Electrochemistry of reduced sulfur species in natural waters—I. The H2S-H2O system     

Jacques Boulègue 《Geochimica et cosmochimica acta》1978,42(9):1439-1445

Careful measurements of rest potentials of platinum electrodes (Eh) in the H₂S-H₂O system were made together with measurements of the pH and the potentials of Ag-Ag₂S electrodes (E_s^2?). The potentials of the platinum electrode are characteristic of H₂S chemisorption followed by H₂S discharge on the platinum. The relations between Eh, E_s^2? and pH are characteristic of the H₂S-H₂O system and of the hydrogen sulfide concentration. Thus these parameters can be employed to distinguish H₂S-H₂O systems from H₂S-S₈-H₂O systems. Field measurements on hot sulfurous springs are in agreement with laboratory data.  相似文献   

A time evolution study of limb spicule spectra     

Kenneth R. Krall  R. J. Bessey  Jacques M. Beckers 《Solar physics》1976,46(1):93-114

Time sequences of simultaneous spectra of limb spicules, obtained using the Sacramento Peak Observatory's tower telescope and echelle spectrograph are analyzed. Intensity determinations of H and K, H, 8498 and 8542 of calcium are tabulated for three observing heights. Electron densities averaged over the entire visible lifetimes of spicules are -6 × 10¹⁰ cm^–3 at observing heights of 6000km, while maximum and minimum values were -1.1 × 10¹¹ cm^–3 at 6000km and - 2 × 10¹⁰ cm^–3 at 10000km. Electron temperatures range between 12 000 K and 16 000 K. Profile halfwidths indicate turbulent velocities of 12 to 22 km s^–1, and spectral tilts are interpreted as caused by differential velocity fields of -3 km s^–1 per 1000 km. No large scale spicule expansions or contractions are observed, although possible expulsions or accretions of material are observed. Spicules may be wider in the calcium K and H lines than in H.Now at School of Science and Engineering, The University of Alabama in Huntsville, Huntsville, Alabama.  相似文献   

Modelling weathering processes at the catchment scale: The WITCH numerical model     

Yves Goddéris  Louis M. François  Jacques Schott  David Labat 《Geochimica et cosmochimica acta》2006,70(5):1128-1147

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.  相似文献   

Tripartite climate reversal in Central Europe 5600-5300 years ago     

Michel Magny  Urs Leuzinger  Jean Nicolas Haas 《Quaternary Research》2006,65(1):3-19

The history of variations in water level of Lake Constance, as reconstructed from sediment and pollen analysis of a sediment sequence from the archaeological site of Arbon-Bleiche 3, shows an abrupt rise in lake level dendrochronologically dated to 5375 yr ago (5320 yr relative to AD 1950). This event, paralleled by the destruction of the Neolithic village by fire, provoked the abandonment of this prehistoric lake-shore location established in the former shallow bay of Arbon-Bleiche, and was the last of a series of three episodes of successively higher lake level, the first occurring at 5600-5500 cal yr B.P. The dendrochronologically dated rise event was synchronous with an abrupt increase in atmospheric ¹⁴C. This supports the hypothesis of an abrupt climate change forced by varying solar activity. Moreover, the three successive episodes of higher lake level between 5600 and 5300 cal yr B.P. at Arbon-Bleiche 3 coincided with climatic cooling and/or changes in moisture conditions in various regions of both hemispheres. This period corresponds to the mid-Holocene climate transition (onset of the Neoglaciation) and suggests inter-hemispheric linkages for the climate variations recorded at Arbon-Bleiche 3. This mid-Holocene climate reversal may have resulted from complex interactions between changes in orbital forcing, ocean circulation and solar activity. Finally, despite different seasonal hydrological regimes, the similarities between lake-level records from Lake Constance and from Jurassian lakes over the mid-Holocene period point to time scale as a crucial factor in considering the possible impact of climate change on environments.  相似文献   

Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado     

Miriam Borba-Roschel  Anne Alexandre  Anglica Fortes Drummond Chicarino Varajo  Jean Dominique Meunier  Csar Augusto Chicarino Varajo  Fabrice Colin 《Journal of Geochemical Exploration》2006,88(1-3):172

