Sources of Cd, Cu, Ni and Zn in Portuguese coastal waters     

Marie-Hlne Cott-Krief  Ccile Guieu  Alain J. Thomas  Jean-Marie Martin 《Marine Chemistry》2000,71(3-4)

In order to identify the major sources of trace metals (TM) in the Portuguese coastal waters, 58 surface water samples were collected during September 1988. The area sampled extended from the Tagus Estuary (down to a salinity of 25) to cape Ste Marie on the southern coast of Portugal. Dissolved metal concentrations in the fully marine waters ranged from 30 to 250 pM for Cd, 0.7–15 nM for Cu, 0.9–20 nM for Zn and 1.8–4.5 nM for Ni. Within the Tagus Estuary (salinity 25), concentrations increased to 3400 pM for Cd, 26 nM for Cu, 14 nM for Ni and 230 nM for Zn.The large-scale distribution of these metals is dominated by two strong continental sources, both probably linked to the exploitation of pyrite ores. In the Tagus Estuary, TM enrichments can be mostly attributed to a pyrite roasting plant located on the shore in front of Lisbon. Concerning the south Portuguese shelf waters, several hypotheses are proposed to explain their elevated metal concentrations. We particularly discussed the likely influence of the Tinto/Odiel rivers located 100 km eastward, an influence well known in the shelf waters of the Gulf of Cadiz. These rivers are extremely metal-rich because of acid mine tailings originating from their catchment. Between these two regions, upwelling of relatively metal-poor water largely contributes to the dilution of the continental inputs. Indeed, water exchanges on the shelf linked to the upwelling involve water fluxes 500 times higher than the Tagus River flow, and renew the coastal waters that are thus cleaned from terrestrial contamination. Contrary to many other upwelling systems in non-contaminated areas, the Portuguese upwelling does not act as a source of trace-metal enrichment of the continental margin waters.  相似文献   

Coordinated monitoring of the eccentric O-star binary Iota Orionis: optical spectroscopy and photometry     

Sergey V. Marchenko  Gregor Rauw  Eleonora A. Antokhina  Igor I. Antokhin  Dominique Ballereau  Jacques Chauville  Michael F. Corcoran  Rafael Costero  Juan Echevarria  Thomas Eversberg  Ken G. Gayley  Gloria Koenigsberger  Anatoly S. Miroshnichenko  Anthony F. J. Moffat  Nidia I. Morrell  Nancy D. Morrison  Christopher L. Mulliss  Julian M. Pittard  Ian R. Stevens  Jean-Marie Vreux  Jean Zorec 《Monthly notices of the Royal Astronomical Society》2000,317(2):333-342

With the objective of investigating the windwind collision phenomenon and supporting contemporaneous X-ray observations, we have organized a large-scale, coordinated optical monitoring campaign of the massive, highly eccentric O9 III+B1 III binary Iota Orionis. Successfully separating the spectra of the components, we refine the orbital elements and confirm the rapid apsidal motion in the system. We also see strong interaction between the components during periastron passage and detect phase-locked variability in the spectrum of the secondary star. However, we find no unambiguous signs of the bow shock crashing on the surface of the secondary, despite the predictions of hydrodynamic simulations. Combining all available photometric data, we find rapid, phase-locked variations and model them numerically, thus restricting the orbital inclination to 50° i 70°.  相似文献   

On the detectability of H₂S in Jupiter     

Bruno Bézard  André Marten  Jean Paul Baluteau  Daniel Gautier  Jean-Marie Flaud  Claude Camy-Peyret 《Icarus》1983,55(2):259-271

The influence of hydrogen sulfide, a still-undetected key molecule for the Jovian atmospheric chemistry in the infrared spectrum, was investigated. Synthetic spectra including various vertical distribution profiles of H₂S have been computed and compared with observational data for Jupiter in the 2- to 15-cm^?1 and 1160- to 1200-cm^?1 spectral ranges. No firm conclusion about the presence of H₂S can be drawn from the latter spectral region because of large uncertainties in gaseous opacities. In the microwave range, H₂S is found to be a possible candidate to explain the measurements. Constraints to its vertical distribution which would imply a significant supersaturation in the troposphere are derived. Physical and chemical processes involving H₂S in the atmosphere are discussed in the light of this hypothesis.  相似文献   

Global representation of the drying–wetting curves of four engineering soils: experiments and correlations     

Zhong-Sen Li  Assia Benchouk  Feth-Ellah Mounir Derfouf  Nabil Abou-Bekr  Said Taibi  Hanène Souli  Jean-Marie Fleureau 《Acta Geotechnica》2018,13(1):51-71

