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271.
The Francevillian Group in Gabonese Republic was recently established as a typical sedimentary sequence for the Paleoproterozoic.However,its age is rather poorly constrained,mainly based on Rb-Sr and Nd-Sm datings.This study reports new zircon data obtained from Chaillu massif and N'goutou complex,which constrain the protolith age of the basement orthogneisses and the igneous age of an intrusive granite,respectively.Most zircons from the orthogneisses are blue and exhibit oscillatory zoning in cathode-luminescence images.Zircons with lower common lead abundances tend to be distributed close to the concordia curve.Two age clusters around 2860 Ma and 2910 Ma are found in zircons plotted on the concordia curve.Based on the Th/U ratios of zircons,these ages correspond to the protolith ages of the orthogneisses,and the zircons are not metamorphic in origin.Syenites and granites were collected from the N'goutou complex that intrudes into the FA and FB units of the Francevillian Group.The granitoids exhibit chemical composition of A-type granite affinity.Half of zircons separated from the granite are non-luminous,and the remaining half exhibit obscure internal textures under cathode-luminescence observation.All zircon grains contain significant amounts of common lead;the lead isotopic variability is probably attributed to the mixing of two components in the zircons.The zircon radiogenic ~(207)Pb/~(206)Pb ratio is 0.13707 ± 0.0010.corresponding to a ~(207)Pb/~(206)Pb age of 2191 ± 13 Ma.This constrains the minimum depositional age of the FA and FB units.Furthermore,the FB unit consists of manganese-rich carbonate rocks and organic carbon-rich black shales with macroscopic fossils.Based on our age constraints,these organisms appeared in the study area just after the last Paleoproterozoic Snowball Earth event,in concert with global scale oxidation event encompassing the Snowball Earth.  相似文献   
272.
From 1999 to 2005, studies carried out in the frame of regional and national French programs aimed to determine whether the Phaeocystisglobosa bloom affected the intertidal benthic communities of the French coast of the eastern English Channel in terms of composition and/or functioning. Study sites were chosen to cover most of the typical shore types encountered on this coast (a rocky shore, an exposed sandy beach and a small estuary). Both the presence of active Phaeocystis cells and their degradation product (foam) did have a significant impact on the studied shores. The primary production and growth rates of the kelp Saccharina latissima decreased during the bloom because of a shortage of light and nutrient for the macroalgae. On sandy sediments, the benthic metabolism (community respiration and community primary production), as well as the nitrification rate, were enhanced during foam deposits, in relation with the presence of bacteria and active pelagic cells within the decaying colonies. In estuarine sediments, the most impressive impact was the formation of a crust at the sediment surface due to drying foam. This led to anoxic conditions in the surface sediment and resulted in a high mortality among the benthic community. Some organisms also tended to migrate upward and were then directly accessible to the higher trophic level represented by birds. Phaeocystis then created a shortcut in the estuarine trophic network. Most of these modifications lasted shortly and all the systems considered came back to their regular properties and activities a few weeks after the end of the bloom, except for the most impacted estuarine area.  相似文献   
273.
We investigated initiation and propagation of compaction bands (CB) in six wet and four dry Bentheim sandstone samples deformed in axial compression tests with strain rates ranging from 3.2 × 10?8 s?1 to 3.2 × 10?4 s?1. Circumferential notches with 0.8-mm width and 5-mm depth served to initiate CB at mid-sample length. Wet samples were saturated with distilled water and deformed at 195 MPa confining pressure and 10 MPa pore pressure. Dry samples were deformed at 185 MPa confining pressure. Twelve P-wave sensors, eight S-wave sensors and two pairs of orthogonally oriented strain-gages were glued to the sample surface to monitor acoustic emission (AE), velocities and local strain during the loading process. Nucleation of compaction bands is indicated by AE clusters close to the notch tips. With progressive loading, AE activity increased and AE hypocenters indicated propagation of a single CB normal to the sample axis. CB propagation from the sample periphery towards the centre was monitored. Microstructural analysis of deformed samples shows excellent agreement between location of AE clusters and CBs. In both dry and wet samples the lateral propagation of CBs was about 100 times faster than axial shortening rates. At the slowest displacement rate, AE activity during band propagation was reduced and CB nucleation in wet samples occurred at 20% lower stresses. This may indicate an increasing contribution of stress corrosion processes to the formation of the compaction bands. In dry and wet samples inelastic compaction energy per area ranged between 16 and 80 kJ m?2. This is in good agreement with previous estimates from laboratory and field studies.  相似文献   
274.
