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511.
The paper presents the automatic time recording of transits of the image of a star across the hairs in the visual field of a telescope and the automatic reception of radio time signals for the determination of astronomical latitude and longitude of a station using an astrolabe. The automatization was achieved by an electronic calculator Hewlett Packard HP41CX and an especially constructed relay. The method proved very practical in the course of making the network of geoidal points more dense for the needs of geodesy.  相似文献   
512.
Summary The synthetic TlPbSbS3 represents a rare example of a sulphosalt with statistical distribution of Tl, Pb and Sb in the structure. Within the TlSbS2-PbS system, TlPbSbS3 is the end member of the solid solution series with TlSbS2, but no solubility with PbS is detected. The high temperature-TlPbSbS3 is orthorhombic and inverts at about 620 K to the low-temperature phase. The low-temperature modification of TlPbSbS3 was structurally investigated by X-ray powder diffraction and by the Rietveld analysis of the data. The structure is monoclinic, with a = 4.1707(4) Å, b = 4.2856(4) Å, c = 12.157(1) Å, = 105.49(1)°, space group P21/c. Like in the high-temperature form, there is a cation disorder over the equivalent positions in the structure. The interatomic distances of (Tl, Ph, Sb) to S are 2.71, 2.72, 2.88, 3.15, 3.29, 3.51 (Å). There is a close similarity between the TlPbSbS3 polymorphs and the and forms of SnS, as regards the atomic coordinations and the general structure types and the same type of phase transformation is supposed for both cases. The small differences in the structure type and symmetry, between the low temperature forms of SnS and TlPbSbS3, result probably from stronger metal-metal interactions in the latter. A substitution-derivative relation to SnS type is established owing to the strong structural effect of the lone electron pairs of Tl and Sb. The substitution of Ag for Tl and Bi for Sb in ABCS3 type compounds diminishes this effect and PbS type structures are produced.
Die zwei Polymorphen von TlPbSbS3 und die Strukturellen Beziehungen von Phasen in System TlSbS2-PbS
Zusammenfassung Die synthetische Phase TlPbSbS3 ist ein seltenes Beispiel von einem Sulfosalz mit der statistischen Verteilung von TI, Pb und Sb in der Struktur. In der TlSbS2-PbS Phasensystem, ist TlPbSbS3 das Endmitglied der Mischkristallreihe, die sich im Richtung TlSbS2 ausstreckt. Weitere Ausdehnung der Mischkristallreihe in der Richtung SbS konnte nicht bewiesen werden. Die Hochtemperatur-TlPbSbS3 ist rhombisch und wird beim 620 K in die Tieftemperatur Modifikation umgewandelt. Die Tieftemperaturphase ist mit der Röntgenpulverdiffraktion und Rietveld Methode strukturell untersucht worden. Die ist monoklin, mit den Gitterkonstanten: a = 4.1707(4) Å, b = 4.2856(4) Å, c = 12.157(1) Å, = 105.49(1)°, Raumgruppe P21/c. Die statistische Verteilung von Kationen ist auch hier vorhanden. Die zwischenatomare Abstande (Tl, Pb, Sb)-S sind: 2.71, 2.72, 2.88, 3.14, 3.28, 3.51 (Å). Es besteht eine enge Verwandschaft zwischen den polymorphen Modifikationen von TlPbSbS3 und den und Polymorphen von SnS, was die atomare Koordinationen und den generellen Strukturtypus betrifft, wobei ein ähnlicher Mechanismus der Phasenumwandlung für die beiden Fälle vermutet werden könnte. Die Differenzen in der Struktur und Symmetrie zwischen der Tieftemperaturmodifikationen von SnS und TlPbSbS3 sind wahrscheinlich durch die bedeutende Metall-Metall Wirkungen in der zweiten verursacht. Die Phase TlPbSbS3 ist ein substitution-derivative von der SnS Struktur, was durch die starke lone-electron-pair Aktivität von Kationen zu erklären ist. Die Ersetzung von Tl durch Ag und Sb durch Bi vermindert diese Aktivität und die entstandenen Strukturen sind in dem Fall dem PbS-Typus verwandt.


