Rare-earth elements in groundwaters from the Osamu Utsumi mine and Morro do Ferro analogue study sites, Poços de Caldas, Brazil     

N. Miekeley  H. Coutinho de Jesus  C.L. Porto da Silveira  P. Linsalata  R. Morse 《Journal of Geochemical Exploration》1992,45(1-3)

Data are presented on rare-earth elements (REE) in prefiltered (<450 nm) near-surface and deeper groundwaters and in corresponding particulate matter (>450 nm) from the Osamu Utsumi uranium mine and the Morro do Ferro thorium-REE-deposit. Groundwaters from both sites typically contain between 1–50 μg/l of total REE, but can reach values of up to 160 μg/l in the deepest borehole F4 (U-Mine: 150–415 m). Even higher REE concentrations of up to 29 mg/l were measured in acidic, sulfate-rich near-surface waters of the same site. The chondrite-normalized REE patterns in deeper, more reducing groundwaters and in their corresponding suspended particle fractions are similar to those observed in the bedrock (phonolites), indicating that bedrock leaching and secondary mineral sorption occurred without significant fractionation between these elements, in accordance with the only small variations in the stability constants of the expected REE-sulfate complexes in these waters. Groundwaters from the unsaturated zone of both sites show a very characteristic cerium depletion (less pronounced than that observed in the corresponding suspended particulate fractions), which is most probably related to the oxidation of Ce (III) under the prevailing E_h-conditions of these waters (600 to 800 mV), and to sorption/precipitation reactions of the much less soluble Ce(IV) species. Coarse particulate matter (>450 nm), composed mainly of amorphous ferric hydrous oxides, has a strong capacity for sorption of REE. This is shown by its very high REE concentrations, in some boreholes > 8,000 μg/g (total REE), and by the calculated association ratios R_a (ml/g), which are in the order of 10⁵ to 10⁶. The implications of these findings for the migration behavior of REE in both environments are discussed.  相似文献   

Chemical and physical characterization of suspended particles and colloids in waters from the Osamu Utsumi mine and Morro do Ferro analogue study sites, Poços de Caldas, Brazil     

N. Miekeley  H. Coutinho de Jesus  C.L. Porto da Silveira  C. Degueldre 《Journal of Geochemical Exploration》1992,45(1-3)

Data are presented on suspended particles and colloids in groundwaters from the Osamu Utsumi mine and the Morro do Ferro analogue study sites. Cross-flow ultrafiltration with membranes of different pore sizes (450 nm to 1.5 nm) was used to prepare colloid concentrates and ultrafiltrates for analyses of major and trace elements and U- and Th-isotopic compositions. Additional characterization of colloidal and particulate material was performed by ESCA, SEM and X-ray diffraction. The results indicate the presence of low concentrations of colloids in these waters (typically < 500 μg/l), composed mainly of iron/organic species. Minor portions of uranium and other trace elements, but significant fractions of the total concentrations of Th and REE in prefiltered waters (< 450 nm) were associated with these colloids.Suspended particles (> 450 nm), also composed mainly of hydrous ferric oxides and humic-like compounds, show the same trend as the colloids with respect to U, Th and REE associations, but elemental concentrations were typically higher by a factor of 1,000 or more. In waters of low pH and with high sulphate content, these associations are considerably lower. Due to the low concentrations of suspended particles in groundwaters from the Osamu Utsumi uranium mine (typically <0.5 mg/l), these particles carry only a minor fraction of U and the REE (<10% of the total concentrations in unfiltered groundwaters), but a significant, usually predominant fraction of Th (30–70%). The suspended particle load in groundwaters from the Morro do Ferro environment is typically higher than in those from the mine by a factor of 5 to 10. This suggests that U, Th and the REE could be transported predominantly by particulate matter. However, these particles and colloids seem to have a low capacity for migration.  相似文献   

The first multi-model ensemble of regional climate simulations at kilometer-scale resolution part 2: historical and future simulations of precipitation     

Pichelli  Emanuela  Coppola  Erika  Sobolowski  Stefan  Ban  Nikolina  Giorgi  Filippo  Stocchi  Paolo  Alias  Antoinette  Belu&#;i&#;  Danijel  Berthou  Segolene  Caillaud  Cecile  Cardoso  Rita M.  Chan  Steven  Christensen  Ole B&#;ssing  Dobler  Andreas  de Vries  Hylke  Goergen  Klaus  Kendon  Elizabeth J.  Keuler  Klaus  Lenderink  Geert  Lorenz  Torge  Mishra  Aditya N.  Panitz  Hans-Juergen  Sch&#;r  Christoph  Soares  Pedro M. M.  Truhetz  Heimo  Vergara-Temprado  Jesus 《Climate Dynamics》2021,56(11):3581-3602