It is likely that the structure of a volcanic edifice can be significantly modified by deformation caused by large, shallow intrusions. Such deformation may interact with that caused by volcano loading. We explore such intrusion-related and loading-related deformation with field evidence and analogue models. To do this we have chosen the eroded Palaeogene Mull volcano (Scotland) that had a major edifice, has well exposed intrusions and significant deformation. There are thin Mesozoic sedimentary rocks forming ductile layers below the volcano, but their thickness is insufficient to allow the gravitational spreading of the volcanic edifice, especially when considering that a thick lava pile covers them. Thus intrusive push may have been the driving force for deformation. The Mull activity migrated toward the northwest, forming three successive intrusive complexes (Centres 1, 2 and 3). Our detailed fieldwork reveals that deformation due to these was accommodated on three levels; along thrust planes in lava sequences, along a décollement located in a thin clay-rich sediment succession and in basement schists. A relative chronology has been established between different groups of structures using dyke and sill cross-cutting relationships. Centre 1 is surrounded by a fold and thrust belt leading to radial expansion. In contrast, Centre 2 and 3 are connected to thrusts located to the south and east, bounded by strike-slip faults, leading to expansion to the southeast. The migration of centres and the directed sliding of the edifice may be related to the presence to the southeast of low-resistance Dalradian basement that failed significantly during growth of Centres 2 and 3. To study the observed relationships we have carried out scaled analogue models. Models are made with fine powder intruded by a viscous magma analogue. The models show an intimate relationship between intrusion growth, uplift of the volcano and subsequent flank sliding. The structures produced can be compared with Mull and suggest that the Centre 1 thrust belt probably formed following edifice gravitational sliding as a consequence of the uplift associated with Centre 1 formation. Centre 2 and 3 are responsible for the sector sliding of the edifice flank toward the southeast as the magmatic complex became more asymmetric. The features observed at Mull and in the models are similar to those seen on active volcanoes, such as Etna, providing a structural framework for their deformation and evolution.  相似文献   
275.
Although connectivity is acknowledged as a key factor of a catchment hydrological behaviour, it still misses reference evaluation methodologies. Therefore the objective of the paper is to evaluate different quantitative indicators of hydrological connectivity, using the concepts of structural and functional connectivity commonly used in ecology. The indicators were tested on contrasted numerical fields of micro-topography that present distinct hydrological responses.  相似文献   
276.
Ultra-low-volume (ULV) aerosol applications of insecticides are used to manage high densities of adult mosquitoes. We used two-dimensional probabilistic risk assessment methodologies to evaluate three pyrethroid insecticides (phenothrin, resmethrin, and permethrin), pyrethrins, and two organophosphate insecticides (malathion and naled), applied by truck-mounted ULV sprayer. Piperonyl butoxide, a synergist commonly used in pyrethroid and pyrethrins formulations, was also assessed. The objective of our study was to evaluate probabilistically if a deterministic human-health risk assessment of mosquito insecticides was sufficiently conservative to protect human-health. Toddlers and infants were the highest risk groups while adult males were the lowest risk group assessed in this study. Total acute exposure ranged from 0.00003 to 0.0003 mg/kg day−1 for the chemicals and subgroups assessed examining inhalation, dermal, oral, and hand-to-mouth exposure. We used the risk quotient (RQ) method for our risk assessment, which is calculated by dividing the total potential exposure for each subgroup and chemical by its ingestion toxic endpoint value (RfD). Mean RQs ranged from 0.000004 to 0.034 for all subgroups and chemicals, with none exceeding the RQ level of concern. Naled had the highest RQs of any chemical assessed while PBO had the lowest. Sensitivity analysis demonstrated that the exposure from inhalation and deposition contributed the largest variance to the model output. Results support the findings of previous studies that the risks from adult mosquito management are most likely negligible, and that the human-health deterministic risk assessment is most likely sufficiently conservative.  相似文献   
277.
