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181.
On the first of January 1992, unusual earthquake activity started in Steigen, northern Norway. By 31 December, 1992, a total of 207 events had been recorded in several pulses. Among these, several events with magnitudes larger than 3.0 ( M c) were also felt by the people. The epicentral distribution of these events seems to suggest that they all are concentrated in a small region (approximately 10 km in diameter) in the Brennvika Bay (67.8°N, 14.9°E), between Leinesfjorden in the north and Nordfolda in the south. The distribution of events in time is characteristic of a swarm in which no dear evidence of a mainshock–aftershock sequence was observed. Macroseismic intensity surveys as well as synthetic modelling indicate shallow focal depths in the range 5–8 km. Based on a composite focal mechanism, indicating an oblique-slip fault striking NE with a normal component dipping NW, combined with an observed NE trend in the epicentres and the focal depths, these events correlate with a previously proposed fault zone along Nordfolda. The NE trend has been dominant in the area throughout geological time, starting from the Caledonian Orogeny to the post-Caledonian basin developments, as well as the post-glacial and neotectonic structural features. At present, the deep-seated structural anomaly underneath the Lofoten Ridge seems to be the major factor controlling the structural trends in the area. The activity along the Nordfolda fault zone could be related to this large-scale structure, although the causes of the stresses that would create the seismic activity are not very clear, as there are several possible stress-generating mechanisms involved, such as post-glacial uplift of the land masses, the 'ridge-push' effect from Mohn's Ridge, and vertical stresses generated by the sediment loading in the adjacent basins.  相似文献   
182.
Abstract— The effect of shallow marine water (?30–100 m deep) in the late excavation and early modification stages of a marine‐target crater 5 km in diameter, as exemplified by the Late Cretaceous Wetumpka impact structure in Alabama, USA, is manifest in the early collapse of a weak part of the rim. Excavation flow and connate marine water are interpreted to be factors in this collapse. This partial rim collapse catastrophically emplaced an upper‐structure‐filling unit of broken and redistributed sedimentary target formations, which presently mantles the deeper fallback breccia deposits within the structure. Furthermore, rim collapse flow facilitated the formation of a structurally modified, extrastructure terrain, which is located outside and adjacent to the collapsed rim segment. This extrastructure terrain appears to be the product of extensive slumping of poorly consolidated target sedimentary formations.  相似文献   
183.
Alluvial fans serve as useful archives that record the history of depositional and erosional processes in mountainous regions and thus can reveal the environmental controls that influenced their development. Economically, they play an important role as groundwater reservoirs as well as host rocks for hydrocarbons in deeply buried systems. The interpretation of these archives and the evaluation of their reservoir architecture, however, are problematic because marked heterogeneity in the distribution of sedimentary facies makes correlation difficult. This problem is compounded because the accumulated sedimentary deposits of modern unconsolidated fan systems tend to be poorly exposed and few such systems have been the focus of investigation using high‐resolution subsurface analytical techniques. To overcome this limitation of standard outcrop–analogue studies, a geophysical survey of an alpine alluvial fan was performed using ground‐penetrating radar to devise a scaled three‐dimensional subsurface model. Radar facies were classified and calibrated to lithofacies within a fan system that provided outcropping walls and these were used to derive a three‐dimensional model of the sedimentary architecture and identify evolutionary fan stages. The Illgraben fan in the Swiss Alps was selected as a case study and a network of ca 60 km sections of ground‐penetrating radar was surveyed. Seven radar facies types could be distinguished, which were grouped into debris‐flow deposits and stream‐flow deposits. Assemblages of these radar facies types show three depositional units, which are separated by continuous, fan‐wide reflectors; they were interpreted as palaeo‐surfaces corresponding to episodes of sediment starvation that affected the entire fan. An overall upward decline in the proportion of debris‐flow deposits from ca 50% to 15% and a corresponding increase in stream‐flow deposits were identified. The uppermost depositional unit is bounded at its base by a significant incision surface up to 700 m wide, which was subsequently filled up mostly by stream‐flow deposits. The pronounced palaeo‐surfaces and depositional trends suggest that allocyclic controls governed the evolution of the Illgraben fan, making this fan a valuable archive from which to reconstruct past sediment fluxes and environmental change in the Alps. The results of the integrated outcrop–geophysical approach encourage similar future studies on fans to retrieve their depositional history as well as their potential reservoir properties.  相似文献   
184.
