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21.
One of the two objectives of the Vemanaute cruise of the French deep submersible Nautile, was the geological study of the eastern intersection area between the Mid-Atlantic Ridge (MAR) and the Vema Fracture Zone in the equatorial Atlantic. Fourteen dives were conducted that allowed detailed geological survey and sampling of the main morphostructural units of this area: the northern and southern walls of the fracture zone, the median ridge, the northern and southern troughs and the nodal basin. In situ observations of recent tectonic features such as furrows, ridges and circular depressions, concentrated within the southern trough, allowed us to establish the location and the size of the present-day displacement zone. Geological investigations have shown that the nodal basin is entirely floored by basalts thus contrasting with other equivalent areas such as the Kane and Oceanographer fracture zone-MAR eastern intersections. Finally, this study stresses the great opposition between the relatively old and tectonically inactive northern part of the fracture, and the southern part which shows active tectonics and recent volcanic activity.  相似文献   
22.
The activity of the Damavand volcano (Central Alborz, northern Iran) began 1.8 Ma ago and continued up to 7 ka BP. Although the volcanic suite is clearly of shoshonitic affinity, only two petrographic types can be distinguished in the studied lavas: (1) weakly differentiated absarokites (49 < %SiO2 < 51), scattered around the volcano but with a regional extension, (2) highly differentiated banakites (59 < %SiO2 < 63), which form the bulk of the 4,000 m thick volcanic pile. All lavas are alkalic (3.7 < %K2O < 5), REE and LILE-rich (e.g., 85 < La < 148 ppm; 9 < Th < 32 ppm) and show highly fractionated REE patterns (69 < La/Yb < 115) and pronounced Nb–Ta negative anomalies. The absarokites are characterised by Sr (0.7045–0.7046) and Nd (0.51266–0.51269) isotope compositions close to the Bulk Earth values, and distinct from those of the banakites (0.7047 < 87Sr/86Sr < 0.7049, 0.51258 < 143Nd/144Nd < 0.51262). The Pb isotope ratios are also slightly lower in the absarokites than in the banakites (18.71 < 206Pb/204Pb < 18.77, 15.62 < 207Pb/204Pb < 15.63, 38.85 < 208Pb/204Pb < 38.91, and 18.77 < 206Pb/204Pb < 18.84, 15.62 < 207Pb/204Pb < 15.64, 38.94 < 208Pb/204Pb < 39.06, respectively). Overall, there is a clear tendency towards higher Sr, Pb and lower Nd isotope ratios with increasing degree of differentiation. This study suggests that the absarokites result from a low degree of partial melting (∼5%) of a highly metasomatized mantle source, which inherited its characteristics from an old subduction setting. The initiation of volcanic activity 1.8 Ma ago results from variations in the lithospheric thermal regime, probably related to lithospheric delamination as proposed for Anatolia (Pearce et al. 1990). The banakites are mainly generated by extensive fractional crystallisation (∼70%) of the absarokitic magma, with a limited amount (a few percents) of assimilation of an old crustal component, in the form of bulk assimilation or AFC processes, which both can explain the Sr, Nd and Pb isotope data.  相似文献   
23.
Trapped holes located on Al-O-Al bonds in kaolinite were studied by electron paramagnetic resonance spectroscopy (EPR) at 9.3 and 35 GHz applied to well-crystallized, X-ray irradiated and oriented samples. The Q-band EPR spectrum is characterized by three clearly separated groups of 11 quasi-equidistant superhyperfine lines centered at gxx=2.040±0.0005, gyy=2.020±0.0005 and gzz=2.002±0.001. In each of these groups, the 11 superhyperfine lines exhibit intensities according to the ratios 12345654321. An angular dependence of the Q-band EPR spectrum with respect to the magnetic field is demonstrated by measurements on oriented films of kaolinite. An appropriate numerical treatment of the EPR spectra is described, which allowed extraction of the SuperHyperfine Structures (SHFS). X-and Q-band spectra have also been simulated. It is concluded from these experiments that only one type of center is present. This center, labelled the B-center in the literature, is very probably a hole trapped on oxygen (O- center) atoms coupled to two octahedral aluminium.  相似文献   
24.
In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H2S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H2S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.  相似文献   
25.
The Pirin Mountains in southwest Bulgaria spatially mark a transition between the Mediterranean and temperate climate zones. Therefore they are also particularly relevant for research on high mountain climate and the effect of landscape transformation. Historical climate records gathered in the area have been researched, checked and statistically examined. The mountainous climate has been characterised and trends in the evolution of temperature and precipitation since 1931 have been outlined. There are objective evidences for an increasing annual mean temperature, longer vegetative periods and local droughts in spring and autumn. Significant changes also appear in climatic threshold values such as the number of frost change days. This last parameter is very important for the sustainability of mountainous ecosystems.  相似文献   
26.