We present a method for recovering the distribution functions of edge-on thin axisymmetric discs directly from their observable kinematic properties. The most generally observable properties of such a stellar system are the line-of-sight velocity distributions of the stars at different projected radii along the galaxy. If the gravitational potential is known, then the general two-integral distribution function can be reconstructed using the shapes of the high-velocity tails of these line-of-sight distributions. If the wrong gravitational potential is adopted, then a distribution function can still be constructed using this technique, but the low-velocity parts of the observed velocity distributions will not be reproduced by the derived dynamical model. Thus, the gravitational potential is also tightly constrained by the observed kinematics.  相似文献   
278.
Mathematical Geosciences - In the current era of big data and machine learning, a strong focus exists on prediction and classification. In industrial applications, however, many important questions...  相似文献   
279.
As on Earth, Titan’s atmosphere plays a major role in the cooling of heated surfaces. We have assessed the mechanisms by which Titan’s atmosphere, dominantly N2 at a surface pressure of 1.5 × 105 Pa, cools a warm or heated surface. These heated areas can be caused by impacts generating melt sheets and (possibly) by endogenic processes emplacing cryolavas (a low-temperature liquid that freezes on the surface). We find that for a cooling cryolava flow, lava lake, or impact melt body, heat loss is mainly driven by atmospheric convection. Radiative heat loss, a dominant heat loss mechanism with terrestrial silicate lava flows, plays only a minor role on Titan. Long-term cooling and solidification are dependent on melt sheet or flow thickness, and also local climate, because persistent winds will speed cooling. Relatively rapid cooling caused by winds reduces the detectability of these thermal events by instruments measuring surface thermal emission. Because surface temperature drops by ≈50% within ≈1 day of emplacement, fresh flows or impact melt may be difficult to detect via thermal emission unless an active eruption is directly observed. Cooling of flow or impact melt surfaces are orders of magnitude faster on Titan than on airless moons (e.g., Enceladus or Europa).Although upper surfaces cool fast, the internal cooling and solidification process is relatively slow. Cryolava flow lengths are, therefore, more likely to be volume (effusion) limited, rather than cooling-limited. More detailed modeling awaits constraints on the thermophysical properties of the likely cryomagmas and surface materials.  相似文献   
280.
The Fe(II)-catalysed transformation of synthetic schwertmannite, ferrihydrite, jarosite and lepidocrocite to more stable, crystalline Fe(III) oxyhydroxides is prevented by high, natural concentrations of Si and natural organic matter (NOM). Adsorption isotherms demonstrate that Si adsorbs to the iron minerals investigated and that increasing amounts of adsorbed Si results in a decrease in isotope exchange between aqueous Fe(II) and the Fe(III) mineral. This suggests that the adsorption of Si inhibits the direct adsorption of Fe(II) onto the mineral surface, providing an explanation for the inhibitory effect of Si on the Fe(II)-catalysed transformation of Fe(III) minerals. During the synthesis of lepidocrocite and ferrihydrite, the presence of equimolar concentrations of Si and Fe resulted in the formation of 2-line ferrihydrite containing co-precipitated Si in both cases. Isotope exchange experiments conducted with this freeze-dried Si co-precipitated ferrihydrite species (Si-ferrihydrite) demonstrated that the rate and extent of isotope exchange between aqueous Fe(II) and solid 55Fe(III) was very similar to that of 2-line ferrihydrite formed in the absence of Si and which had not been allowed to dry. In contrast to un-dried ferrihydrite formed in the absence of Si, Si-ferrihydrite did not transform into a more crystalline Fe(III) mineral phase over the 7-day period of investigation. Reductive dissolution studies using ascorbic acid demonstrated that both dried Si-ferrihydrite and un-dried 2-line ferrihydrite were very reactive, suggesting these species may be major contributors to the rapid release of dissolved iron following flooding and the onset of conditions conducive to reductive dissolution in acid sulphate soil environments.  相似文献   
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