This paper focuses on the chemical and isotopic features of dissolved gases (CH4 and CO2) from four meromictic lakes hosted in volcanic systems of Central–Southern Italy: Lake Albano (Alban Hills), Lake Averno (Phlegrean Fields), and Monticchio Grande and Piccolo lakes (Mt. Vulture). Deep waters in these lakes are characterized by the presence of a significant reservoir of extra-atmospheric dissolved gases mainly consisting of CH4 and CO2. The δ13C-CH4 and δD-CH4 values of dissolved gas samples from the maximum depths of the investigated lakes (from ?66.8 to ?55.6?‰ V-PDB and from ?279 to ?195?‰ V-SMOW, respectively) suggest that CH4 is mainly produced by microbial activity. The δ13C-CO2 values of Lake Grande, Lake Piccolo, and Lake Albano (ranging from ?5.8 to ?0.4?‰ V-PDB) indicate a significant CO2 contribution from sublacustrine vents originating from (1) mantle degassing and (2) thermometamorphic reactions involving limestone, i.e., the same CO2 source feeding the regional thermal and cold CO2-rich fluid emissions. In contrast, the relatively low δ13C-CO2 values (from ?13.4 to ?8.2?‰ V-PDB) of Lake Averno indicate a prevalent organic CO2. Chemical and isotopic compositions of dissolved CO2 and CH4 at different depths are mainly depending on (1) CO2 inputs from external sources (hydrothermal and/or anthropogenic); (2) CO2–CH4 isotopic exchange; and (3) methanogenic and methanotrophic activity. In the epilimnion, vertical water mixing, free oxygen availability, and photosynthesis cause the dramatic decrease of both CO2 and CH4 concentrations. In the hypolimnion, where the δ13C-CO2 values progressively increase with depth and the δ13C-CH4 values show an opposite trend, biogenic CO2 production from CH4 using different electron donor species, such as sulfate, tend to counteract the methanogenesis process whose efficiency achieves its climax at the water–bottom sediment interface. Theoretical values, calculated on the basis of δ13C-CO2 values, and measured δ13CTDIC values are not consistent, indicating that CO2 and the main carbon-bearing ion species (HCO3 ?) are not in isotopic equilibrium, likely due to the fast kinetics of biochemical processes involving both CO2 and CH4. This study demonstrates that the vertical patterns of the CO2/CH4 ratio and of δ13C-CO2 and δ13C-CH4 are to be regarded as promising tools to detect perturbations, related to different causes, such as changes in the CO2 input from sublacustrine springs, that may affect aerobic and anaerobic layers of meromictic volcanic lakes.  相似文献   
185.
Nitrate (NO3 ?) reduction processes are important for depleting the NO3 ? load from agricultural source areas before the discharge water reaches surface waters or groundwater aquifers. In this study, we experimentally demonstrate the co-occurrence of microbial iron sulfide oxidation by NO3 ? (MISON) and other NO3 ?-depleting processes in a range of contrasting sediment types: sandy groundwater aquifer, non-managed minerotrophic freshwater peat and two brackish muddy sediments. Approximately 1/3 of the net NO3 ? reduction was caused by MISON in three of the four environments despite the presence of organic carbon in the sediment. An apparent salinity limitation to MISON was observed in the most brackish environment. Addition of high surface area synthetically precipitated iron sulfide (FeS x ) to the aquifer sediment with the lowest natural FeS x reactivity increased both the relative fraction of NO3 ? reduction linked to MISON from approximately 30–100 % and the absolute rates by a factor of 17, showing that the potential for MISON-related NO3 ? reduction is environmentally significant and rate limited by the availability of reactive FeS x .  相似文献   
186.
