Calculations of activity-composition relations in multi-site solid solutions: the example of AB2O4 spinels     

Jean Lehmann  Jacques Roux 《Contributions to Mineralogy and Petrology》1984,87(4):328-336

A model to calculate activities in multisite solutions like spinels, from a general expression of the Gibbs free energy is developped. The free energy is written as that of a solution with ideal mixing of cations on each sublattice corrected by any suitable higher order terms. It is shown that activities of i^th end-member can be simply written: $${\text{act (}}i{\text{) = (}}\gamma _i {\text{/}}\gamma _i^{\text{0}} {\text{)}}\mathop \prod \limits_j (N_j /N_j^0 )^{P(j,{\text{ }}i)} .$$ N _j are site occupancy fractions; the γ _i are equal to one for the ideal multisite model and depend only on the higher order corrections to this model; ⁰ indicate values for the i ^th end member. The exponents in the matrix P are integers and constants. The activities cannot be expressed explicitly as function of the macroscopic composition. The site occupancy fractions which minimize the Gibbs free energy must be calculated first solving a set of non linear equations which define the internal equilibrium conditions. The (Fe²⁺, Mg) (Al, Cr, Fe³⁺) spinel are used to illustrate these calculations. For multicomponent AB₂O₄ spinels activity expressions derived for the reference ideal multisite mixing model are: $${\text{act (AB}}_{\text{2}} {\text{O}}_{\text{4}} {\text{) = }}\frac{{({\text{A}})[{\text{B}}]^2 }}{{({\text{A}})_0 [{\text{B}}]_0^2 }}$$ (A): fraction of tetrahedral sites occupied by A²⁺; [B]: fraction of octahedral sites occupied by B³⁺. Because the site occupancy fractions at equilibrium are not independent (but related by the internal equilibrium relations) many equivalent expressions of the activities can be obtained. Finally approximations proposed in the literature to obtain simple explicit activity-concentration relationships are discussed.  相似文献   

Surface sealing as influenced by slope angle and position of simulated stones in the top layer of loose sediments   总被引：1，自引：0，他引：1  

Jean Poesen 《地球表面变化过程与地形》1986,11(1):1-10

The influence of five different slope angles and two different positions of simulated stones in the top layer of a sandy and a silty sediment on surface sealing intensity is examined in the laboratory. Sealing intensity is assessed by studying changes of percolation rate through a sediment layer with simulated rainfall duration and by measuring cohesion of the 5 mm thick upper sediment layer, a measure of seal strength, by means of a torvane. Slope has a negative influence on sealing intensity. For a constant per cent of simulated stone cover, sealing intensity is lowest in the case of stones placed on the sediment surface compared to the case of stones pushed into the surface layer. Explanations for these findings are given and some implications are further discussed.  相似文献   

Middle miocene deduction and late miocene beginning of collision registered in the hengchun peninsula: Geodynamic implications for the evolution of Taiwan     

Bernard Pelletier  Jean Franois Stephan 《Tectonophysics》1986,125(1-3)

Taiwan is located in the axis of the Manila Trench. It results from an oblique collision between the northernmost part of the Luzon arc and the Chinese passive margin. This active collision follows the subduction of the Oligocene-Miocene oceanic crust of the South China Sea along the Manila Trench. The tectonized Chinese margin emerged in the Hengchun peninsula (South Taiwan). Gentle folds which are delineated by the Quaternary reefal limestones demonstrate Recent deformations. These folds deformed a thick detrital sequence of Miocene age (Ssuchung Chi series) which was previously strongly folded and thrust westward (axis NS-N20) upon the Renting mélange of Latest Miocene age. These main deformations, sealed by the Middle Pliocene, are the evidence for the onset of collision in this part of Taiwan at the end of the Miocene. Because of its obliquity, the collision started already in the northern part of Taiwan during the Late Miocene (6-7-8 Ma ?).The Ssuchung Chi series, a sequence of proximal turbidites, has contained, since the Middle Miocene (NN 6~13 Ma), fragments of an Oligocene to Lower Miocene oceanic crust. This ophiolitic material is very similar to the East Taiwan Ophiolite of the Coastal Range. It originated most probably from a slice of South China Sea crust obducted in Middle Miocene times (13–14 Ma) upon the Chinese margin (North of the Hengchun peninsula). This obduction occurred 7 to 8 Ma before the beginning of collision. These results make it possible to propose an evolutionary model for Taiwan from the Oligocene to the Recent, with the different phases of a collision between a volcanic arc and a passive margin.  相似文献   

The study of molybdenites through the¹⁸⁷Re-¹⁸⁷Os chronometer     

Jean Marc Luck  Claude J. Allègre 《Earth and Planetary Science Letters》1982,61(2):291-296

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Prediction of extractable metals in retention pond sediments at surface coal mines     