This paper presents the first multi-model ensemble of 10-year, “convection-permitting” kilometer-scale regional climate model (RCM) scenario simulations downscaled from selected CMIP5 GCM projections for historical and end of century time slices. The technique is to first downscale the CMIP5 GCM projections to an intermediate 12–15 km resolution grid using RCMs, and then use these fields to downscale further to the kilometer scale. The aim of the paper is to provide an overview of the representation of the precipitation characteristics and their projected changes over the greater Alpine domain within a Coordinated Regional Climate Downscaling Experiment Flagship Pilot Study and the European Climate Prediction system project, tasked with investigating convective processes at the kilometer scale. An ensemble of 12 simulations performed by different research groups around Europe is analyzed. The simulations are evaluated through comparison with high resolution observations while the complementary ensemble of 12 km resolution driving models is used as a benchmark to evaluate the added value of the convection-permitting ensemble. The results show that the kilometer-scale ensemble is able to improve the representation of fine scale details of mean daily, wet-day/hour frequency, wet-day/hour intensity and heavy precipitation on a seasonal scale, reducing uncertainty over some regions. It also improves the representation of the summer diurnal cycle, showing more realistic onset and peak of convection. The kilometer-scale ensemble refines and enhances the projected patterns of change from the coarser resolution simulations and even modifies the sign of the precipitation intensity change and heavy precipitation over some regions. The convection permitting simulations also show larger changes for all indices over the diurnal cycle, also suggesting a change in the duration of convection over some regions. A larger positive change of frequency of heavy to severe precipitation is found. The results are encouraging towards the use of convection-permitting model ensembles to produce robust assessments of the local impacts of future climate change.

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Analysis of contamination hazard of surface water by the methodology of TECHNEAU: a case study from the dam 9 April 1947 in northern Morocco     

Ismail Hilal  Jamal Eddine Stitou El Messari  Jesus Gabriel Moreno Navarro  Mohamed Draoui 《Arabian Journal of Geosciences》2017,10(8):197

Preventive protection of surface waters against pollution and the guarantee of the best quality water are the major challenges to provide a sustainable supply of drinking water for the future generations. In this article, we present a hazard mapping application for water contamination of the dam “9 April 1947” located in the northwest of Morocco. This study was motivated by the proliferation of many pollution sources in the study area knowing that the dam feeds the region of Tanger-Asilah that has over 3 million inhabitants. The methodology used was applied for the first time in the city of Freiburg-Ebnet in Germany under the TECHNEAU project funded by the European commission and based on weighting of the different sources of contamination according to three indices: the toxicity index, quantity index, and probability index. The multiplication of the three indices has given us a hazard index named HI varying between 0 and 120 depending on the harmfulness of hazard; the later index has been used to create the final contamination hazard map. The hazard map shows 65% of the watershed area is witnessing a very low danger, 22% of the watershed area is witnessing a low danger, 10% of the watershed area is witnessing a the high danger, and 3% of the watershed area is witnessing a moderate.  相似文献   

Surface temperature,chlorophyll and advection patterns during a summer upwelling event off central Portugal     

Paulo B. Oliveira  Rita Nolasco  Jesus Dubert  Teresa Moita  Álvaro Peliz 《Continental Shelf Research》2009,29(5-6):759-774

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A Numerical Study on the Relationship Between Transmissivity and Specific Capacity in Heterogeneous Aquifers   总被引：7，自引：0，他引：7  

Peter M. Meier  Jesus Carrera  Xavier Sanchez-Vila 《Ground water》1999,37(4):611-617

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Vertical mixing and elements of mesoscale dynamics over North Carolina shelf and contiguous Gulf Stream waters   总被引：2，自引：1，他引：1  

Iossif Lozovatsky  Jesus Planella-Morato  Kipp Shearman  Qing Wang  Harindra Joseph S. Fernando 《Ocean Dynamics》2017,67(6):783-798

Results of microstructure measurements conducted in October–November of 2015 as a part of the Coupled Air Sea Processes and Electromagnetic Ducting Research (CASPER) project are discussed. The measurements were taken on the North Carolina shelf and across the Gulf Stream front. On the shelf, the oceanic stratification was influenced by highly variable surface salinity and along-bottom advection. Vertical mixing was mostly governed by variable winds. The vertical eddy diffusivity was estimated using the VMP-based dissipation measurements, and the diffusivity values obtained during calm periods and stormy winds were compared. Parameterization of the diffusivity for various mesoscale dynamical conditions is discussed in terms of shear instabilities and internal wave-generated turbulence based on data obtained in deep waters of the Gulf Stream and on the continental slope.  相似文献   