This paper evaluates the remediation potential of a salinized coastal aquifer by utilizing a scenario simulation. Therefore, the numerical model OpenGeoSys is first validated against analytical and experimental data to represent transient groundwater level development and variable density saline intrusion. Afterwards, a regional scale model with a three-dimensional, heterogeneous hydrogeology is calibrated for a transient state and used to simulate a best-case scenario. Water balances are evaluated in both the transient calibration and scenario run. Visualization techniques help to assess the complex model output providing valuable insight in the occurring density-driven flow processes. Furthermore, modeling and visualization results give information on the time scale for remediation activities and, due to limitations in data quality and quantity reveal potential for model improvement.  相似文献   
187.
Tourmalinization associated with peraluminous granitic intrusions in metapelitic host-rocks has been widely recorded in the Iberian Peninsula, given the importance of tourmaline as a tracer of granite magma evolution and potential indicator of Sn-W mineralizations. In the Penamacor-Monsanto granite pluton (Central Eastern Portugal, Central Iberian Zone), tourmaline occurs: (1) as accessory phase in two-mica granitic rocks, muscovite-granites and aplites, (2) in quartz (±mica)-tourmaline rocks (tourmalinites) in several exocontact locations, and (3) as a rare detrital phase in contact zone hornfels and metapelitic host-rocks. Electron microprobe and stable isotope (δ18O, δD, δ11B) data provide clear distinctions between tourmaline populations from these different settings: (a) schorl–oxyschorl tourmalines from granitic rocks have variable foititic component (X□ = 17–57 %) and Mg/(Mg + Fe) ratios (0.19–0.50 in two-mica granitic rocks, and 0.05–0.19 in the more differentiated muscovite-granite and aplites); granitic tourmalines have constant δ18O values (12.1 ± 0.1 ‰), with wider-ranging δD (?78.2 ± 4.7 ‰) and δ11B (?10.7 to ?9.0 ‰) values; (b) vein/breccia oxyschorl [Mg/(Mg + Fe) = 0.31–0.44] results from late, B- and Fe-enriched magma-derived fluids and is characterized by δ18O = 12.4 ‰, δD = ?29.5 ‰, and δ11B = ?9.3 ‰, while replacement tourmalines have more dravitic compositions [Mg/(Mg + Fe) = 0.26–0.64], close to that of detrital tourmaline in the surrounding metapelitic rocks, and yield relatively constant δ18O values (13.1–13.3 ‰), though wider-ranging δD (?58.5 to ?36.5 ‰) and δ11B (?10.2 to ?8.8 ‰) values; and (c) detrital tourmaline in contact rocks and regional host metasediments is mainly dravite [Mg/(Mg + Fe) = 0.35–0.78] and oxydravite [Mg/(Mg + Fe) = 0.51–0.58], respectively. Boron contents of the granitic rocks are low (<650 ppm) compared to the minimum B contents normally required for tourmaline saturation in granitic melts, implying loss of B and other volatiles to the surrounding host-rocks during the late-magmatic stages. This process was responsible for tourmalinization at the exocontact of the Penamacor-Monsanto pluton, either as direct tourmaline precipitation in cavities and fractures crossing the pluton margin (vein/breccia tourmalinites), or as replacement of mafic minerals (chlorite or biotite) in the host-rocks (replacement tourmalinites) along the exocontact of the granite. Thermometry based on 18O equilibrium fractionation between tourmaline and fluid indicates that a late, B-enriched magmatic aqueous fluid (av. δ18O ~12.1 ‰, at ~600 °C) precipitated the vein/breccia tourmaline (δ18O ~12.4 ‰) at ~500–550 °C, and later interacted with the cooler surrounding host-rocks to produce tourmaline at lower temperatures (400–450 °C), and an average δ18O ~13.2 ‰, closer to the values for the host-rock. Although B-metasomatism associated with some granitic plutons in the Iberian Peninsula seems to be relatively confined in space, extending integrated studies such as this to a larger number of granitic plutons may afford us a better understanding of Variscan magmatism and related mineralizations.  相似文献   
188.
