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11.
Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal   总被引:1,自引:0,他引:1  
This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the 13C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in 18O is mainly inherited from the isotopic composition of Baikal water.  相似文献   
12.
Argon and nitrogen isotopes of air in polar ice cores provide constraints on past temperature and firn thickness, with relevance to past climate. We developed a method to simultaneously measure nitrogen and argon isotopes in trapped air from the same sample of polar ice. This method reduces the time required for analysis, allowing large numbers of measurements. We applied this method to the entire Holocene sequence of the GISP2 ice core (82.37-1692.22 m) with a 10-20 year sampling interval (670 depths). δ40Ar and δ15N show elevated values in the oldest part of the dataset, consistent with a thicker firn layer and increased temperature gradient in the firn due to the legacy of the abrupt warming at the end of the Younger Dryas interval and the gradual warming during the Preboreal interval (11.5-10.0 ka). The Preboreal Oscillation and the 8.2k event are clearly recorded. The data show remarkable stability after the 8.2k event.Available data suggests that post-coring gas loss involves two distinct types of fractionation. First, smaller molecules with less than a certain threshold size leak through the ice lattice with little isotopic fractionation. Second, gas composition changes via gas loss through microcracks, which induces isotopic fractionation. These two gas loss processes can explain most trends in our data and in other ice core records.  相似文献   
13.
Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m−3) and RGM (8.1 ± 5.6 pg m−3) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m−3, 3.2 ± 2.9 pg m−3 for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m−3). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s−1 for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s−1 for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m−2, or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m−3) and RGM (50–150 pg m−3) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).  相似文献   
14.
Linearized water wave theory is used to show that a submerged long circular cylinder suitably constrained by springs and dampers to make small harmonic oscillations, can be extremely efficient in absorbing the energy in an incident regular wave whose crests are parallel to the axis of the cylinder. Experimental results are described which confirm the theory for small amplitude waves and which suggest that the device can still be fairly efficient in waves of moderate amplitude.  相似文献   
15.
A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m2/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.  相似文献   
16.
Hydroids are typically attached, benthic cnidarians that feed on a variety of small prey. During sampling on Georges Bank in spring 1994, we found huge numbers of hydroids suspended in the plankton. They fed on young stages of copepods that are an important prey for fish, as well as on young fish themselves. Two independent methods were used to estimate feeding rates of the hydroids; both indicate that the hydroids are capable of consuming from 50% to over 100% of the daily production of young copepods. These results suggest that hydroids can have a profound effect on the population dynamics of zooplankton and young fish on Georges Bank.  相似文献   
17.
Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.  相似文献   
18.
19.
The role of relative sea-level rise as a cause for the rapid erosion of Louisiana's barrier island coast is investigated through a numerical implementation of a modified Bruun rule that accounts for the low percentage of sand-sized sediment in the eroding Louisiana shoreface. Shore-normal profiles from 150 km of coastline west of the Mississippi delta are derived from bathymetric surveys conducted during the 1880s, 1930s and 1980s. An RMS difference criterion is employed to test whether an equilibrium profile form is maintained between survey years. Only about half the studied profiles meet the equilibrium criterion; this represents a significant limitation on the potential applicability of the Bruun rule. The profiles meeting the equilibrium criterion, along with measured rates of relative sea-level rise, are used to hindcast shoreline retreat rates at 37 locations within the study area. Modeled and observed shoreline retreat rates show no significant correlation. Thus, in terms of the Bruun approach, relative sea-level rise has no power for hindcasting (and presumably forecasting) rates of coastal erosion for the Louisiana barrier islands.  相似文献   
20.
ANGUS photographs and ALVIN observational data from Fracture Zones A and B on the Mid-Atlantic Ridge near 37°N were examined for structural and sedimentological indications of the area's tectonics. Both transform fault zones are characterized by volcanic rubble, breccias, chalks, and undisturbed sediments typical of slow-slipping transforms.The photographic data consist of 16 camera-sled traverses from the FAMOUS Expedition using the ANGUS deep-towed camera system. These data cover several different morphotectonic provinces along the strike of both slow-slipping (2 cm yr-1) fracture zones. ALVIN data come from two dives in the central part of Fracture Zone B. The two fracture zones differ in their distribution of fractured and sheared chalks which indicate regions of strike-slip deformation along the transform. Evidence of shearing is confined to a very narrow region in the center of FZ A, whereas the zone of shear deformation is as much as 6 km wide across FZ B. Other differences include the morphology and depth of the transform valleys and their contiguous nodal basins and the extent of exposures of fresh-looking volcanic ridges in the nodal basin.  相似文献   
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