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31.
32.
The SrCa ratio and other parameters have been measured in fossil planktonic foraminifera from the Atlantic and Pacific Ocean basins in order to evaluate the SrCa ratio of seawater during the last 75 million years. Results on well-preserved samples indicate that the ratio has increased to its present value by 10–15% during the Cenozoic, and that minima occurred between 55-45 Ma and 10-5 Ma, when the ratio was 15–25% less than at present. The long-term increase may reflect either decreasing deposition of aragonite with a high SrCa ratio in shallow seas, or decreasing seafloor spreading rates and consequently decreasing hydrothermal supply of Ca during the Cenozoic. Other geologic evidence suggests that the Eocene minimum (near 50 Ma) may have resulted from increased aragonite sedimentation, while the Late Miocene minimum (between 10-5 Ma) may have been caused by an increased rate of seawater-basalt exchange when seafloor spreading rates increased on the East Pacific Rise near 10 Ma.  相似文献   
33.
Major Ion Characterization of Coastal Saline Ground Waters   总被引:1,自引:0,他引:1  
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34.
It is well known that terrain may vary markedly over small areas and that statistics used to characterise spatial variation in terrain may be valid only over small areas. In geostatistical terminology, a non-stationary approach may be considered more appropriate than a stationary approach. In many applications, local variation is not accounted for sufficiently. This paper assesses potential benefits in using non-stationary geostatistical approaches for interpolation and for the assessment of uncertainty in predictions with implications for sampling design. Two main non-stationary approaches are employed in this paper dealing with (1) change in the mean and (2) change in the variogram across the region of interest. The relevant approaches are (1) kriging with a trend model (KT) using the variogram of residuals from local drift and (2) locally-adaptive variogram KT, both applied to a sampled photogrammetrically derived digital terrain model (DTM). The fractal dimension estimated locally from the double-log variogram is also mapped to illustrate how spatial variation changes across the data set. It is demonstrated that estimation of the variogram of residuals from local drift is worthwhile in this case for the characterisation of spatial variation. In addition, KT is shown to be useful for the assessment of uncertainty in predictions. This is shown to be true even when the sample grid is dense as is usually the case for remotely-sensed data. In addition, both ordinary kriging (OK) and KT are shown to provide more accurate predictions than inverse distance weighted (IDW) interpolation, used for comparative purposes.  相似文献   
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The site characterization and analysis cone penetrometer system (SCAPS), equipped with realtime fluorophore detection capabilities, was used to delineate subsurface contaminant releases in an area where plating shop waste was temporarily stored. Records indicated that various nonaqueous phase liquids (NAPLs) were released at the site. The investigators advanced the SCAPS laser-induced fluorescence (LIF) sensor to depths beneath the water table of the principal water-bearing zone. The water table was located approximately 6 feet (1.8 m) below ground surface (bgs) across the site. Fluorescence, attributed to fuel compounds commingled with chlorinated solvents, was observed at depths ranging from 4.0 to 11.5 feet (1.2 to 3.5 m) bgs. Fluorescence, attributed to naturally occurring organic materials (by process of elimination and spectral characteristics) commingled with chlorinated solvent constituents, was observed at depths ranging from approximately 13 to 40 feet (4.0 to 12.2 m) bgs. Fluorescence responses from compounds confirmed to be commingled with chlorinated solvents indicates that the SCAPS fluorophore detection system is capable of indirectly delineating vadose zone and subaqueous chlorinated solvents and other dense nonaqueous phase liquids (DNAPLs) at contaminant release sites. This confirmation effort represents the first documented account of the successful application of LIF to identify a mixed DNAPL/LNAPL source zone.  相似文献   
37.
The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m3 of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades.  相似文献   
38.
Theoretical and Applied Climatology - A number of studies have sought to relate net radiation over natural surfaces to incoming global radiation. Several deficiencies are noted in interpretation of...  相似文献   
39.
Newly-discovered carbonatitic fragments from the West Eifel are described in terms of their petrography and trace-element content.  相似文献   
40.
Summary An atmosphere is modelled by averaging measurements taken at eight locations for 1968 September 9. The effectiveness of the modelling is evaluated by comparing the atmospheric dispersion properties determined from an experimentally recorded signal resulting from a nuclear explosion on that date and those computed from the model atmosphere. The effects of atmospheric winds are shown to change the dispersion properties.
A theoretical barogram is synthesized for a receiver located 7930 km from the source and is compared to the recorded signal for the event. Barograms are synthesized for two different source functions and the source functions are discussed.  相似文献   
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