results are consistent with an initially semi-isobaric retrograde P–T path.
Received: 2 April 1996 / Accepted: 15 November 1996 相似文献
85.
Re-Os Isotopic Measurements at the Femtomole Level in Natural Samples 总被引:17,自引:0,他引:17
Jean Louis Birck Matthieu Roy Barman Françoise Capmas 《Geostandards and Geoanalytical Research》1997,21(1):19-27
Here we describe a new chemical separation method for Os and an improved mass spectrometric procedure for Re and Os. This technique is based on the selective extraction of OsO4 from aqueous solution in liquid bromine. Among other advantages, this procedure avoids the cumbersome distillation procedure for Os and uses only commercial "off the shelf" PFA teflon labware. Blank levels for 0.5 g sample sizes are: 0.06 pg and 0.5 pg for Os and Re respectively. Samples containing as little as 1 pg g−1 Os can be analysed reliably with this method. Adaptation to other dissolution methods is also discussed. 相似文献
86.
87.
88.
89.
Edouard Bard Grant M. Raisbeck Franoise Yiou Jean Jouzel 《Earth and Planetary Science Letters》1997,150(3-4):453-462
For about the last 30 years it has been recognized that the high frequency component of the tree rings 14C/12C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric 14C/12C. During the last millennium other periods of high 14C/12C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic 10Be measured in ice from the South Pole to check the solar origin of the observed 14C/12C variations. In order to compare quantitatively the results obtained on 10Be and 14C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of 14C. As an input to a 12-box numerical model we used the relative fluctuations of the 10Be concentrations record measured in South Pole ice and converted it into a synthetic 14C record. We took into account the fact that 10Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled 14C record are much smaller (a factor of 20) than those observed for the raw 10Be record. In addition, the variations are smoother and shifted in time by a few decades. The 10Be-based 14C variations closely resemble the 14C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal 14C/12C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the 10Be-based 14C and the tree-ring 14C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium. 相似文献
90.
Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function.
This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients
from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance
model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns
out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of
eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the
2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance
function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields
with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial
interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the
predefined covariance functions are evaluated. 相似文献