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.  相似文献   

Structural similarity and variety at the tips in a wide range of strike–slip faults: a review     

Young‐Seog Kim  David J. Sanderson 《地学学报》2006,18(5):330-344

Strike–slip faults are often accompanied by a variety of structures, particularly at their tips. The zones of additional fracturing are classified as tip‐damage zones. These zones can be subdivided into several different damage patterns based on the nature and orientation of faults and fractures developed. Damage zones at the ends of small strike–slip faults (mode II tips) develop wing cracks, horsetail splays, antithetic faults, synthetic branch faults and solution surfaces. Similar tip‐damage patterns are also commonly observed at larger (regional) scales, but with a dominance of faulting over tensile cracks and solution surfaces. Wing cracks and horsetail splays developed at small‐scale faults are replaced by normal faults in large‐scale faults. Antithetic faults and synthetic branch faults are observed at small and large scales. Thrust faults are developed at large scales, in a similar pattern to solution surfaces at a small scale. All these structures may show slightly different angular relationships to the master fault at small and large scale, but develop in response similar stress distribution and mechanics around the fault. Thus, mode II tip‐damage zones show similar patterns over a wide range of fault scales.  相似文献   

Zircon geochronology and Sm–Nd isotopic study: Further constraints for the Archean and Paleoproterozoic geodynamical evolution of the southeastern Guiana Shield, north of Amazonian Craton, Brazil     

Lúcia T. da Rosa-Costa  Jean M. Lafon  Claude Delor 《Gondwana Research》2006,10(3-4):277-300

The eastern part of the Guiana Shield, northern Amazonian Craton, in South America, represents a large orogenic belt developed during the Transamazonian orogenic cycle (2.26–1.95 Ga), which consists of extensive areas of Paleoproterozoic crust and two major Archean terranes: the Imataca Block, in Venezuela, and the here defined Amapá Block, in the north of Brazil.

Pb-evaporation on zircon and Sm–Nd on whole rock dating were provided on magmatic and metamorphic units from southwestern Amapá Block, in the Jari Domain, defining its long-lived evolution, marked by several stages of crustal accretion and crustal reworking. Magmatic activity occurred mainly at the Meso-Neoarchean transition (2.80–2.79 Ga) and during the Neoarchean (2.66–2.60 Ga). The main period of crust formation occurred during a protracted episode at the end of Paleoarchean and along the whole Mesoarchean (3.26–2.83 Ga). Conversely, crustal reworking processes have dominated in Neoarchean times. During the Transamazonian orogenic cycle, the main geodynamic processes were related to reworking of older Archean crust, with minor juvenile accretion at about 2.3 Ga, during an early orogenic phase. Transamazonian magmatism consisted of syn- to late-orogenic granitic pulses, which were dated at 2.22 Ga, 2.18 Ga and 2.05–2.03 Ga. Most of the ε_Nd values and T_DM model ages (2.52–2.45 Ga) indicate an origin of the Paleoproterozoic granites by mixing of juvenile Paleoproterozoic magmas with Archean components.

The Archean Amapá Block is limited in at southwest by the Carecuru Domain, a granitoid-greenstone terrane that had a geodynamic evolution mainly during the Paleoproterozoic, related to the Transamazonian orogenic cycle. In this latter domain, a widespread calc-alkaline magmatism occurred at 2.19–2.18 Ga and at 2.15–2.14 Ga, and granitic magmatism was dated at 2.10 Ga. Crustal accretion was recognized at about 2.28 Ga, in agreement with the predominantly Rhyacian crust-forming pattern of the eastern Guiana Shield. Nevertheless, T_DM model ages (2.50–2.38 Ga), preferentially interpreted as mixed ages, and ε_Nd < 0, point to some participation of Archean components in the source of the Paleoproterozoic rocks. In addition, the Carecuru Domain contains an oval-shaped Archean granulitic nucleus, named Paru Domain. In this domain, Neoarchean magmatism at about 2.60 Ga was produced by reworking of Mesoarchean crust, as registered in the Amapá Block. Crustal accretion events and calc-alkaline magmatism are recognized at 2.32 Ga and at 2.15 Ga, respectively, as well as charnockitic magmatism at 2.07 Ga.