With 3 Figures  相似文献   
513.
Summary A hitherto unknown TI-sulfosalt, containing antimony and arsenic, was discovered by ore microscopy (including quantitative reflectance measurements) and electron microprobe analysis in samples from the Allchar TI-Sb-As sulfide ore deposit (Macedonia). The chemical formula is TI5Sb9(As,Sb)4S22, X-ray single crystal and powder diffration data gave the lattice parameters o = 7.393(4) Å, b0 = 8.707(2) Å, co = 17.584(3) Å, = 103.81(1)°, = 91.79(1)°, = 109.50(1)°; space group , Z = 1. The new mineral and the new mineral naine jankoviéite have been approved by the IMA/CNMMN.
Jankoviit, Tl5Sb9(As,Sb)4S22, ein neues TI-Sulfosalz aus Allehar, Macedonien
Zusammenfassung Ein bislang unbekanntes Thallium-Antimon-Arsen-Sulfosalz wurde mittels Erzmikroskopie (inklusive quantitativer Reflexionsmessungen) und Elektronenstrahl-Mikrosonde in Proben aus der TI-Sb-As-Sulfid-Lagerstätte Allchar in Macedonien entdeckt. Die chemische Formel lautet Tl5Sb9(As,Sb)4S22, aus Röntgen-Einkristallaufnahmen und Pulverdiffraktogrammen konnten folgende Gitterkonstanten bestimmt werden: ao = 7.393(4) Å, bo = 8.707(2) _Å, co = 17.584(3) Å, a = 103.81(1)°, = 91.79(1)°, = 109.50(1)°; Raumgruppe , Z = 1. Das neue Mineral, sowie der neue Mineralname Jankoviit wurden durch die IMA/CNMMN anerkannt.
  相似文献   
514.
Electrochemical methods based on adsorption of organic molecules at the mercury electrode-solution interface were used to investigate surfactant production by marine phytoplankton. Six species of marine phytoplankton, representing the classes of Bacillariophyceae, Haeptophyceae, Chlorophyceae and Cryptophyceae, were studied in batch cultures.Our experimental results showed that surfactants were produced in culture media by healthy exponential growing cells. The measured response was found to depend on the particular species and the age of the culture.Total surfactant content in culture media generally increased with cell density, while surfactants per cell showed an inverse relation to cell density. However, we found that in Cryptomonas culture medium, during the exponential growth, excretion of the insoluble surfactant material per cell was independent of cell concentration.In addition to culture experiments, surfactant activity at several northern Adriatic stations was measured during various stages of phytoplankton bloom. It was concluded that a significant part of surfactant activity in a seawater column is due to phytoplankton production.  相似文献   
515.
DNA damage and apoptosis in the mussel Mytilus galloprovincialis   总被引:4,自引:0,他引:4  
The effects of known genotoxic substances (4-nitroquinoline-N-oxide, benzo[a]pyrene, teniposide, etoposide, cycloheximide, tributyltin) on human cells (FLC, HL-60) and on mussels were investigated. The correlations between formation of DNA strand breaks and DNA fragmentation characteristic for the process of apoptosis were estimated. Strand breaks induced by 4-nitroquinoline-N-oxide and benzo[a]pyrene did not correlate with DNA fragmentation detected in the process of apoptosis. Induction of internucleosomal DNA fragmentation in HL-60 cells was initiated by teniposide, etoposide and tributyltin, while in the gills of mussels this was detected only with tributyltin. Levels of DNA strand breaks in natural mussel populations, living at locations under the influence of urban and industrial wastes, do not mirror the apoptotic processes.  相似文献   
516.
517.
