The speciation of Fe(II) and Fe(III) in natural waters     

Frank J. Millero  Wensheng Yao  Jennifer Aicher 《Marine Chemistry》1995,50(1-4)

The interactions of Fe(II) and Fe(III) with the inorganic anions of natural waters have been examined using the specific interaction and ion pairing models. The specific interaction model as formulated by Pitzer is used to examine the interactions of the major components (Na⁺, Mg²⁺, Ca²⁺, K⁺, Sr²⁺, Cl⁻, SO₄⁻, HCO₃⁻, Br⁻, CO₃²⁻, B(OH)₄⁻, B(OH)₃ and CO₂) of seawater and the ion pairing model is used to account for the strong interaction of Fe(II) and Fe(III) with major and minor ligands (Cl⁻, SO₄²⁻, OH⁻, HCO₃⁻, CO₃²⁻ and HS⁻) in the waters. The model can be used to estimate the activity and speciation of iron in natural waters as a function of composition (major sea salts) and ionic strength (0 to 3 M). The measured stability constants (K_FeX^*) of Fe(II) and Fe(III) have been used to estimate the thermodynamic constants (K_FeX) and the activity coefficient of iron complexes (γ_FeX) with a number of inorganic ligands in NaClO₄ medium at various ionic strengths: In(K_FeX/γ_Feγ_X) = InK_FeX − In(γ_FeX) The activity coefficients for free ions (γ_Fe, γ_x) needed for this extrapolation have been estimated from the Pitzer equations. The activity coefficients of the ion pairs have been used to determine Pitzer parameters (B_FeX, B_FeX⁰, C_FeX^φ) for the iron complexes. These results make it possible to estimate the stability constants for the formation of Fe(II) and Fe(III) complexes over a wide range of ionic strengths and in different media. The model has been used to determine the solubility of Fe(III) in seawater as a function of pH. The results are in good agreement with the measurements of Byrne and Kester and Kuma et al. When the formation of Fe organic complexes is considered, the solubility of Fe(III) in seawater is increased by about 25%.  相似文献   

The rise of seafood awareness campaigns in an era of collapsing fisheries     

Jennifer L. Jacquet  Daniel Pauly 《Marine Policy》2007

The human appetite for seafood has intensified and so has overfishing and damage to marine ecosystems. Recently, the response to the fisheries crisis has included a considerable effort directed toward raising the seafood awareness of consumers in North America and Europe. The resulting campaigns aim to affect the seafood demand and to lead to a sustainable seafood supply. Though there are indicators of some regional successes, lack of support by the Asian market and the proliferation of self-serving seafood labels are but two of the many significant limitations of these campaigns. This contribution investigates the difficulties and successes of seafood awareness campaigns, as well as the need for indicators of campaign effectiveness.  相似文献   

CYP1A- and CYP3A-immunopositive protein levels in digestive gland of the mussel Mytilus galloprovincialis from the Mediterranean Sea     

Jennifer P. Shaw  Lawrence D. Peters  J. Kevin Chipman 《Marine environmental research》2004,58(2-5):649

CYP1A-immunopositive protein can be elevated in response to planar PAHs and PCBs in Mytilus sp. digestive gland whilst CYP3A-immunopositive protein has been associated with testosterone 6β-hydroxylation in fish. Levels of CYP1A- and CYP3A-immunopositive protein were determined in Mytilus galloprovincialis digestive gland microsomes collected from 12 sites in the Mediterranean Sea during May and September 2001. CYP1A-immunopositive protein was significantly highest at contaminated sites whilst CYP3A-immunopositive protein was significantly lowest. A weak negative correlation (r²=0.21) was seen between CYP1A- and CYP3A-immunopositive protein. Little evidence of differences at the different sampling times was observed. These results confirm previous work indicating elevation of CYP1A-immunopositive protein in Mytilus sp. digestive gland at contaminated sites. Further study is required to characterise CYP3A-like expression in Mytilus and to elucidate the consequences of possible CYP3A-like down-regulation at contaminated sites.  相似文献   

Cloning and analysis of the CYP1A promoter from the atlantic killifish (Fundulus heteroclitus)     

Powell WH  Morrison HG  Weil EJ  Karchner SI  Sogin ML  Stegeman JJ  Hahn ME 《Marine environmental research》2004,58(2-5):119-124

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Spatial distribution of juvenile and adult female Tanner crabs (Chionoecetes bairdi) in a glacial fjord ecosystem: implications for recruitment processes     

Nielsen  Julie K.; Taggart  S. James; Shirley  Thomas C.; Mondragon  Jennifer 《ICES Journal of Marine Science》2007,64(9):1772-1784

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High-Latitude Springtime Photochemistry. Part I: NOx, PAN and Ozone Relationships     