The lithological association and the available isotopic data registered in the Carecuru Domain suggests a geodynamic evolution model based on the development of a magmatic arc system during the Transamazonian orogenic cycle, which was accreted to the southwestern border of the Archean Amapá Block.  相似文献   

On the origin of rock fragment mulches on Vertisols: A case study from the Ethiopian highlands   总被引：1，自引：2，他引：1  

Jan Moeyersons  Jan Nyssen  Jean Poesen  Jozef Deckers  Mitiku Haile 《Geomorphology》2006,76(3-4):411-429

Many Vertisols in Tigray, Ethiopia, typically carry a discontinuous rock fragment (RF, size 0.5–> 40 · 10^− 2 m) cover with 10 to 100 RFs m^− 2. Such RF mulches are of agricultural and environmental significance because they influence the water balance in the underlying soils and the crop yield. Natural RF concentrations are mostly considered as eolian or hydraulic lag deposits, or as the result of lateral transport over the soil surface from a rock outcrop, upslope. In cultivated areas RF mulches can develop by tillage.This paper presents the case of a natural RF mulch whose lithology indicates that the RFs are up-squeezed by the local Vertisol. The study site is located in the pass of Enda Maryam, Tigray, Northern Ethiopia (39°8′ E and 13°36′ N). A circular area of 10 m diameter, about 200 m away from the water divide in the valley has been cleared annually between 01/1999 and 05/2003. During this period, 625 RFs, 17 being > 7.5 · 10^− 2 m in size, totalling a mass of nearly 62 kg, have been collected. After correction for measurement procedures, the rate of RF up-warping by the Vertisol at Enda Maryam is assessed at 5 RFs m^− 2 in 3 years. At this rate of appearance, the formation of current RF concentrations on top of active valley Vertisols is only a matter of 10^1–2 years, provided the availability of RFs below the soil surface.Although important underground displacements were measured in the Vertisol between 01/1999 and 05/2002, the supposed link between up-squeezing of RFs and plastic deformations of ‘chimney’, ‘diapir’ or ‘intrusion’-like type in the Vertisol could not be evidenced. Instead, RFs are clearly concentrated on the soil surface as well as in depth, along the existing vertical desiccation cracks, often > 1 m deep which display polygonal configurations at the soil surface. Further, bundles of slickensides containing some RFs, have been mapped at the base of the Vertisol. The slickenside configuration suggests that the RF-bearing substrate is being scraped off.While the underground displacement of RFs along active slickensides seems normal, the process of RFs ascending in ‘upright’ position in the edge of desiccation cracks needs explanation. The closure of a desiccation crack is a peristaltic-like movement, following ascent or descent of the capillary fringe. It is hypothesized that this movement gradually pushes the RF to the surface or to another place or level in the soil profile where the crack closes in last instance.The apparent young age of the valley Vertisol mulches in Ethiopia might indicate the very recent formation of yearly recurrent desiccation cracks of Vertisols in the area. Available information confirms that most valleys in the study area used to be perennially marshy. Under these conditions no movements of RFs in the soil profile are expected to occur. Gullying, leading to pronounced seasonal desiccation of the Vertisols, started in several cases not more than 50 years ago.  相似文献   

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*     

Karen E. Smoyer‐Tomic  John C. Spence  Carl Amrhein 《The Professional geographer》2006,58(3):307-326

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.  相似文献   

Deformability characteristics of brazilian laterites     

Jacques De Medina  Laura M. G. Motta  João D. G. Dos Santos 《Geotechnical and Geological Engineering》2006,24(4):949-971

This paper summarizes the resilient and permanent deformation characteristics of laterite gravels, determined by cyclic loading in triaxial tests of compacted specimens. A study of laterite pavements was carried out on eight paved road sections in the state of Mato Grosso. Also reported is the influence of fine sand admixture, specimen size and soaking in two laterite samples from Roraima and Rondônia in the North of Brazil. The experimental relationships of resilient moduli against applied stresses are interpreted empirically for models what may be incorporated in a structural analysis of full depth of laterite pavement.  相似文献