Using orbital imaging radar, we have detected a large number of circular structures in the southwestern Egyptian desert, covering more than 4500 km2 close to the Gilf Kebir plateau in sandstones of Upper Cretaceous. Fieldwork confirmed that it is a new impact crater field: 13 craters from 20 m to 1 km in diameter were studied. The impact origin is confirmed by the observation of shock-related structures, such as shatter cones and planar fractures in quartz grains of breccia. Considering the extension of the crater field, it was possibly created by several meteorites that broke up when entering the atmosphere. To cite this article: P. Paillou et al., C. R. Geoscience 336 (2004).

Résumé

À partir d'images satellites issues de systèmes radar, nous avons détecté un grand nombre de structures circulaires dans le Sud-Ouest du désert égyptien, s'étendant sur plus de 4500 km2 à l'est du plateau du Gilf Kebir, dans des grès du Crétacé supérieur. Une étude sur le terrain a permis de vérifier qu'il s'agit d'un champ d'impacts météoritiques jusque là inconnu : 13 structures, d'un diamètre compris entre 20 m et 1 km, ont été reconnues comme cratères d'impact. La présence d'un grand nombre de cônes de percussion et de brèches dans lesquelles des quartz choqués à structures planaires ont été observés confirment l'hypothèse de l'impact. Considérant l'extension du champ d'impact, il a probablement été créé par plusieurs météorites qui se sont fragmentées dans l'atmosphère terrestre. Pour citer cet article : P. Paillou et al., C. R. Geoscience 336 (2004).  相似文献   
27.
Lherzolite xenoliths with calcite-rich microgranular secondary aggregates (0.1–1 mm) have been sampled in a Messinian breccia pipe from the northeastern part of the Languedoc volcanic province (South France). Their study shows that the carbonate crystallized at low pressure from a silico-carbonated melt resulting from partial melting of diopside and spinel at depth. This melting has been induced by injection, shortly before the eruption, of CO2 and H2O-rich fluids, stored probably within the upper lithospheric mantle and reset in motion by the magma ascension. These fluids would derive from decarbonation of levels of deeper lithospheric mantle previously metasomatized by carbonatitic melts. To cite this article: J.-M. Dautria et al., C. R. Geoscience 338 (2006).  相似文献   
28.
Fluoride concentrations have been determined in major French rivers and estuaries. The unpolluted estuary in the Loire has been compared with the Seine, Gironde and Charente where important discharges occur. Natural dissolved concentration can be multiplied by a factor of 30. Particulate fluorine concentration reach almost 2000 ppm in the Seine estuary. The percentage between free and complexed dissolved fluoride is not affected by the anthropic discharge. The present French rivers discharge of fluoride is 700% higher than the pristine value. At a global scale, dissolved fluoride has probably increased by 25% compared with the natural situation.  相似文献   
29.
In order to identify the major sources of trace metals (TM) in the Portuguese coastal waters, 58 surface water samples were collected during September 1988. The area sampled extended from the Tagus Estuary (down to a salinity of 25) to cape Ste Marie on the southern coast of Portugal. Dissolved metal concentrations in the fully marine waters ranged from 30 to 250 pM for Cd, 0.7–15 nM for Cu, 0.9–20 nM for Zn and 1.8–4.5 nM for Ni. Within the Tagus Estuary (salinity 25), concentrations increased to 3400 pM for Cd, 26 nM for Cu, 14 nM for Ni and 230 nM for Zn.The large-scale distribution of these metals is dominated by two strong continental sources, both probably linked to the exploitation of pyrite ores. In the Tagus Estuary, TM enrichments can be mostly attributed to a pyrite roasting plant located on the shore in front of Lisbon. Concerning the south Portuguese shelf waters, several hypotheses are proposed to explain their elevated metal concentrations. We particularly discussed the likely influence of the Tinto/Odiel rivers located 100 km eastward, an influence well known in the shelf waters of the Gulf of Cadiz. These rivers are extremely metal-rich because of acid mine tailings originating from their catchment. Between these two regions, upwelling of relatively metal-poor water largely contributes to the dilution of the continental inputs. Indeed, water exchanges on the shelf linked to the upwelling involve water fluxes 500 times higher than the Tagus River flow, and renew the coastal waters that are thus cleaned from terrestrial contamination. Contrary to many other upwelling systems in non-contaminated areas, the Portuguese upwelling does not act as a source of trace-metal enrichment of the continental margin waters.  相似文献   
30.
With the objective of investigating the windwind collision phenomenon and supporting contemporaneous X-ray observations, we have organized a large-scale, coordinated optical monitoring campaign of the massive, highly eccentric O9 III+B1 III binary Iota Orionis. Successfully separating the spectra of the components, we refine the orbital elements and confirm the rapid apsidal motion in the system. We also see strong interaction between the components during periastron passage and detect phase-locked variability in the spectrum of the secondary star. However, we find no unambiguous signs of the bow shock crashing on the surface of the secondary, despite the predictions of hydrodynamic simulations. Combining all available photometric data, we find rapid, phase-locked variations and model them numerically, thus restricting the orbital inclination to 50° i 70°.  相似文献   
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