Harald J. Beine  Daniel a. Jaffe  John a. Herring  Jennifer a. Kelley  Terje Krognes  Frode Stordal 《Journal of Atmospheric Chemistry》1997,27(2):127-153

Springtime measurements of NO_x, ozone, PAN,J(NO₂), and other compounds were made near Ny-Ålesund,Svalbard (78°54N, 11°53E), in 1994 and Poker Flat,Alaska (65°08N, 147°29W), in 1995. At Svalbard medianmixing ratios for PAN and NO_x of 237 and 23.7 pptv,respectively, were observed. The median mixing ratios at Poker Flat for PANand NO_x were 79.5 and 85.9 pptv, respectively. These data areused to estimate thermal PAN decomposition using several differentapproaches. At Svalbard PAN decomposition was very small, while at PokerFlat up to 30 pptv/h PAN decomposed. At both sites the NO_x/PANratio increased with temperature between –10 and 20°C implyingthat PAN decomposition is an important NO_x source. In-situozone production was calculated from the measured NO, NO₂,O₃, J(NO₂), and temperature data, using thesteady state assumption Median ozone production was 605 pptv/h at PokerFlat, and one order of magnitude smaller at Svalbard during the daytime.Only at Poker Flat could a direct influence on the diurnal ozone cycle beobserved from in-situ production. These results imply that PAN decompositionis a major source of NO_x in the high latitude troposphere, andthat this contributes to the observed spring maximum in surface ozone.  相似文献   

The politics of firm networks: How large firm power limits small firm innovation     

Susan Christopherson  Jennifer Clark 《Geoforum》2007,38(1):1-3

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Explicitly incorporating spatial dependence in predictive vegetation models in the form of explanatory variables: a Mojave Desert case study     

Jennifer Miller  Janet Franklin 《Journal of Geographical Systems》2006,8(4):411-435

Predictive vegetation modeling is defined as predicting the distribution of vegetation across a landscape based upon its relationship with environmental factors. These models generally ignore or attempt to remove spatial dependence in the data. When explicitly included in the model, spatial dependence can increase model accuracy. We develop presence/absence models for 11 vegetation alliances in the Mojave Desert with classification trees and generalized linear models, and use geostatistical interpolation to calculate spatial dependence terms used in the models. Results were mixed across models and methods, but in general, the spatial dependence terms more consistently increased model accuracy for widespread alliances. GLMs had higher accuracy in general.  相似文献   

Geostatistical analysis in weathering studies: case study for Stanton Moor building sandstone     

Jennifer M. McKinley  Patricia Warke  Christopher. D. Lloyd  Alastair H. Ruffell  Bernard J. Smith 《地球表面变化过程与地形》2006,31(8):950-969

Geostatistical techniques for spatial prediction and spatial simulation have been used in an innovative application to the study of weathering of natural building stone. The study investigates the differences in the spatial variation of permeability characteristics between fine‐ and coarse‐grained Stanton Moor building sandstone. Non‐destructive permeability measurements, using an unsteady‐state Portable Probe Permeameter, were made on three adjacent faces of two cubic blocks representative of fine‐ to medium‐grained and medium‐ to coarse‐grained Stanton Moor Sandstone. The findings provide greater understanding in the investigation of the durability characteristics of the Stanton Moor Sandstone and show that the spatial distribution and variability of permeability is more important in predicting the overall strength and weathering properties than mean permeability and absolute minimum and maximum values. The results suggest that both primary textural characteristics (such as grain size) and extent of cementation appear to be important factors in determining the overall durability properties of Stanton Moor Sandstone as a building stone. Geostatistical analysis has been shown to be an important tool in the characterization of spatial variation for the investigation of weathering of building stones. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Adaptive Governance and Climate Change in the Tropical Highlands of Western South America   总被引：2，自引：1，他引：2  

Kenneth R. Young  Jennifer K. Lipton 《Climatic change》2006,78(1):63-102

Climate changes occurring during the past several decades in the high elevations of the tropical Andes Mountains have implications for the native plant and animal species, for the ecological integrity of the affected land cover, and for the human-biophysical systems involved. Consequences are also probable for rural inhabitants and their livelihoods, especially for farmers and pastoralists. Biophysical factors have always changed in these mountainous zones; the extent and degree of alteration acting on native and agricultural biodiversity is the concern. Addressing these climate changes is probably within the adaptive capacity of many local land-use systems, unless external socioeconomic or political forces are unsupportive or antagonistic. Suitable programs to provide information, subsidies, or alternatives could be designed. We highlight some of the inherent resiliencies of natural and cultural systems in the Andes and suggest that these systems contain lessons that could be useful elsewhere, in terms of the traits that allow for the sustainable utilization of dynamic and heterogeneous landscapes.  相似文献