Jean E. Bogner 《Environmental Geology》1982,4(3-4):223-238

Fifty-two grab samples of bottom sediment in settling ponds were obtained at 17 surface coal mines in the eastern and midwestern U.S. A series of laboratory extraction procedures were designed to simulate a wide range of possible natural conditions. The three types of laboratory extraction procedures were (1) a low-pH buffered extract; (2) a series of low-pH, near-neutral-pH, and high-pH nonbuffered extracts; and (3) a DTPA extract. For the transition metals examined (Fe, Mn, Ni, Zn, Co, Cu, Cr, Fe, Al), higher percentages were extracted by the low-pH buffered extract than by the low-pH nonbuffered extract and the DTPA extract. Within the nonbuffered series, higher percentages of individual metals were extracted at lower pH levels. There was generally a consistent order of “extractability” for all the extracts performed. At the mines using a chemical treatment to neutralize acid mine drainage, Mn was the most mobile and Fe and Al the least mobile of the metals considered; at the mines not using a chemical treatment, Ni, Zn, and Co were among the most mobile and Fe, Al, and Cr the least mobile of the metals studied. Two stepwise regression procedures (maximum R² improvement and backward elimination) were used to suggest a ranking of independent variables that influence extractable metals. Statistically significant independent variables differed for the various metals. In general, the total amount of metal present was most important in determining metal extractability in the buffered extract at the mines using chemical treatment, and variables related to the natural acidity or alkalinity of the sediment and element interrelationships were important in the other extracts. A detailed examination of regression equations for the buffered extract suggests that it is possible to predict extractable metals using simple regression models based on the total amount of metals present, metals interrelationships, and sediment acidity or alkalinity.  相似文献   

Dust,clouds, rain types,and climatic variations in tropical north Africa   总被引：2，自引：0，他引：2  

Jean Maley 《Quaternary Research》1982,18(1):1-16

Dust and processes of raindrop formation in the clouds play a very important role in the climatic evolution of tropical north Africa. Sedimentologic, stratigraphic, pedologic, geomorphologic, and palynologic data converge to show that a major environmental change occurred in tropical Africa about 7000 yr B.P. In the Sudanian and Sudano-Guinean zones (wet tropical zone), from 15,000 to 7000 yr B.P., rivers deposited mostly clay, while from 7000 to 4000 yr B.P. they deposited mostly sand. During the first period, pedogenesis was vertisolic (montmorillonite dominant), associated with pollen belonging mostly to vegetation typical of hydromorphic soils, while during the second period pedogenesis was of ferruginous type (kaolinite dominant) with pollen belonging mostly to vegetation typical of well-drained soils. The great change near 7000 yr B.P. is linked chiefly to a major hydrological change that appears related to a change in the size of raindrops: from fine rains associated with considerable atmospheric dust (raindrop diameter essentially less than 2 mm) to the second period associated with thunderstorm rains (raindrop diameter mostly greater than 2 mm). The size of raindrops is related particularly to cloud thickness and dust concentration in the troposphere. Thunderstorm activity is influenced also by fluctuations of the atmospheric electricity, modulated by the sun.  相似文献   

Late Pleistocene paleo-oceanography of the Norwegian-Greenland Sea: Benthic foraminiferal evidence     

S.Stephen Streeter  Paul E. Belanger  Thomas B. Kellogg  Jean Claude Duplessy 《Quaternary Research》1982,18(1):72-90

Fluctuations in benthic foraminiferal faunas over the last 130,000 yr in four piston cores from the Norwegian Sea are correlated with the standard worldwide oxygen-isotope stratigraphy. One species, Cibicides wuellerstorfi, dominates in the Holocene section of each core, but alternates downcore with Oridorsalis tener, a species dominant today only in the deepest part of the basin. O. tener is the most abundant species throughout the entire basin during periods of particularly cold climate when the Norwegian Sea presumably was ice covered year round and surface productivity lowered. Portions of isotope Stages 6, 3, and 2 are barren of benthic foraminifera; this is probably due to lowered benthic productivity, perhaps combined with dilution by ice-rafted sediment; there is no evidence that the Norwegian Sea became azoic. The Holocene and Substage 5e (the last interglacial) are similar faunally. This similarity, combined with other evidence, supports the presumption that the Norwegian Sea was a source of dense overflows into the North Atlantic during Substage 5e as it is today. Oxygen-isotope analyses of benthic foraminifera indicate that Norwegian Sea bottom waters warmer than they are today from Substage 5d to Stage 2, with the possible exception of Substage 5a. These data show that the glacial Norwegian Sea was not a sink for dense surface water, as it is now, and thus it was not a source of deep-water overflows. The benthic foraminiferal populations of the deep Norwegian Sea seem at least as responsive to near-surface conditions, such as sea-ice cover, as they are to fluctuations in the hydrography of the deep water. Benthic foraminiferal evidence from the Norwegian Sea is insufficient in itself to establish whether or not the basin was a source of overflows into the North Atlantic at any time between the Substage 5e/5d boundary at 115,000 yr B.P. and the Holocene.  相似文献   

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France     

Philippe Lesage  Pierre Antoine Blum  Marcel Vadell  Jean Francois Fels 《Pure and Applied Geophysics》1983,121(5-6):889-902