Karst aquifers represent one of the main sources of water supply in Serbia. Wide distributions of karstic areas, abundant reserves, and excellent quality of karst groundwater have been the reasons for its extensive use in water supply systems throughout the country. In Serbia, 70 karstic sources have been tapped for centralized water supply, with the assessed minimal capacity exceeding 4.5 m3/s. Most of the large cities of Eastern and Western Serbia currently use karst groundwater for water supply; however, due to unstable flow regime when only natural springflow is tapped, numerous problems arise during the recession period (summer–autumn). During the last two decades, after favorable conditions had been confirmed through hydrogeological survey and feasibility studies, several newly constructed systems for artificial control of karst aquifers (mostly in Eastern Serbia) resulted in significantly improved water supply.  相似文献   
518.
Summary In connection with a number of recent publications on anomalous (excessive) absorption of shortwave radiation (SWR) by clouds, the data of aircraft observations of spectral and total SWR vertical profiles in the troposphere obtained within the CAENEX, GAAREX and FGGE programmes have been discussed. These data demonstrated persuasively the existence of substantial SWR absorption by clouds in the visible wavelength region. In this context, the results of simulation numerical medelling of the SWR transfer in clouds have been considered. These show a significant enhancement of the SWR absorption by clouds due to an increase of the mean free path of photons under an impact of multiple scattering in clouds. Another important consideration may be the impact of SWR-absorbing pollutants in clouds, especially soot aerosols.With 4 Figures  相似文献   
519.
Summary Koshava is a gusty wind of moderate to strong intensity, blowing from the south-eastern direction, over the area of the Republic of Serbia. It is caused by the interaction between the synoptic circulation and the orography of the Carpathian and the Balkan mountains. The Koshava wind can damage buildings, factories and industrial plants or city infrastructure. Therefore it is important to estimate its gust and the gustiness factor on the basis of the measured data.This paper discusses a statistical analysis of wind data in the maximum influence area of the Koshava wind in the periods of maximum duration of Koshava. The focus of the paper is the examination of urban and suburban effects on Koshava wind and the correlation between the instantaneous maximum wind speed and the hourly mean wind speed. The best fitting with various empirical distributions is proposed.With 10 Figures  相似文献   
520.
In the Central Dinarides and South Tisia different Paleozoic complexes occur in four geotectonic zones: (1) comparatively autochthonous units located in the cores of disrupted anticlines of the External Dinarides; (2) allochthonous disrupted units accompanied by more predominant Triassic formations in the Sava Nappe, which is thrust onto the northeastern margin of the External Dinarides; (3) allochthonous disrupted units, also together with Triassic formations, in the Pannonian and Durmitor nappes of the Internal Dinarides; and (4) polymetamorphic sequences in basement of the Pannonian Basin and South Tisia, respectively. This paper presents basic geological features for the main Paleozoic areas included in these four zones. The tectonostratigraphic units of the first two zones were related to the Gondwana passive continental margin, those of the third zone to the Paleotethyan oceanic realm, and those of Tisia to the active Laurussia margin. Geodynamic evolution of all these Paleozoic complexes was related to opening and closure of the Rheic and Paleotethys Oceans. Rifting processes along North Gondwana started in the Silurian, locally in the Cambrian-Ordovician, and were followed by the Late Silurian/Devonian opening of the Paleotethys. Subduction processes were active by the end of the Devonian and at the beginning of the Carboniferous along the Laurussia margin. They were followed during the Westphalian by main Variscan deformation during collision of Gondwana and Laurussia. Associated metamorphism was very low-grade in the Paleozoic units of the Sava Nappe, low-grade to epidote-amphibolite grade within the Paleozoic complexes of the Pannonian and Durmitor nappes in the Internal Dinarides, and poly-metamorphic with migmatites and granitoids in South Tisia. These processes gave rise to a Pangea stage with the Variscan basement disconformably overlain by Late Carboniferous and Permian sediments.  相似文献   
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