This paper presents simulation results related to coupled thermal–hydraulic–mechanical (THM) processes in engineered barrier systems (EBS) and clay host rock, in one case considering a possible link to geochemistry. This study is part of the US DOE Office of Nuclear Energy’s used fuel disposition campaign, to investigate current modeling capabilities and to identify issues and knowledge gaps associated with coupled THMC processes and EBS–rock interactions associated with repositories hosted in clay rock. In this study, we simulated a generic repository case assuming an EBS design with waste emplacement in horizontal tunnels that are back-filled with bentonite-based swelling clay as a protective buffer and heat load, derived for one type of US reactor spent fuel. We adopted the Barcelona basic model (BBM) for modeling of the geomechanical behavior of the bentonite, using properties corresponding to the FEBEX bentonite, and we used clay host rock properties derived from the Opalinus clay at Mont Terri, Switzerland. We present results related to EBS host–rock interactions and geomechanical performance in general, as well as studies related to peak temperature, buffer resaturation and thermally induced pressurization of host rock pore water, and swelling pressure change owing to variation of chemical composition in the EBS. Our initial THM modeling results show strong THM-driven interactions between the bentonite buffer and the low-permeability host rock. The resaturation of the buffer is delayed as a result of the low rock permeability, and the fluid pressure in the host rock is strongly coupled with the temperature changes, which under certain circumstances could result in a significant increase in pore pressure. Moreover, using the BBM, the bentonite buffer was found to have a rather complex geomechanical behavior that eventually leads to a slightly nonuniform density distribution. Nevertheless, the simulation shows that the swelling of the buffer is functioning to provide an adequate increase in confining stress on the tunnel wall, leading to a stabilization of any failure that may occur during the tunnel excavation. Finally, we describe the application of a possible approach for linking THM processes with chemistry, focusing on the evolution of primary and secondary swelling, in which the secondary swelling is caused by changes in ionic concentration, which in turn is evaluated using a transport simulation model.  相似文献   
189.
Geografisk Tidsskrift, Danish Journal of Geography 105(2):15–22, 2005

The change of Cu and Zn concentrations in Danish agricultural soils was studied in areas with intensive pig production. Cu and Zn are found in pig manure as the metals are added to pig feed as growth promoters. The changes in concentrations of total and 0.02 MEDTA extractable Cu and Zn in soils from 1986 to 1998 were determined from samples taken at two depths (0–25 cm and 25–50 cm) from 73 sites. Pig manure and mineral fertilizer was added to 60 sites whereas fertilizer only was used on 13 sites. During the survey period soil Cu concentrations increased in both depths but mostly in the sites where pig manure was added. Furthermore, the results indicated that some plant-available Cu and Zn were transported from the topsoil to the subsoil. No significant change in soil Zn concentration was found although a slight reduction was observed. Comparing soil metal concentrations observed in 1998 to the total pig manure application in a 12-year period, it was observed that application of manure caused an accumulation of Cu and of Zn in the upper 50 cm soil. The accumulation rates correspond to the Cu and Zn concentrations in the pig manure.  相似文献   
190.
The objective of this paper was to investigate the THM-coupled responses of the storage formation and caprock, induced by gas production, CO2-EGR (enhanced gas recovery), and CO2-storage. A generic 3D planer model (20,000?×?3,000?×?100?m, consisting of 1,200?m overburden, 100?m caprock, 200?m gas reservoir, and 1,500?m base rock) is adopted for the simulation process using the integrated code TOUGH2/EOS7C-FLAC3D and the multi-purpose simulator OpenGeoSys. Both simulators agree that the CO2-EGR phase under a balanced injection rate (31,500?tons/year) will cause almost no change in the reservoir pressure. The gas recovery rate increases 1.4?% in the 5-year CO2-EGR phase, and a better EGR effect could be achieved by increasing the distance between injection and production wells (e.g., 5.83?% for 5?km distance, instead of 1.2?km in this study). Under the considered conditions there is no evidence of plastic deformation and both reservoir and caprock behave elastically at all operation stages. The stress path could be predicted analytically and the results show that the isotropic and extensional stress regime will switch to the compressional stress regime, when the pore pressure rises to a specific level. Both simulators agree regarding modification of the reservoir stress state. With further CO2-injection tension failure in reservoir could occur, but shear failure will never happen under these conditions. Using TOUGH-FLAC, a scenario case is also analyzed with the assumption that the reservoir is naturally fractured. The specific analysis shows that the maximal storage pressure is 13.6?MPa which is determined by the penetration criterion of the caprock.  相似文献   
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