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271.
Geologic carbon sequestration (GCS) is being considered as a climate change mitigation option in many future energy scenarios. Mathematical modeling is routinely used to predict subsurface CO2 and resident brine migration for the design of injection operations, to demonstrate the permanence of CO2 storage, and to show that other subsurface resources will not be degraded. Many processes impact the migration of CO2 and brine, including multiphase flow dynamics, geochemistry, and geomechanics, along with the spatial distribution of parameters such as porosity and permeability. In this article, we review a set of multiphase modeling approaches with different levels of conceptual complexity that have been used to model GCS. Model complexity ranges from coupled multiprocess models to simplified vertical equilibrium (VE) models and macroscopic invasion percolation models. The goal of this article is to give a framework of conceptual model complexity, and to show the types of modeling approaches that have been used to address specific GCS questions. Application of the modeling approaches is shown using five ongoing or proposed CO2 injection sites. For the selected sites, the majority of GCS models follow a simplified multiphase approach, especially for questions related to injection and local‐scale heterogeneity. Coupled multiprocess models are only applied in one case where geomechanics have a strong impact on the flow. Owing to their computational efficiency, VE models tend to be applied at large scales. A macroscopic invasion percolation approach was used to predict the CO2 migration at one site to examine details of CO2 migration under the caprock.  相似文献   
272.
Sediment transport is known to have a significant impact on hydropower infrastructures and changes in sediment transport rates are important for sediment management measures and hydroelectricity production. In this study, we present how climate change may affect bedload transport in 66 high alpine catchments used by hydropower companies in the Valais, Switzerland. Future sediment yield is estimated with a runoff‐based sediment transport model for the two future 30 year time periods 2021–2050 and 2070–2099. The analysis is integrated into a modelling chain in which error‐corrected and downscaled climate scenarios generated in the framework of the ENSEMBLES project are coupled to the hydrological model PREVAH, glacier retreat and bedload transport. To calibrate the sediment transport model, we used the observed sediment volumes in water intakes and reservoirs if such data were available. The results obtained show on average a decrease of sediment yield due to the reduced runoff generation during summer, especially for the scenario period 2070–2099. A shift of the seasonal sediment transport regime with a current maximum during July and August to earlier months in the year is predicted. Projections of future sediment yield rely on the accuracy of the individual modeling chain elements. The different sources of uncertainty are discussed qualitatively. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
273.
In laboratory experiments we determine the mass gain and loss in central collisions between centimetre- to decimetre-size SiO2 dust targets and submillimetre- to centimetre-size SiO2 dust projectiles of varying mass, size, shape and at different collision velocities up to ∼56.5 m s−1. Dust projectiles much larger than 1 mm lead to a small amount of erosion of the target but decimetre targets do not break up. Collisions produce ejecta, which are smaller than the incoming projectile. Projectiles smaller than 1 mm are accreted by a target even at the highest collision velocities. This implies that net accretion of decimetre and larger bodies is possible. Independent of the original size of a considered projectile, after several collisions, all fragments will be of submillimetre size which might then be (re)accreted in the next collision with a larger body. The experimental data suggest that collisional growth through fragmentation and reaccretion is a viable mechanism to form planetesimals.  相似文献   
274.
Energy balance closure for the LITFASS-2003 experiment   总被引:2,自引:1,他引:1  
In the first part, this paper synthesises the main results from a series of previous studies on the closure of the local energy balance at low-vegetation sites during the LITFASS-2003 experiment. A residual of up to 25% of the available energy has been found which cannot be fully explained either by the measurement uncertainty of the single components of the surface energy balance or by the length of the flux-averaging period. In the second part, secondary circulations due to heterogeneities in the surface characteristics (roughness, thermal and moisture properties) are discussed as a possible cause for the observed energy balance non-closure. This hypothesis seems to be supported from the fluxes derived from area-averaging measurement techniques (scintillometers, aircraft).  相似文献   
275.
276.
Realtime satellite clock corrections are usually estimated using undifferenced phase and range observations from a global network. Because a large number of ambiguity parameters must be estimated, the computation is time-consuming. Consequently, only a sparse global network of limited number of stations is processed by most IGS Realtime Analysis Centers with an update rate of 5 s. In addition, it is very desirable to build the capability to simultaneously estimate clock corrections for multi-GNSS constellations. Although the estimation can be sped up by epoch-differenced observations that eliminate ambiguities, the derived clocks can contain a satellite-specific bias that diminishes the contribution of range observations. We introduce a computationally efficient approach for realtime clock estimation. Both the epoch-differenced phase and undifferenced range observations are used together to estimate the epoch-differenced satellite clocks and the initial clock bias for each satellite and receiver. The biased clock corrections accumulated from the estimated epoch-differenced clocks are then aligned with the estimated clock biases and provided as the final clock corrections to users. The algorithm is incorporated into the EPOS-RT software developed at GFZ (GeoForschungsZentrum) and experimentally validated with the IGS global network. The comparison with the GFZ rapid products shows that the accuracy of the clock estimation with the new approach is comparable with that of the undifferenced approach, whereas the computation time is reduced to one-tenth. As a result, estimation of high-rate satellite clocks from a large reference network and tracking satellites of multi-GNSS constellations becomes achievable.  相似文献   
277.
