An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution     

Gleb S Pokrovski  Jacques SchottJean-Louis Hazemann  François Farges  Oleg S Pokrovsky 《Geochimica et cosmochimica acta》2002,66(24):4203-4222

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.  相似文献   

Where the buffalo roam: Boundaries and the politics of scale in the yellowstone region     

Jean Lavigne 《GeoJournal》2002,58(4):285-292

For more than twenty years, the state of Montana has pursued a controversial policy of lethal control to manage winter migrations of bison from Yellowstone National Park. In the late 1990s, as the state and a number of federal agencies attempted to cooperatively outline a more palatable scenario for bison management, local environmental groups became active participants in the debate. This paper examines the strategies pursued by these organizations in the course of their attempt to construct a new, ecosystem-level territorial space and jurisdictional scale for bison, and places their struggle within the context of existing work in geography on the politics of scale. Ultimately, the failure of their efforts illustrates some of the important constraints faced by social groups that attempt to create new territorial regimes and new scales of resistance in the interstices of existing political structures.  相似文献   

Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28   总被引：1，自引：0，他引：1  

Jean S. Kane 《Geostandards and Geoanalytical Research》2002,26(1):7-29

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.  相似文献   

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing     

Klaus Kümmerer  Ali Al‐Ahmad  Almut Henninger 《洁净——土壤、空气、水》2002,30(4):171-178

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period     

Jean‐Jacques Macaire  Saïda Bellemlih  Christian Di‐Giovanni  Patrick De Luca  Lionel Visset  Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Comparison between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr     

Jacques Bourgois  François Michaud 《Earth and Planetary Science Letters》2002,201(1):35-44

When combined with the Miocene-Recent volcanic record of Baja California, a parallel drawn between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr. The slab-free zone manifestations challenge the notion that ridge subduction has not occurred beneath the southern Baja California peninsula. The geochemically distinctive rocks from the Santa Clara volcanic field of west-central Baja California, including coeval adakites and niobium-enriched basalt, are commonly inferred to signal partial melting of the subducting plate at shallow depths and relatively high temperatures, before slab dehydration occurs. Such PT conditions for slab melting have only been observed in association with spreading-ridge subduction. We propose that slab window development beneath southern Baja California and mainland Mexico (30° to 18°N) resulted from subduction of the East Pacific rise.  相似文献   

La « Mission d'Andalousie », expédition géologique de l'Académie des sciences de Paris à la suite du grand séisme de 1884The ‘Mission d'Andalousie’, a geological expedition of the French Academy of Sciences,following the great Andalusian earthquake of 1884     

Jean Bonnin  Michel Durand-Delga  André Michard 《Comptes Rendus Geoscience》2002,334(10):795-808

  相似文献   

Le Bassin lusitanien (Portugal) à l'Aptien supérieur–Albien : organisation séquentielle,proposition de corrélations, évolutionThe Lusitanian Basin (Portugal) during the late Aptian–Albian: sequential arrangement,proposal of correlations,evolution     

Jorge Dinis  Jacques Rey  Pierre-Charles de Graciansky 《Comptes Rendus Geoscience》2002,334(10):757-764

. Three transgressive–regressive 2nd-order cycles were identified in the Upper Aptian–Albian fluvial and marine deposits of the Lusitanian Basin. Its widespread nature, probably including eustatic origin, allows correlation between the southern package, with precise stratigraphic positioning, and the northern series with a poorly constrained age. The main unconformities can be related to the onset of an oceanic crust, in the western margin of Galicia during the Late Aptian, in the bay of Biscay during the Early Albian, and, to the northwest of the Galicia triple point, during the Middle to Late Albian transition, and, at the Albian–Cenomanian boundary, to a probable compressive event with Africa due to the rotation of Iberia. To cite this article: J. Dinis et al., C. R. Geoscience 334 (2002) 757–764.  相似文献   

Soulèvement et plissement tectoniques révélés par analyse mathématique empirique de profils longitudinaux de rivières : un cas à TaiwanEmpirical mathematical analysis of longitudinal river profiles reveals tectonic uplift and folding: a case in Taiwan     

Jacques Angelier  Rou-Fei Chen 《Comptes Rendus Geoscience》2002,334(15):1103-1111

We analyse longitudinal river profiles in southwestern Taiwan. As all necessary data are not available, a physical modelling of river erosion would be subject to large uncertainties. We thus shortcut this modelling and adopt simple empirical exponential equations giving riverbed elevation as a function of downstream distance. We identify a positive altimetric anomaly, which reveals active uplift of an anticline at the front of the fold-and-thrust belt. To cite this article: J. Angelier, R.-F. Chen, C. R. Geoscience 334 (2002) 1103–1111.  相似文献   

Asymmetric one‐storey elastic systems with non‐linear viscous and viscoelastic dampers: Simplified analysis and supplemental damping system design     

Wen‐Hsiung Lin  Anil K. Chopra 《地震工程与结构动力学》2003,32(4):579-596

Investigated is the accuracy in estimating the response of asymmetric one‐storey systems with non‐linear viscoelastic (VE) dampers by analysing the corresponding linear viscous system wherein all non‐linear VE dampers are replaced by their energy‐equivalent linear viscous dampers. The response of the corresponding linear viscous system is determined by response history analysis (RHA) and by response spectrum analysis (RSA) extended for non‐classically damped systems. The flexible and stiff edge deformations and plan rotation of the corresponding linear viscous system determined by the extended RSA procedure is shown to be sufficiently accurate for design applications with errors generally between 10 and 20%. Although similar accuracy is also shown for the ‘pseudo‐velocity’ of non‐linear VE dampers, the peak force of the non‐linear VE damper cannot be estimated directly from the peak damper force of the corresponding linear viscous system. A simple correction for damper force is proposed and shown to be accurate (with errors not exceeding 15%). For practical applications, an iterative linear analysis procedure is developed for determining the amplitude‐ and frequency‐dependent supplemental damping properties of the corresponding linear viscous system and for estimating the response of asymmetric one‐storey systems with non‐linear VE dampers from the earthquake design (or response) spectrum. Finally, a procedure is developed for designing non‐linear supplemental damping systems that satisfy given design criteria for a given design spectrum. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献