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.  相似文献   

Reconstructions of spring/summer precipitation for the Eastern Mediterranean from tree-ring widths and its connection to large-scale atmospheric circulation     

Ramzi Touchan  Elena Xoplaki  Gary Funkhouser  Jürg Luterbacher  Malcolm K. Hughes  Nesat Erkan  Ünal Akkemik  Jean Stephan 《Climate Dynamics》2005,25(1):75-98

This study represents the first large-scale systematic dendroclimatic sampling focused on developing chronologies from different species in the eastern Mediterranean region. Six reconstructions were developed from chronologies ranging in length from 115 years to 600 years. The first reconstruction (1885–2000) was derived from principal components (PCs) of 36 combined chronologies. The remaining five, 1800–2000, 1700–2000, 1600–2000, 1500–2000 and 1400–2000 were developed from PCs of 32, 18, 14, 9, and 7 chronologies, respectively. Calibration and verification statistics for the period 1931–2000 show good levels of skill for all reconstructions. The longest period of consecutive dry years, defined as those with less than 90% of the mean of the observed May–August precipitation, was 5 years (1591–1595) and occurred only once during the last 600 years. The longest reconstructed wet period was 5 years (1601–1605 and 1751–1755). No long term trends were found in May–August precipitation during the last few centuries. Regression maps are used to identify the influence of large-scale atmospheric circulation on regional precipitation. In general, tree-ring indices are influenced by May–August precipitation, which is driven by anomalous below (above) normal pressure at all atmospheric levels and by convection (subsidence) and small pressure gradients at sea level. These atmospheric conditions also control the anomaly surface air temperature distribution which indicates below (above) normal values in the southern regions and warmer (cooler) conditions north of around 40°N. A compositing technique is used to extract information on large-scale climate signals from extreme wet and dry summers for the second half of the twentieth century and an independent reconstruction over the last 237 years. Similar main modes of atmospheric patterns and surface air temperature distribution related to extreme dry and wet summers were identified both for the most recent 50 years and the last 237 years. Except for the last few decades, running correlation analyses between the major European-scale circulation patterns and eastern Mediteranean spring/summer precipitation over the last 237 years are non-stationary and insignificant, suggesting that local and/or sub-regional geographic factors and processes are important influences on tree-ring variability over the last few centuries.  相似文献   

Ice core evidence for secular variability and 200-year dipolar oscillations in atmospheric circulation over East Antarctica during the Holocene   总被引：3，自引：0，他引：3  

Barbara Delmonte  Jean Robert Petit  Gerhard Krinner  Valter Maggi  Jean Jouzel  Roberto Udisti 《Climate Dynamics》2005,24(6):641-654

Two Holocene ice core records from East Antarctica (Vostok and EPICA-Dome C) were analysed for dust concentration and size distribution at a temporal resolution of 1 sample per ~50 years. A series of volcanic markers randomly distributed over the common part of the ice cores (from 9.8 to 3.5 kyear BP) ensures accurate relative dating (±33 years). Dust-size records from the two sites display oscillations structured in cycles with sub-millennial and secular scale frequencies that are apparently asynchronous. The power spectra of the composite sum (Σ) of the two dust-size records display spectral energy mostly for 150- to 500-year periodicities. On the other hand, the 200-year band is common to both records and the 200 year components of the two sites are out-of-phase (100-year lead or lag) over ~5.5 kyear, a phenomenon also reflected by a significant (>99% conf. lev.) band in the power spectra of the composite difference (Δ) of the two size records. During long-range transport, mineral dust originating from the Southern Hemisphere continents is graded to a variable extent depending on the altitude and duration of atmospheric transport. Relatively coarse dust is associated with air mass penetration from the middle–lower troposphere and conversely relatively fine dust with upper troposphere air masses or the influence of subsidence over the Antarctic plateau, a hypothesis already proposed for the changes that occurred during the Last Glacial Maximum to Holocene transition (Delmonte et al. 2004b). Moreover, we assume that the overall fluctuation of air mass advection over Antarctica depends on the meridional pressure gradient with respect to low latitudes, i.e. the Antarctic Oscillation (AAO). We therefore suggest a regional variability in atmospheric circulation over East Antarctica. The 150–500 year power spectrum of the composite (Σ) parameter represents the long term variability of the AAO, imprinted by secular internal oscillations probably related to the southern ocean-climatic system. On the other hand, the Δ dust composite parameter suggests a persistent atmospheric dipole over East Antarctica delivering coarser (finer) dust particles alternatively to Vostok and Dome C regions with a bi-centennial periodicity. Indeed, a seesaw phenomenon in dust size distribution was already observed at three East Antarctic sites during the last deglaciation (Delmonte et al. 2004b) and was interpreted as a progressive reduction of the eccentricity of the polar vortex with respect to the geographic south pole. Interestingly, the Δ parameter shows a pronounced 200-year oscillation mode, throwing new light on the unresolved question of a possible relationship between climate and solar activity.  相似文献