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11.
Early miocene post-collisional calc-alkaline magmatism along the easternmost segment of the periadriatic fault system (Slovenia and Croatia) 总被引:1,自引:0,他引:1
Dr. R. Altherr Dr. B. Lugović Dr. H. -P. Meyer Dr. V. Majer 《Mineralogy and Petrology》1995,54(3-4):225-247
Summary Early Miocene calc-alkaline igneous rocks from the easternmost segment of the Periadriatic fault system can be subdivided into two series of different alkalinity: (1) Volcanics which occur in the vicinity of the Velenje-Rogatec Line range from high-alumina basalt via low-K and medium-K andesites to medium-K dacites. (2) In the Pohorje Mountains mafic rocks are lacking. A high-K tonalitic pluton crystallized at pressures of about 0.7 GPa as indicated by Al-in-hornblende barometry and accessory magmatic epidote. Rapid exhumation of the tonalite during dextral transtension along the Periadriatic fault system is indicated by tonalitic pebbles in Helvetian (?) clastic sediments. High-K andesitic to dacitic volcanics are interlayered with, and dikes cut, the clastic sediments.Compositional variations shown by the volcanics from the Velenje-Rogatec Line are consistent with fractionation of the observed phenocryst assemblages (olivine, plagioclase, clinopyroxene, orthopyroxene, titanomagnetite). Substantial fractionation of plagioclase is indicated by decreasing Sr/Nd and Sr/Y values and increasing negative Eu anomalies with increasing SiO2. All samples have chondrite-normalized HREE > 9.6 and low (Tb/Yb)n ratios (1.29–1.08). With increasing SiO2, the abundances of HREE and Y (18 to 39 ppm) increase and those of Sc (32.5 to 20.9 ppm) decrease slightly. These features, together with low Hf/Lu and Zr/Y values (10.1–5.7 and 5.7–3.6, respectively), rule out garnet as a major fractionating phase. Since (La/Yb)n values (3.24–6.59) do not increase with SiO2 and chondrite-normalized REE patterns do not show concave-upward shapes, fractionation of amphibole was probably insignificant. Although Rb/Cs values ( 18) are generally low, a significant contribution by continental crustal materials to the magmas by an AFC process is suggested by negative correlations of Nb/U(7.16 to 3.14) and Nb/Th(2.14 to 0.87) values with SiO2, as well as by low Hf/Ta(7.8–3.4), and in part also by K/Rb (340-71) and Zr/Rb (5.0–1.7) values.Rocks from the Pohorje Mountains have high abundances of U. Values of Nb/U and Nb/Th are low (3.55 to 1.85 and 1.27 to 0.64, respectively) and are negatively correlated with SiO2. These features, in combination with high values of Ba/Nb (56 to 93), Ba/La (23–30), and Rb/Cs (19–56), as well as with previously published 18O values ( 9) for the tonalite indicate a substantial contribution of the continental crust to these magmas. High Sr abundances (455 to 984 ppm) and moderate negative Eu anomalies suggest that fractionation of plagioclase was of minor importance. Although the rocks have relatively low Sc (9.3 to 3.8 ppm) and Y (21 to 14 ppm) contents, low (Tb/Yb)n values (1.67–1.14) indicate that garnet was not a major fractionating phase. Instead, fractionation of amphibole is a viable mechanism to explain the combination of high (La/Yb)n (21.8–13.1) and low (Tb/Yb)n.
