Cordierite-garnet-H2O equilibrium: A geological thermometer,barometer and water fugacity indicator     

Jacques Martignole  Jean -Charles Sisi 《Contributions to Mineralogy and Petrology》1981,77(1):38-46

The high-grade assemblage Cd-Ga-Si-Qz can be thermodynamically modelled from available calorimetric data on the metastable reaction: (I) $$3 MgCd \rightleftarrows 2 Py + 4 Si + 5 Qz$$ naturalK _D ^Fe-Mg between garnet and cordierite and experimental results on cordierite hydration. In the system SiO₂-Al₂O₃-MgO-H₂O, reaction (I) becomes (II) $$3 MgCd \cdot nH_2 O \rightleftarrows 2 Py + 4 Si + 5 Qz + 3 nH_2 O$$ . However, hydrous cordierite is neither a hydrate nor a solid solution between water and anhydrous cordierite and when nH₂O (number of moles of H₂O in Cd) is plotted against \(P_{H_2 O} \) , the resulting isotherms are similar to adsorption isotherms characteristic of zeolitic minerals. Reaction (II) can thus be considered as a combination of reaction (I) with a physical equilibrium of the type nH₂O (in Cd)?nH₂O (in vapor phase). Starting from a point on equilibrium (I), introduction of H₂O into anhydrous Mg-cordierite lowers the chemical potential of MgCd and hence stabilizes this mineral to higher pressure relative to the right-hand assemblage in reaction (I). The pressure increment of stabilization,ΔP, above the pressure limit of anhydrous cordierite stability at constantT, has been calculated using the standard thermodynamics of adsorption isotherms. Cordierite is regarded as a mixture of Mg₂Al₄Si₅O₁₈ and H₂O. The activity of H₂O in the cordierite is evaluated relative to an hypothetical standard state extrapolated from infinite H₂O dilution, by using measured hydration data. The activity of Mg₂Al₄Si₅O₁₈ in the cordierite is then obtained by integration of the Gibbs-Duhem equation, and the pressure stabilization increment,ΔP, computed by means of the relation: $$\Delta V_s \Delta P \cong - RT\ln a_{MgCd}^{MgCd \cdot nH2O} \left( {\Delta V indepentdent of P and T} \right)$$ . Thus, one may contour theP-T plane in isopleths of nH₂O=constant within the area of Mg-cordierite stability allowed by the hydration data for \(P_{H_2 O} = P_{total} \) . The present model indicates greater stabilization of cordierite by H₂O than the model of Newton and Wood (1979) and the calculated curve for metastable breakdown of hydrous MgCd is consistent with experimental data on cordierite breakdown at \(P_{H_2 O} = P_{total} \) . Mg/(Mg+Fe) isopleths have been derived for cordierites of varying nH₂O in the SiO₂-Al₂O₃-MgO-FeO-H₂O system using the additional assumptions that (Fe, Mg) cordierite and (Fe, Mg) garnet behave as ideal solutions, and that typical values of the distribution coefficient of Fe and Mg between coexisting garnet and cordierite observed in natural parageneses can be applied to the calculations. The calculated stable breakdown curve of Fe-cordierite under conditions of \(P_{H_2 O} = P_{total} \) to almandine, sillimanite, quartz and vapor has a positive slope (dP/dT) apparently in contrast to the experimental negative slope. This may be explained by hydration kinetics, which could have allowed systematic breakdown of cordierites of metastable hydration states in the experiments. The bivariant Cd-Ga fields calibrated from the present model are, potentially, good petrogenetic indicators, as, given the iron-magnesium ratio of garnet and cordierite and the hydration number of cordierite, the temperature, pressure and water fugacity are uniquely determined. As this geothermobarometer is in part based on the water content of cordierite, it can be used only if there is some assurance that the actual hydration is inherited from high-grade metamorphic conditions. Such conditions could be realised if the slope of unloading-cooling retrograde metamorphism is more or less parallel to a cordierite isohydron.  相似文献   

Dynamical-statistical methods of meso-scale precipitation forecasting over mountainous terrain     

Walter Kuhn  Jean Quiby 《Pure and Applied Geophysics》1976,114(6):945-964

Summary Two diagnostic fine-mesh models for the determination of the vertical wind component over mountainous terrain have been developed. Both models rely on large-scale grid-point data. The first is based on the equivalent-barotropic scheme and uses 500 mbar heights as input data; the second model is built on the omega-equation and makes use of four input levels. Large-scale terms are interpolated from the large-scale grid to a fine-mesh grid with tenfold smaller mesh-width, while orographic terms are computed in the fine-mesh grid only. The slope of the model-topography and frictional effects are taken into consideration. Humidity and thermal convection are ignored. From computed vertical velocities and observed precipitations, an approximate prediction of precipitation is inferred by a regression technique. In the majority of cases, the baroclinic model gave slightly better results than the barotropic model.  相似文献   

New terrestrial heat flow measurements on the Nazca Plate     

Roger N. Anderson  Marcus G. Langseth  Victor Vacquier  Jean Francheteau 《Earth and Planetary Science Letters》1976,29(2):243-254

