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31.
The COUPLEX1 Test case (Bourgeat et al., 2003) is devoted to the comparison of numerical schemes on a convection–diffusion–reaction problem. We first show that the results of the simulation can be mainly predicted by a simple analysis of the data. A finite volume scheme, with three different treatments of the convective term, is then shown to deliver accurate and stable results under a low computational cost.  相似文献   
32.
The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).  相似文献   
33.
Nickel speciation in a nickel hyperaccumulating plant (Sebertia acuminata) and its associated soil of southern New Caledonia was studied using various analytical methods. The soil is formed of iron oxides (goethite, hematite), which contain almost all the nickel. The available nickel is probably linked to the organic matter in the litter. Sebertia acuminata, acts as a nickel pump, and concentrates the metal in its leaves. It partitions nickel and silica; nickel is concentrated in the cells (probably in the vacuoles) as organometallic complexes, whereas silica forms the framework of the cells, and the phytolithes. A thorough study of these plants seems essential in order to define the soil–plant relations, and to propose appropriate ways for ecological restoration. To cite this article: N. Perrier et al., C. R. Geoscience 336 (2004).  相似文献   
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The unexplored area of Azarhare in central Morocco is studied thanks to three sections composed of five lithological facies Main biostratigraphical and sedimentological results concern (1) the identification of Late Visean biozones, with important presence of problematic algae Ungdarella, (2) the regional extension of deposit sequences SD5, SD6 and SD7 previously defined, (3) and an analysis of the diagenetic kaolinite. To cite this article: A. Karim et al., C. R. Geoscience 337 (2005).  相似文献   
37.
The potential of radar imagery in geological exploration was investigated at a study site in Mauritania (Akjoujt region). Compared with optical images, the results obtained show how radar imagery can help not only in detecting surface geological structures such as dykes and veins, but also mapping subsurface structures beneath a shallow layer of sand (palaeochannels). The mapping potential was found to be much better at long wavelengths than at short ones (L-band, compared with C- and X-band). As for optical images, their contribution is much more limited in the mapping of surface geological structures, and inappropriate for detecting subsurface structures. We conclude that spatial remote sensing enables the improvement of existing geological maps and the optimization of cartographic surveying. To cite this article: N. Baghdadi et al., C. R. Geoscience 337 (2005).  相似文献   
38.
The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).  相似文献   
39.
Correlations presented by Spycher et al. (2003) to compute the mutual solubilities of CO2 and H2O are extended to include the effect of chloride salts in the aqueous phase. This is accomplished by including, in the original formulation, activity coefficients for aqueous CO2 derived from several literature sources, primarily for NaCl solutions. Best results are obtained when combining the solubility correlations of Spycher et al. (2003) with the activity coefficient formulation of Rumpf et al. (1994) and Duan and Sun (2003), which can be extended to chloride solutions other than NaCl. This approach allows computing mutual solubilities in a noniterative manner with an accuracy typically within experimental uncertainty for solutions up to 6 molal NaCl and 4 molal CaCl2.  相似文献   
40.
This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.  相似文献   
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