The main objective of this paper is to examine how different engineering soils react to environmental variations and to provide correlations to characterize their behaviour under null external mechanical stress. Two French and two Algerian soils with liquid limits ranging from 36 to 112 were prepared under both slurry and Proctor compaction conditions, and then subjected to drying–wetting paths with suction controlled from several kPa to several hundreds of MPa. Experimental results are presented in five diagrams to show globally and simultaneously the shrinkage–swelling, saturation–desaturation and water retention characteristics. A reasonable consistency was observed between the oedometric and drying curves of slurry, confirming the equivalence between hydraulic loading (suction) and mechanical loading (consolidation stress) on the volume change behaviour of different soils. As an intrinsic parameter of soil nature, liquid limit was found to have a significant influence on the shrinkage limit, air-entry suction and compressibility of both slurry and compacted samples. For that reason, correlations between these characteristics and liquid limit were set up, providing a good basis for a first estimation of the drying–wetting curves. At the micro-scale, new experimental results were obtained: either on drying or wetting path, the micro-pores were almost unaffected, whereas, when matrix suction increased from 0.1 to 8 MPa, the volume of macro-pores decreased to quasi-closure. At last, the analogy between the compaction and drying–wetting curves, and the comparison of different methods to determine the water retention curve were addressed. Such analogies and comparisons contribute to a better understanding of the mechanisms of mechanical stress and suction.  相似文献   

Correcting surface winds by assimilating high-frequency radar surface currents in the German Bight     

Alexander Barth  Aida Alvera-Azcárate  Jean-Marie Beckers  Joanna Staneva  Emil V. Stanev  Johannes Schulz-Stellenfleth 《Ocean Dynamics》2011,61(5):599-610

Surface winds are crucial for accurately modeling the surface circulation in the coastal ocean. In the present work, high-frequency radar surface currents are assimilated using an ensemble scheme which aims to obtain improved surface winds taking into account European Centre for Medium-Range Weather Forecasts winds as a first guess and surface current measurements. The objective of this study is to show that wind forcing can be improved using an approach similar to parameter estimation in ensemble data assimilation. Like variational assimilation schemes, the method provides an improved wind field based on surface current measurements. However, the technique does not require an adjoint, and it is thus easier to implement. In addition, it does not rely on a linearization of the model dynamics. The method is validated directly by comparing the analyzed wind speed to independent in situ measurements and indirectly by assessing the impact of the corrected winds on model sea surface temperature (SST) relative to satellite SST.  相似文献   

The tectono-sedimentary evolution of a hyper-extended rift basin: the example of the Arzacq–Mauléon rift system (Western Pyrenees,SW France)     

Emmanuel Masini  Gianreto Manatschal  Julie Tugend  Geoffroy Mohn  Jean-Marie Flament 《International Journal of Earth Sciences》2014,103(6):1569-1596

In this paper, we present a sedimentary and structural analysis that together with maps, sections and new Ar/Ar data enable to describe the tectono-sedimentary evolution of the Mauléon hyper-extended rift basin exposed in the W-Pyrenees. Hyper-extension processes that ultimately resulted in exhuming mantle rocks are the result of the subsequent development of two diachronous detachment systems related to two evolutional stages of rifting. An initial Late Aptian Early Albian crustal thinning phase is first recorded by the development of a crustal necking zone controlled by the north-vergent Southern Mauléon Detachment system. During a subsequent exhumation phase, active faulting migrates to the north with the emplacement of the Northern Mauléon detachment system that exhumed north section thinned continental crust and mantle rocks. This diachronous crustal thinning and exhumation processes are also recorded by the diachronous deposition of syn-tectonic sedimentary tracts above the two supra-detachment sub-basins. Syn-tectonic sedimentary tracts record the progressive exhumation of footwall rocks along detachment systems. Tectonic migration from the southern to the northern Mauléon Detachment system is recorded by the coeval deposition of “sag” deposits above the necking zone basin and of syn-tectonic tracts above exhumed rocks north section. Located on a hanging-wall situation related to the Mauléon hyper-extension structures, the Arzacq Basin also records a major crustal thinning phase as shown by its subsidence evolution so as by deep seismic images. The absence of major top-basement structures and its overall sag morphology suggest that crustal thinning processes occurred by decoupled extension of lower crustal levels contrasting with the Southern Mauléon Detachment system. Reconciling observations from the Mauléon and Arzacq Basins, we finally propose in this paper that they were the result of one and the same asymmetric crustal thinning and exhumation processes, where extension is accommodated into the upper crust in the Mauléon Basin (lower plate basin) and relayed in ductile lower crust below the Arzacq Basin (upper plate basin).  相似文献   

Metal fluxes through the Strait of Gibraltar: the influence of the Tinto and Odiel rivers (SW Spain)     

Franoise Elbaz-Poulichet  Nicholas H. Morley  Jean-Marie Beckers  Philippe Nomerange 《Marine Chemistry》2001,73(3-4)

