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221.
We used numerical simulations to investigate the general relationship between urban morphology and the intensity of wind gusts in built-up areas at the pedestrian level. The simulated urban boundary layer developed over a 19.2 km (length) \(\times \) 4.8 km (width) \(\times \) 1.0 km (height) simulation domain, with 2-m resolution in all directions, to explicitly resolve the detailed shapes of buildings and the flow at the pedestrian level. This complex computation was accomplished using the lattice Boltzmann method and by implementing a large-eddy simulation model. To generalize the results, a new parameter that expresses the intensity of gusts (the gust index, \({\tilde{U}}_{ max})\) was defined as the local maximum wind speed divided by the freestream velocity. In addition, this parameter was decomposed into the mean wind-speed ratio, \({\tilde{U}} \) and turbulent gust ratio, \({\tilde{U}}^{{\prime }}\) to evaluate the qualities of gusts. These parameters were useful for quantitatively comparing the gust intensities within urban canopies at different locations or even among different experiments. In addition, the entire horizontal domain was subdivided into homogeneous square patches, in which both the simulated gust parameters and the morphological characteristics of building geometries were averaged. This procedure masked the detailed structure of individual buildings but retained the bulk characteristics of the urban morphology. At the pedestrian level, the gust index decreased with increasing building cover. Compared to \({\tilde{U}} \), the quantity \({\tilde{U}}^{{\prime }}\) notably contributed to the index throughout the range of plan area index \((\lambda _p)\) values. The dependences of all normalized wind-speed ratios transiently changed at \(\lambda _p =~0.28\). In cases where \(\lambda _p < 0.28, {\tilde{U}} \) decreased with increasing \(\lambda _p \), although \({\tilde{U}}^{{\prime }}\) was almost constant. In cases where \(\lambda _p > 0.28, {\tilde{U}}\) was almost constant and \({\tilde{U}}^{{\prime }}\) decreased with increasing \(\lambda _p \). This was explained by the change in flow regimes within the building canyon. At a higher elevation above the canopy layer, \(\lambda _p \) becomes less relevant to normalized wind-speed ratios, and instead the aerodynamic roughness length became important.  相似文献   
222.
Managing authorities in Scandinavia arrange public information meetings when members of the public express fear because wolves or brown bears approach human settlements. This study aimed to increase the understanding of the potential effect of information meetings on self-reported fear of wolves and brown bears. In total, 198 participants completed questionnaires before and after the information meetings. Nine follow-up interviews were held 1 year later. The quantitative analyses revealed that participants who found the information credible reported a significant increase in social trust and a decrease in vulnerability and fear. The qualitative analyses pointed to the importance of information content and meta-communication, for example, nonverbal cues. It is proposed that, among participants who find the information credible, information meetings may change the appraisal of wolves and brown bears, and therefore they might prove useful as an intervention to address fear of these animals.  相似文献   
223.
Wismar Bay is a shallow coastal embayment in the Western Baltic Sea which is polluted by various industries. Macrobenthos data collected between 1986–91 are examined for qualitative and quantitative changes attributable to oxygen depletion and the subsequent time needed for recovery. Regular oceanographic surveys since 1976 indicate one episode of oxygen deficiency, caused by deep-water intrusion into the study area. However, principal component analyses show that the benthic community alternated between periods of relative stability and sudden change at both of the deeper sites examined. Deep-water intrusions from outside the bay are documented twice followed by sudden changes in the benthic community, but similar events may also have occurred in other years. The benthos showed little resilience when impacted, and the changes in the benthic community during July–August are proposed to monitor the future influence of the deep-water intrusions.  相似文献   
224.
Cylindrical sediment traps were deployed at various depths in the anoxic water of Framvaren for two periods of one year (1981–1982 and 1983–1984). The traps were emptied three times during 1981–1982 and five times during 1983–1984. The vertical fluxes of total suspended material, organic carbon and nitrogen were calculated on a daily and annual basis. The average annual sediment flux 20 m above the bottom was approximately 60 g m−2 y−1 and the flux of organic carbon was 20 g m−2 y−1. On the basis of an average C/N ratio of 8 and a constant carbon flux below a depth of 20 m, it is concluded that little mineralization of the organic matter takes place in the anoxic water column. Assuming a primary production of the order to 50–100 g m−2 y−1, 22–24% of that reaches the anoxic water masses. Further breakdown of organic matter takes place in the surface sediments.  相似文献   
225.