Detailed geological mapping, core logging and petrographic analysis are supplemented with geochemical data to evaluate the petrogenesis of the Upper Group (UG1, UG2) stratiform chromitite seams in the Dwars River area, Bushveld Complex. Seven important and widespread features of UG1 and UG2 chromitite are addressed: (1) chromitite seams are dissociated from specific silicate successions and enclosed in Cr-rich silicates with a common genetic origin, (2) chromitite seams cut structures and textures in host silicates, have vein-like structures and host xenoliths, (3) chromitite seams are braided, (4) chromite grain distributions suggest flow segregation, (5) silicates in chromitite seams have modal proportions, forms and compositions different from those in binding silicate rocks, (6) PGE distributions in UG2 chromitite suggest flow segregation, and (7) chromitite seams are bound by coarse-grained silicates possibly formed through contact heating and/or de-volatization. These features are integrated into a model whereby UG chromitite seams developed from the intrusion of chromite crystal slurries. This model proposes that chromite grains first accumulated within structural traps of the Bushveld conduits, and that these accumulations were then re-mobilized with silicate melt (± sulfides and/or fluids?) to spread laterally as chromite crystal slurries within the layered ultramafic-mafic cumulates of the Bushveld Complex.  相似文献   
278.
More than 99% of water use in Denmark is based on groundwater. Denmark has had a comprehensive national groundwater-monitoring programme since 1988 based on 74 well catchment areas and six small agricultural catchments with more than 1,500 screens at different depths for regular, mostly annual, water quality sampling. In addition, water samples from 10,000 abstraction wells are analysed every 3–5 years. The water is analysed for main components, inorganic trace elements, organic micro pollutants, and pesticides and their metabolites. A unique feature is the 20-year time-series data of inorganic pollutants. Groundwater modelling supports traditional monitoring to improve the conceptual geological understanding and to assess the quantitative status and the interaction between groundwater and surface water. The programme has been continuously adjusted to incorporate new knowledge from research programmes and meet new policy demands, currently the European Union Water Framework Directive, particularly with respect to an increased focus on quantitative aspects and on the groundwater/surface water interaction. The strengths and weaknesses of the Danish programme are assessed and compared with other national groundwater-monitoring programmes. Issues discussed include: strategic considerations for monitoring design, the link between research and monitoring, and adoption of responses to climate changes.  相似文献   
279.
Chromium-reducible sulfur (CRS) distillations are intended to recover only reduced inorganic sulfur compounds (RIS) including elemental sulfur. However, the quantitative recovery of elemental sulfur is not ensured in common CRS-distillations. The new method presented here was designed to remedy this deficiency. An increase in ethanol concentration assured the quantitative recovery of elemental sulfur in various forms and, in addition, all other RIS-compounds were quantitatively recovered. Furthermore, the selectivity of the procedure was improved by an additional filtration step to eliminate zinc particles from the Cr(II)-solution. Thus, the recovery of sulfates and organic sulfur compounds was significantly decreased by a factor of up to 35, depending on the compound analysed. Exhaustive testing with a variety of pure phases, rock and soil samples demonstrated the precision and accuracy of the new method. The new protocol eliminated the constraints of previous procedures. The improved distillation efficiency for elemental sulfur ensured the quantitative recovery of all RIS-compounds in a single-step distillation.  相似文献   
280.
Mountains are an excellent system for evaluating ecological and biogeographical patterns. The obvious variations of the environmental factors along the altitude create different zones with adapted plant assemblages. However, few studies make use of plant functional type(PFT) for describing the variation of vegetation along altitudinal gradients. A PFT is a group of taxa with similar traits which respond similarly to the environmental gradients. In this study, we used PFTs as indicators describing five vegetation zones in the western Alborz Mt, Iran from 2000 – 4500 m. The plant trait data presented here covers six plant traits including growth form, stemleaf ratio, spinescence, hairiness, leaf consistency and plant height of 297 species. We considered altitude and soil factors to test the importance of environmental variables. We applied a multivariate analysis of three table ordination, i.e. environmental, species, and traits data to identify the PFTs. We further applied fourth-corner statistic to quantify trait-environment relationships. A constrained hierarchical clustering was used to detect five altitudinal zones and two zones of low and high nitrogen concentration. With regard to altitude wediscuss the distribution of species, traits and PFTs. Growth form, plant height and stem-leaf ratio were significantly related to altitude and nitrogen. We identified 19 PFTs from which 18 were significantly associated to one or more altitudinal zones. While the lower altitudinal zones contain a variety of PFTs higher altitudes contain less PFTs with the highest altitude containing only one single PFT, tiny rosette plants with soft mesomorphic leaves. We identified grazing and climatic harshness as well as rockiness as the most important drivers of the distribution of plant functional traits and types across the studied gradient.  相似文献   
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