A large set of new data concerning dissolved metal concentrations has been acquired in the Gulf of Cadiz and in the Strait of Gibraltar from 1996 to 1999. These data, associated with models (hydrodynamic, tracer advection–dispersion and mixing), have been used to assess the influence of rivers draining the South Iberian Pyrite Belt on the Gulf of Cadiz and on the Atlantic inflow in the Strait of Gibraltar.Metal concentrations in surface waters from the Gulf of Cadiz are maximal near the mouth of the Tinto/Odiel rivers with values exceeding 50 nmol/kg (Mn), 5 nmol/kg (Ni), 30 nmol/kg (Cu), 100 nmol/kg (Zn), 0.9 nmol/kg (Cd) and 45 nmol/kg (As). From the Tinto/Odiel river, a plume of contamination follows the coast in the direction of the Strait of Gibraltar. The computation of a tracer advection–dispersion model confirms that the coastal currents carry the metals discharged from the Tinto and Odiel to the Strait of Gibraltar.From temperature–salinity and metal–salinity plots, four water masses can be recognised in the Gulf of Cadiz and in the Strait of Gibraltar: North Atlantic Surface Water (NASW), North Atlantic Central Water (NACW) and metal-enriched Spanish Shelf Waters from the Gulf of Cadiz (SSW). The Mediterranean Outflow Water (MOW) is also clearly seen at depths greater than 300 m.The chemical characteristics of these various water masses have been used in a mixing model to evaluate their relative contribution to the Atlantic inflow through the Strait of Gibraltar. These contributions are seasonally variable. In June 1997, the contribution was: 80±20%, 5±5% and 15±10% for NASW, NACW and SSW, respectively. In September, the SSW contribution was apparently negligible.Finally, these relative contributions allow the evaluation of the metal fluxes in the Strait of Gibraltar. The presence of SSW in the Strait increases the metal flux to the Mediterranean Sea by a factor of 2.3 (Cu), 2.4 (Cd), 3 (Zn) and 7 (Mn). It does not modify significantly As and Ni fluxes.  相似文献   

Local ensemble assimilation scheme with global constraints and conservation   总被引：1，自引：1，他引：0  

Alexander Barth  Yajing Yan  Aida Alvera-Azcárate  Jean-Marie Beckers 《Ocean Dynamics》2016,66(12):1651-1664

Ensemble assimilation schemes applied in their original, global formulation respect linear conservation properties if the ensemble perturbations are set up accordingly. For realistic ocean systems, only a relatively small number of ensemble members can be calculated. A localization of the ensemble increment is therefore necessary to filter out spurious long-range correlations. The conservation of the global properties will be lost if the assimilation is performed locally, since the conservation requires a coupling between all model grid points which is removed by the localization. The distribution of ocean observations is often highly inhomogeneous. Systematic errors of the observed parts of the ocean state can lead to spurious adjustment of the non-observed parts via data assimilation and thus to a spurious increase or decrease in long-term simulations of global properties which should be conserved. In this paper, we propose a local assimilation scheme (with different variants and assumptions) which can satisfy global conservation properties. The proposed scheme can also be used for non-local observation operators. Different variants of the proposed scheme are tested in an idealized model and compared to the traditional covariance localization with an ad-hoc step enforcing conservation. It is shown that the inclusion of the conservation property reduces the total RMS error and that the presented stochastic and deterministic schemes avoiding error space rotation provide better results than the traditional covariance localization.  相似文献   

Natural convection of compressible and incompressible gases in undeformable porous media under cold climate conditions     

Marc Lebeau  Jean-Marie Konrad 《Computers and Geotechnics》2009

A numerical model for convective heat and mass transport of compressible or incompressible gas flows with soil-water phase change is presented. In general, the gaseous phase is considered as compressible and the model accounts for adiabatic processes of compression heating and expansion cooling. The inherently compressible gaseous phase may nevertheless be considered as incompressible by adopting the Oberbeck–Boussinesq approximations. The numerical method used to solve the equations that describe natural convection is based on a Galerkin finite element formulation with adaptive mesh refinement and dynamic time step control. As most existing numerical studies have focused on the behavior of incompressible fluids, model substantiation examines the influence of fluid compressibility on two-widely used benchmarks of steady-state convective heat and mass transport. The relative importance of the effect of pressure-compressibility cooling is shown to increase as the thermal gradient approaches the magnitude of the adiabatic gradient. From these results, it may be concluded that pore-air compressibility cannot be neglected in medium to large-sized enclosures at small temperature differentials. After demonstrating its ability to solve fairly complex transient problems, the model is used to further our understanding of the thermal behavior of the toe drain at the LA2-BSU dam in the province of Quebec, Canada.  相似文献   

Is the world's economic centre of gravity already in Asia?   总被引：1，自引：0，他引：1  

Jean-Marie Grether  Nicole A Mathys 《Area》2010,42(1):47-50

This paper proposes a novel and simple measure of the world's economic centre of gravity. Over the recent decades, this centre has shifted towards Asia, but is still located in Europe.  相似文献