A simplified input output relation method using AR model for earthquake wave propagation analysis     

Hideji Kawakami  Paul de Jesus Bidon 《地震工程与结构动力学》1997,26(10):1041-1057

This paper introduces a Simplified Input Output Relation Method (SIORM) using multiple-variable autoregression (AR) model which can be used to determine ground wave propagation properties. Using the AR model, a method is developed to establish the basis for the formulation of SIORM. The degree of accuracy of this method is evaluated. SIORM is applied to actual ground acceleration records taken at Minamisuna and Etchujima sites in Japan and its results are discussed in this paper. © 1997 John Wiley & Sons, Ltd.  相似文献   

Survival of lichens and bacteria exposed to outer space conditions - Results of the Lithopanspermia experiments     

Rosa de la Torre  Leopoldo G. Sancho  Asunción de los Ríos  Karen Olsson-Francis  Petra Rettberg  Jean-Pierre P. de Vera  Jesus Martinez Frías  Maria Mercedes Lucas  Ana Pintado 《Icarus》2010,208(2):735-292

In the space experiments Lithopanspermia, experimental support was provided to the likelihood of the lithopanspermia concept that considers a viable transport of microorganisms between the terrestrial planets by means of meteorites. The rock colonising lichens Rhizocarpon geographicum and Xanthoria elegans, the vagrant lichen Aspicilia fruticulosa, and endolithic and endoevaporitic communities of cyanobacteria and bacteria with their natural rock substrate were exposed to space for 10 days onboard the Biopan facility of the European Space Agency (ESA). Biopan was closed during launch and re-entry. In addition, in the Stone facility, one sample of R. geographicum on its natural granitic substrate was attached at the outer surface of the re-entry capsule close to the stagnation point, only protected by a thin cover of glass textolite. Post-flight analysis, which included determination of the photosynthetic activity, LIVE/DEAD staining, and germination capacity of the ascospores, demonstrated that all three lichen were quite resistant to outer space conditions, which include the full spectrum of solar extraterrestrial electromagnetic radiation or selected wavelength ranges. This high resistance of the lichens to space appears to be due to their symbiotic nature and protection by their upper pigmented layer, the cortex. In contrast, the rock- or halite-inhabiting bacteria were severely damaged by the same exposure. After atmospheric re-entry, the granite of the Stone sample was transformed into a glassy, nearly homogenous material, with several friction striae. None of the lichen cells survived this re-entry process. The data suggest that lichens are suitable candidates for testing the concept of lithopanspermia, because they are extremely resistant to the harsh environment of outer space. The more critical event is the atmospheric re-entry after being captured by a planet. Experiments simulating the re-entry process of a microbe-carrying meteoroid did not show any survivors.  相似文献   

Nutrient dynamics in an alpine headwater stream: use of continuous water quality sensors to examine responses to wildfire and precipitation events          下载免费PDF全文

Lauren R. Sherson  David J. Van Horn  Jesus D. Gomez‐Velez  Laura J. Crossey  Clifford N. Dahm 《水文研究》2015,29(14):3193-3207

Stream water quality can change substantively during diurnal cycles, discrete flow events, and seasonal time scales. In this study, we assessed event responses in surface water nutrient concentrations and biogeochemical parameters through the deployment of continuous water quality sensors from March to October 2011 in the East Fork Jemez River, located in northern New Mexico, USA. Events included two pre‐fire non‐monsoonal precipitation events in April, four post‐fire precipitation events in August and September (associated with monsoonal thunderstorms), and two post‐fire non‐monsoonal precipitation events in October. The six post‐fire events occurred after the Las Conchas wildfire burned a significant portion of the contributing watershed (36%) beginning in June 2011. Surface water nitrate (NO₃? N) concentrations increased by an average of 50% after pre‐fire and post‐fire non‐monsoonal precipitation events and were associated with small increases in turbidity (up to 15 NTU). Beginning 1 month after the start of the large regional wildfire, monsoonal precipitation events resulted in large multi‐day increases in dissolved NO₃? N (6 × background levels), dissolved phosphate (100 × background levels), specific conductance (5 × background levels), and turbidity (>100 × background levels). These periods also corresponded with substantial sags in dissolved oxygen (<4 mg l^?1) and pH (<6.5). The short duration and rapid rates of change during many of these flow events, particularly following wildfire, highlight the importance of continuous water quality monitoring to quantify the timing and magnitude of event responses in streams and to examine large water quality excursions linked to catchment disturbance. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献