With 9 Figures 相似文献
Untermiozäner, kalkalkaliner Post-Kollisions-Magmatismus entlang des östlichsten Segmentes des periadriatischen Störungssystems (Slowenien und Kroatien)
Zusammenfassung Untermiozäne Kalkalkali-Magmatite aus dem östlichen Bereich des Periadriatischen Lineaments gliedern sich in zwei Serien unterschiedlicher Alkalinität: (1) Entlang der Velenje-Rogatec-Linie treten High-Al-Basalte, Low-K- und Medium-K-Andesite und Medium-K-Dazite auf. (2) Im Pohorje-Gebirge, wo basische Magmatite fehlen, kristallisierte ein High-K-Tonalit bei Drücken von ca. 0.7 GPa (Al-in-Hornblende-Barometer, magmatischer Epidot). Gerölle dieses Tonalits in einer untermiozänen (Helvet?) klastischeu Abfolge belegen eine schnelle Heraushebung des Tonalits durch dextrale Transtension im östlichsten Bereich des periadriatischen Lineaments. Eingeschaltet in die klastischen Sedimente sind andesitische bis dazitische Pyroklastika und Laven sowie diskordante dazitische Gänge, die alle der High-K-Serie angehören.Die chemische Variation innerhalb der Vulkanitserie von der Velenje-Rogatec-Linie läßt sich durch Fraktionierung der Einsprenglingsminerale Olivin, Plagioklas, Klinopyroxen, Orthopyroxen und Titanomagnetit erklären. Abnehmende Sr/Nd- und Sr/Y-Werte und zunehmende negative Eu-Anomalien mit steigendem SiO2 weisen auf eine bedeutende Plagioklas-Fraktionierung hin. Alle Vulkanite besitzen hohe Gehalte an schweren Seltenen Erden (chondritnormiert > 9.6) und geringe (Tb/Yb)n-Werte (1.29–1.08). Mit zunehmendem SiO2 nehmen die Gehalte an Yb(2.02 bis 4.30 ppm) und Y(18 bis 39 ppm) zu, während die Sc-Gehalte (32.5 bis 20.9 ppm) nur geringfügig abnehmen. Diese Charakteristika, zusammen mit geringen Hf/Lu- und Zr/Y-Werten (10.1–5.87 bzw. 5.7–3.6), schließen Granat als wesentliche, fraktionierende Phase aus. Da die (La/Yb)n-Verhältnisse (3.24–6.59) nicht mit SiO2 korrelieren und die chondritnormierten SeltenenErden-Muster keine nach oben konkaven Formen aufweisen, spielte die Fraktionierung von Amphibol keine wesentliche Rolle. Trotz geringer Rb/Cs-Werte ( 18) wird eine beträchtliche krustale Kontamination der Magmen angenommen. Für einen AFC-Prozeß sprechen negative Korrelationen von Nb/U(7.16–3.14) und Nb/Th(2.14–0.87) mit SiO2 (bei steigenden Nb-, U- und Th-Gehalten), geringe Hf/Ta-Werte (7.8–4.3) und teilweise auch geringe K/Rb- (340-71) und Zr/Rb-Verhältnisse (5.0–1.7).Die Magmatite des Pohorje-Gebirges weisen hohe U-Gehalte sowie geringe Nb/U-und Nb/Th-Verhältnisse auf (3.55–1.85 bzw. 1.27–0.64), die eine schwache negative Korrelation mit SiO2 zeigen. Zusammen mit hohen Ba/Nb-(56–93), Ba/La-(23-30) und Rb/Cs-Verhältnissen (19–56) sowie bereits publizierten 8O-Werten ( 9) weisen diese Eigenschaften auf einen beträchtlichen Anteil assimilierten Krustenmaterials in den Magmen hin. Hohe Sr-Gehalte (455–984 ppm) und relativ geringe negative Eu-Anomalien machen es unwahrscheinlich, daß während des AFC-Prozesses in der Unterkruste wesentliche Mengen an Plagioklas fraktioniert wurden. Obwohl die Gehalte an Sc (9.3–3.8 ppm) und Y (21–14 ppm) relativ gering sind, scheidet Granat aufgrund der geringen (Tb/Yb)n- Verhältnisse (1.67–1.14) als dominierende Fraktionierungsphase aus. Die Kombination von hohen (La/Yb)n- Verhältnissen (21.8–13.1) und geringen (Tb/Yb)n-Verhältnissen deutet eher auf Amphibol als wichtige, fraktionierende Phase hin.
With 9 Figures 相似文献
12.
Aleksandar Mezga Christian A. Meyer Blanka Cvetko Teovi Zlatan Bajraktarevi Ivan Gui 《Cretaceous Research》2006,27(6):735-742
The first discovery of dinosaur footprints on the Dalmatian part of the Adriatic-Dinaric carbonate platform (ADCP) is reported. They constitute the geologically youngest record of footprints on the ADCP. The trackbearing layer was formed in the intertidal environment and represents the final stage of a shallowing-upward cycle. Just below it, a heavy dinoturbated limestone layer can be observed. Microfacies analysis, incorporating evidence from benthic foraminifera and algae, indicates a Late Turonian–Early Coniacian age. The overall morphology and size of the footprints points to sauropod dinosaurs; they represent the largest forms recorded so far on the ADCP. This hints at a prolonged sauropod presence on the platform and to its Late Cretaceous connection to the continent rather than isolation. 相似文献
13.
Fabien Nex Gerhard Schäfer Jean-Marie Côme Timothy M. Vogel 《Comptes Rendus Geoscience》2006,338(5):297-306
The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006). 相似文献
14.