Sixty-seven new heat flow measurements on the Nazca Plate are reported, and the thermal regimes of three specific areas on the plate are examined. The Nazca Ridge is an aseismic ridge which may have been generated as an “island trail” from the Easter Island “hot spot” and/or may be a fossil transform fault. The Nazca Ridge has lower heat flow than the surrounding sea floor implying that the ridge might have low “effective” thermal conductivity causing heat to preferentially flow or refract to surrounding ocean crust which has higher conductivity, or, the low heat flow values may be caused by hydrothermal circulation on the ridge. The Carnegie Plateau is an elevated region south of the Carnegie Ridge on the northeastern Nazca Plate with high heat flow and shallow topography consistent with an age of less than 20 m.y. B.P. The central Nazca Plate is an area of highly variable heat flow which is possibly related to thin sediment and to rough regional topography.  相似文献   

Diffusion processes in resorbed garnets     

Pierre de Béthune  Dominique Laduron  Jacqueline Bocquet 《Contributions to Mineralogy and Petrology》1975,50(3):197-204

Mn- (and Ca-) enriched border fringes around resorbed garnets, and Mn-enriched zones along cracks in resorbed garnets and along intergranular boundaries in resorbed sievegarnets, indicate a limited diffusion of Mn (and some Ca) into the garnet structure.  相似文献   

Essai d'organisation paléogéographique et structurale du PaléozoÏque des Andes Méridionales     

Prof. Jean -Claude Vicente 《International Journal of Earth Sciences》1975,64(1):343-394

Hercynian absolute ages obtained from many plutonites and metamorphites of the Sierras Pampeanas compel to consider this polymetamorphic domain rather as an intermediate hinterland and axis of divergent symmetry between the two elementary geosyncline ranges (Cuyanides and Bolivianides) of the south america hercynian orogen. Attempt of Cuyanides paleogeographic organization indice to define during the geosyncline period (Cambrian to Devonian):

the Pampean zone which consist of:

1. an internal sub-zone (eastern) or pampean s. st. with hinterland significance
2. a more external sub-zone (western) or transpampean or Umango sub-zone with intermediate features between eugeanticlinal ridge and eugeosynclinal furrow;
3. the Calingasta zone as a typical eugeosynclinal furrow with pelagic-terrigenous ordovician sedimentation and ophiolitic magmatism followed by early silurian than devonian Flyschs;
4. the Zonda zone as an external ridge with neritic cambro-ordovician facies and devonian flyschs.

The unwonted position of Zonda no metamorphic Facies surrounded by Calingasta and Umango metamorphic Facies, suggest its window situation and wide allochthonous structures for the internal zones. An eastward origin of the nappes is discussed in relation with pampean syntectonic metamorphism and plutonism. Essentially, structures are referred to the Acadian phase (= bretonic) but early paleo-hercynian phases are also emphasized to explain Flyschs sequences and some pampean plutonic cycles. Tardi- and Post-hercynian organization is briefly sketched with related molasses, neomolasses and magmatism. The remarquable geosyncline pattern of the Cuyanides is emphasizes in all stages of its evolution and under aspects however tectonic, magmatic and metamorphic. Finally, the fundamentally western polarity of the Cuyanides is replaced into the most general framework of Gondwanides organization.  相似文献   

La mesure de l'anisotropie de susceptibilité magnétique dans les flyschs: Application à la recherche des directions des paléocourants     

Henri Argenton  Claude Bobier  Jean Polvêche 《Sedimentary Geology》1975,14(2):149-167

Studies made on the anisotropy of magnetic susceptibility of artificial sediments have shown that there are correlations between the orientation of anisotropy axes and of transport directions. Thus, the analysis of parameters of anisotropy of magnetic susceptibility can constitute a means to investigate transport directions in flysch. To test this method in a natural model, the authors have made some measurements on flysch beds belonging to the “grés d'Annot complex”. The sediments have been sampled in the Contes and Peira-Cava synclines where the directions of paleocurrents have been determinated by classical methods. Results obtained both in Contes and in Peira-Cava on fine-grained detrital beds show a good agreement between directions of paleo-transport deduced from orientation of anisotropy axes and those established by classical methods on the levels showing “sole-marks”. However, in some beds of the Peira-Cava syncline, which are characterized by coarser grain size and “sole-marks” of good quality, the scattering of the directions of the anisotropy axes is very great and in some cases the measurements are not reproducible in the same sample.It appears, therefore, that the measurement of the anisotropy of magnetic susceptibility can constitute a good approach to analysing emplacement modes of fine-grained flysch deposits in which the use of classical methods is often difficult. This method of paleocurrent analysis complements the other techniques used in this field of research.  相似文献   

Earth resources,time, and man — A geoscience perspective     

von Engelhardt  W.  Goguel  Jean  Hubbert  M. King  Prentice  J. E.  Price  R. A.  Trümpy  R. 《Environmental Geology》1976,1(4):193-206