Na–H3O jarosite was synthesized hydrothermally at 413 K for 8 days and investigated using single-crystal X-ray diffraction (XRD) and electron microprobe analysis (EMPA). The chemical composition of the studied crystal is [Na0.57(3) (H3O)0.36 (H2O)0.07]A Fe2.93(3) (SO4)2 (OH)5.70 (H2O)0.30, and Fe deficiency was confirmed by both EMPA and XRD analysis. The single-crystal XRD data were collected at 298 and 102 K, and crystal structures were refined in space group \( R\overline{3}m\). The room-temperature data match structural trends of the jarosite group, which vary linearly with the c axis. The low-temperature structure at 102 K shows an anisotropic decrease in the unit cell parameters, with c and a decreasing by 0.45 and 0.03 %, respectively. Structural changes are mainly confined to the A site environment. Only minor changes occur in FeO6 and SO4 polyhedra. The structure responds upon cooling by increasing bond length distortion and by decreasing quadratic elongation of the large AO12 polyhedra. The structural parameters at low temperature follow very similar patterns to structural changes that correspond to compositional variation in the jarosite group, which is characterised by the flexibility of AO12 polyhedra and rigidity of Fe(OH)4O2–SO4 layers. The most flexible areas in the jarosite structure are localized at AO12 edges that are not shared with neighbouring FeO6 octahedra. Importantly, for the application of XRD in planetary settings, the temperature-related changes in jarosite can mimic compositional change.  相似文献   
226.
Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12?xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12?xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I $ \ifmmode\expandafter\bar\else\expandafter\=\fi{4} Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12−xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12−xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I 3 m). The refinement results also confirm that M2 is a split (24g), flat-pyramidal site situated statistically on both sides of the S1−S1–S2 triangle. In tetrahedrite, this split is about 0.6 ?, in tennantite about 0.7 ?. Trends in bond lengths and magnitude of the M2 split were evaluated by means of linear regression with Fe concentration as the independent variable.  相似文献   
227.
A regional isotopic study of Pb and S in hydrothermal galenas and U–Pb and S in potential source rocks was carried out for part of Moravia, Czech Republic. Two major generations of veins, (syn-) Variscan and post-Variscan, are defined based on the Pb-isotope system together with structural constraints (local structures and regional trends). The Pb-isotopic compositions of galena plot in two distinct populations with outliers in 206Pb/204Pb–207Pb/204Pb space. Galena from veins hosted in greywackes provides a cluster with the lowest Pb–Pb ratios: 206Pb/204Pb = 18.15–18.27, 207Pb/204Pb = 15.59–15.61, 208Pb/204Pb = 38.11–38.23. Those hosted in both limestones and greywackes provide the second cluster: 206Pb/204Pb = 18.37–18.44, 207Pb/204Pb = 15.60–15.63, 208Pb/204Pb = 38.14–38.32. These clusters suggest model Pb ages as Early Carboniferous and Triassic–Jurassic, the latter associated with MVT-like deposits. Two samples from veins hosted in Proterozoic rocks lie outside the two clusters: in metagranitoid (206Pb/204Pb = 18.55, 207Pb/204Pb = 15.64, 208Pb/204Pb = 38.29) and in orthogneiss (206Pb/204Pb = 18.79, 207Pb/204Pb = 15.73, 208Pb/204Pb = 38.54). The results from these two samples suggest an interaction of mineralizing fluids with the radiogenic Pb-rich source (basement?). The values of δ34S suggest the Paleozoic host rocks (mostly ?6.7 to +5.2‰ CDT) as the source of S for hydrothermal sulfides (mostly ?4.8 to +2.5‰ CDT). U–Pb data and Pb isotope evolutionary curves indicate that Late Devonian and Early Carboniferous sediments, especially siliciclastics, are the general dominant contributor of Pb for galena mineralization developed in sedimentary rocks. Plumbotectonic mixing occurred, it is deduced, only between the lower and the upper crust (the latter involving Proterozoic basement containing heterogeneous radiogenic Pb), without any significant input from the mantle. It is concluded that in the Moravo–Silesian and Rhenohercynian zones (including proximal districts in Poland) lead and sulfur have been mobilized from the adjacent rocks during multiple hydrothermal events in processes that are remarkably comparable in timing, geochemistry of fluids and nature of sources.  相似文献   
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