Christoph Gaedicke Hans-Ulrich Schlüter Hans Albert Roeser Alexander Prexl Bernd Schreckenberger Heinrich Meyer Christian Reichert Peter Clift Shahid Amjad 《Tectonophysics》2002,355(1-4)
The nature and origin of the sediments and crust of the Murray Ridge System and northern Indus Fan are discussed. The uppermost unit consists of Middle Miocene to recent channel–levee complexes typical of submarine fans. This unit is underlain by a second unit composed of hemipelagic to pelagic sediments deposited during the drift phase after the break-up of India–Seychelles–Africa. A predrift sequence of assumed Mesozoic age occurring only as observed above basement ridges is composed of highly consolidated rocks. Different types of the acoustic basement were detected, which reflection seismic pattern, magnetic anomalies and gravity field modeling indicate to be of continental character. The continental crust is extremely thinned in the northern Indus Fan, lacking a typical block-faulted structure. The Indian continent–ocean transition is marked on single MCS profiles by sequences of seaward-dipping reflectors (SDR). In the northwestern Arabian Sea, the Indian plate margin is characterized by several phases of volcanism and deformation revealed from interpretation of multichannel seismic profiles and magnetic anomalies. From this study, thinned continental crust spreads between the northern Murray Ridge System and India underneath the northern Indus Fan. 相似文献
15.
16.
Thomas Backhaus Rolf Altenburger sa Arrhenius Hans Blanck Michael Faust Antonio Finizio Paola Gramatica Matthias Grote Marion Junghans Wiebke Meyer Manuela Pavan Tobias Porsbring Martin Scholze Roberto Todeschini Marco Vighi Helge Walter L. Horst Grimme 《Continental Shelf Research》2003,23(17-19):1757
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined. 相似文献
17.
We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite
to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol)
has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical
signals on the amount of substance undergoing the reduction process.
Received December 21, 1995/Revised, accepted June 29, 1996 相似文献
18.
Jean-Marie Dautria Jean-Michel Liotard Danièle Briot 《Comptes Rendus Geoscience》2004,336(11):971-981
Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<87Sr/86Sri<0.71192), and display basaltic 143Nd/144Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004). 相似文献
19.
Georges Aouad Valérie Geoffroy Jean-Marie Meyer Jean-Louis Crovisier Denis Damidot Peter Stille 《Comptes Rendus Geoscience》2005,337(15):1340-1347
The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005). 相似文献
20.
Gold mineralization at Hutti is confined to a series of nine parallel, N–S to NNW–SSE trending, steeply dipping shear zones.
The host rocks are amphibolites and meta-rhyolites metamorphosed at peak conditions of 660±40°C and 4±1 kbar. They are weakly
foliated (S1) and contain barren quartz extension veins. The auriferous shear zones (reefs) are typically characterized by four alteration
assemblages and laminated quartz veins, which, in places, occupy the entire reef width of 2–10 m, and contain the bulk of
gold mineralization. A <1.5 m wide distal chlorite-sericite (+biotite, calcite, plagioclase) alteration zone can be distinguished
from a 3–5 m wide proximal biotite-plagioclase (+quartz, muscovite, calcite) alteration zone. Gold is both spatially and temporally
associated with disseminated arsenopyrite and pyrite mineralization. An inner chlorite-K-feldspar (+quartz, calcite, scheelite,
tourmaline, sphene, epidote, sericite) alteration halo, which rims the laminated quartz veins, is characterized by a pyrrhotite,
chalcopyrite, sphalerite, ilmenite, rutile, and gold paragenesis. The distal chlorite-sericite and proximal biotite-plagioclase
alteration assemblages are developed in microlithons of the S2–S3 crenulation cleavage and are replaced along S3 by the inner chlorite-K-feldspar alteration, indicating a two-stage evolution for gold mineralization. Ductile D2 shearing, alteration, and gold mineralization formed the reefs during retrograde evolution and fluid infiltration under upper
greenschist to lower amphibolite facies conditions (560±60°C, 2±1 kbar). The reefs were reactivated in the D3 dextral strike-slip to oblique-slip environment by fault-valve behavior at lower greenschist facies conditions (ca. 300–350°C),
which formed the auriferous laminated quartz veins. Later D4 crosscutting veins and D5 faults overprint the gold mineralization. The alteration mineralogy and the structural control of the deposit clearly points
to an orogenic style of gold mineralization, which took place either during isobaric cooling or at different levels of the
Archean crust. From overlaps in the tectono-metamorphic history, it is concluded that gold mineralization occurred during
two tectonic events, affecting the eastern Dharwar craton in south India between ca. 2550 – 2530 Ma: (1) The assemblage of
various terranes of the eastern block, and (2) a tectono-magmatic event, which caused late- to posttectonic plutonism and
a thermal perturbation. It differs, however, from the pre-peak metamorphic gold mineralization at Kolar and the single-stage
mineralization at Ramagiri. Notably, greenschist facies gold mineralization occurred at Hutti 35–90 million years later than
in the western Dharwar craton.
Editorial handling: G. Beaudoin 相似文献