The earth with all its inhabitants, including man, has had a long history as a slowly evolving complex system which normally exists in a state of stable dynamic equilibrium. Explosive growth in the human population, in the per capita use of nonrenewable resources, and in the degree of human disruption of established ecosystems — the hallmark of man's recent and rapid emergence as the dominant species on the face of the earth — represents a major departure from this state of equilibrium and an ecological crisis of global dimensions. This growth, and the rapid changes that arise from it, have had such a pervasive influence on the collective experience of man that they have come to be regarded as the normal course of events on a stable earth. This has fostered the notion that growth will always be essential for further improvements in the quality of human life. The emergence of a global technological civilization results from man's ingenuity in devising ways of using an ever increasing proportion of energy available at the earth's surface. Rapid growth began only two hundred years ago when the developing technology of the industrial revolution made possible the large-scale exploitation of the earth's fossil-fuel resources and the creation of positive feedback between growth in technology and growth in fossil-fuel production. Annual growth rates in world production of fossil fuels and ores of representative industrial metals, when compared with the nature and finite magnitude of the earth's resources, lead to the inescapable conclusion that the present episode of exponential growth can only be a transitory epoch of a few centuries duration within the totality of human history. Solar radiation offers the prospect of large supplies of energy with minimal environmental impact. However, constraints on growth due to the finite nature of food and mineral resources and the effects of environmental degradation can only be loosened in this way, not removed. Mankind faces an inevitable transition from a brief interlude of exponential growth to a stable condition characterized by rates of growth so slow as to be regarded essentially as a state of no growth. Failure to respond rationally and promptly to this situation could be disastrous.  相似文献   

Late Quaternary vegetational changes on the east side of Yellowstone park,Wyoming     

Jean C.B. Waddington  H.E. Wright 《Quaternary Research》1974,4(2):175-184

A bog pond 4 km east of Yellowstone Lake has a pollen record starting with an Artemisia spruce assemblage, implying alpine vegetation. A layer of volcanic ash, dated as 14,360 ± 400 BP (probably Glacier Peak or Mt. St. Helens J), occurs within the zone, which terminates at 11,630 ± 180 BP. The rest of the pollen sequence is dominated by lodgepole pine, with reappearance of spruce pollen in modest quantities about 4500 BP, according to dating provided by a layer of Mt. Mazama ash (6600 BP). The present vegetation of the area is marked by forests of lodgepole pine with some stands of spruce and fir. The pollen sequence suggests that the upper treeline before 11,600 y. a. was perhaps 500 m lower than today. The climate then became warmer and/or drier than today (Altithermal interval). About 4500 y. a., a slight climatic reversal took place, roughly contemporaneous with the regrowth of glaciers in the western mountains (neoglaciation).  相似文献   

Preliminary petrographic description and geologic implications of the Apollo 17 Station 7 boulder consortium samples     

E.C.T. Chao  Jean A. Minkin  Carolyn L. Thompson 《Earth and Planetary Science Letters》1974,23(3):413-428

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Vesicles,water, and sulfur in Reykjanes Ridge basalts   总被引：1，自引：0，他引：1  

James G. Moore  Jean -Guy Schilling 《Contributions to Mineralogy and Petrology》1973,41(2):105-118

Dredge hauls of fresh submarine basalt collected from the axis of the Reykjanes Ridge (Mid-Atlantic Ridge) south of Iceland were taken aboard R/ V TRIDENT in 1967 and 1971. The samples show systematic changes as the water depth of collection (and eruption) decreases: radially elongate vesicles and concentric zones of vesicles appear at about 700 m depth and are conspicuous to shallow water; the smoothed volume percent of vesicles increases from 5% at 1000 m, 10% at 700 m, to 16% at 500 m, and the scatter in degree of vesicularity increases in shallower water; specific gravity decreases from 2.7±0.1 at 1000 m to 2.3±0.3 at 100 m. Bulk sulfur content for the outer 2 cm averages 843 ppm up to a depth of 200 m, then drops off rapidly in shallower water owing to degassing. Sulfur content below 200 m is independent of depth (or geographic position), and the melt is apparently saturated with sulfur, but the excess cannot escape the lava unless another vehicle carries it out. Only shallower than 200 m, where intense vesiculation of other gases occurs can excess sulfur be lost from the lava erupting on the sea floor. H₂O^+110° averages about 0.35 percent and H₂O^+150° about 0.25 percent, and both apparently decrease in water shallower than 200 m as a result of degassing. H₂O⁺ (below 200 m) decreases with distance from Iceland or increasing depth, presumably as a result of either adsorption of water on the surface of shallower, more vesicular rocks; or more likely due to the presence of the Iceland hot mantle plume supplying undifferentiated primordial material, relative to lavas of the Reykjanes Ridge supplied from the low velocity layer already depleted in volatiles and large lithophile elements. The H₂O^+110°/S ratio of lava erupting below 200 m water depth ranges from 3 to 5 which is comparable to reliable gas analyses from oceanic basaltic volcanoes. Publication authorized by the Director, U.S. Geological Survey.  相似文献