The effect of mineralogy on the mobility of heavy metals in mine tailings: a case study in the Samsanjeil mine,Korea     

Heon Jung Kim  Yeongkyoo Kim  Chang Oh Choo 《Environmental Earth Sciences》2014,71(8):3429-3441

This study examined the chemical speciation and mobility of As and heavy metals in a tailings impoundment in Samsanjeil mine located in Gosung, Korea, as well as the factors affecting them. XRD, SEM, and 5-step sequential extraction were used to examine the samples at two sampling sites (NN and SN sites). The pH of the tailings decreased with increasing depth at the NN site (from 7.2 to 2.8), whereas no significant differences were observed at the SN site (8.1–8.8). The samples at the SN site showed a larger amount of calcite than those at the NN site, indicating that calcite plays an important role buffering the pH in the study sites. Jarosite was found only at the lower part of the NN site, where calcite was not found. The mineralogical observation of jarosite and calcite was also confirmed by SEM. The concentrations of As and heavy metals in the tailings were as follows: Cu > As > Zn > > Pb > Co > Cr > Ni > Cd. The total concentrations of Ni, Zn, Co, and Cd were higher at the SN site than those at the NN site. On the other hand, the concentrations of As and Cr existing as oxyanions were higher at the NN site, which can be explained by the mobility changes of those elements affected by pH variations. At the NN site, the fractions of heavy metals bound to the Fe/Mn oxides, except for As and Cr, decreased, and Cu, Zn, and Co showed an increasing fraction of exchangeable metals with increasing depth. This suggests that the pH and resulting surface charge of minerals, such as goethite and jarosite, are the dominant factors controlling the chemical speciation of metals. These results highlight the importance of mineralogy in controlling the mobility and possible bioavailability of heavy metals in tailings.  相似文献   

Titanium- and water-rich metamorphic olivine in high-pressure serpentinites from the Voltri Massif (Ligurian Alps,Italy): evidence for deep subduction of high-field strength and fluid-mobile elements     

Jan?C.?M.?De HoogEmail author  Keiko?Hattori  Haemyeong?Jung 《Contributions to Mineralogy and Petrology》2014,167(3):990

Titanium- and water-rich metamorphic olivine (Fo 86–88) is reported from partially dehydrated serpentinites from the Voltri complex, Ligurian Alps. The rocks are composed of mostly antigorite and olivine in addition to magnetite, chlorite, clinopyroxene and Ti-clinohumite. In situ secondary ion mass spectrometry (SIMS) data show that metamorphic olivine has very high and strongly correlated H₂O (up to 0.7 wt%) and TiO₂ contents (up to 0.85 wt%). Ti-rich olivine shows colourless to yellow pleochroism. Olivine associated with Ti-clinohumite contains low Ti, suggesting that Ti-rich olivine is not the breakdown product of Ti-clinohumite. Fourier transform infrared spectroscopy (FTIR) absorption spectra show peaks of serpentine, Ti-clinohumite and OH-related Si vacancies. Combining FTIR and SIMS data, we suggest the presence of clustered planar defects or nanoscale exsolutions of Ti-clinohumite in olivine. These defects or exsolutions contain more H₂O (x ~ 0.1 in the formula 4Mg₂SiO₄·(1?x)Mg(OH,F)₂·xTiO₂) than Ti-clinohumite in the sample matrix (x = 0.34–0.46). In addition to TiO₂ and H₂O, secondary olivine contains significant Li (2–60 ppm), B (10–20 ppm), F (10–130 ppm) and Zr (0.9–2.1 ppm). It is enriched in ¹¹B (δ¹¹B = +17 to +23 ‰). Our data indicate that secondary olivine may play a significant role in transporting water, high-field strength and fluid-mobile elements into the deeper mantle as well as introduce significant B isotope anomalies. Release of hydrogen from H₂O-rich olivine subducted into the deep mantle may result in strongly reduced mantle domains.  相似文献   

Assessment of future runoff trends under multiple climate change scenarios in the Willamette River Basin,Oregon, USA     

Il‐Won Jung  Heejun Chang 《水文研究》2011,25(2):258-277

We investigated trends in future seasonal runoff components in the Willamette River Basin (WRB) of Oregon for the twenty‐first century. Statistically downscaled climate projections by Climate Impacts Group (CIG), eight different global climate model (GCM) simulations with two different greenhouse gas (GHG) emission scenarios, (A1B and B1), were used as inputs for the US Geological Survey's Precipitation Runoff Modelling System. Ensemble mean results show negative trends in spring (March, April and May) and summer (June, July and August) runoff and positive trends in fall (September, October and November) and winter (December, January and February) runoff for 2000–2099. This is a result of temperature controls on the snowpack and declining summer and increasing winter precipitation. With temperature increases throughout the basin, snow water equivalent (SWE) is projected to decline consistently for all seasons. The decreases in the centre of timing and 7‐day low flows and increases in the top 5% flow are caused by the earlier snowmelt in spring, decreases in summer runoff and increases in fall and winter runoff, respectively. Winter runoff changes are more pronounced in higher elevations than in low elevations in winter. Seasonal runoff trends are associated with the complex interactions of climatic and topographic variables. While SWE is the most important explanatory variable for spring and winter runoff trends, precipitation has the strongest influence on fall runoff. Spatial error regression models that incorporate spatial dependence better explain the variations of runoff trends than ordinary least‐squares (OLS) multiple regression models. Our results show that long‐term trends of water balance components in the WRB could be highly affected by anthropogenic climate change, but the direction and magnitude of such changes are highly dependent on the interactions between climate change and land surface hydrology. This suggests a need for spatially explicit adaptive water resource management within the WRB under climate change. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Whipple telescope observations of LS I +61 303: 2004–2006     

A. Smith  R. W. Atkins  S. Bradbury  O. Celik  Y. C. K. Chow  P. Cogan  C. Dowdall  S. J. Fegan  P. Fortin  D. Gall  G. H. Gillanders  J. Grube  K. J. Gutierrez  T. A. Hall  D. Hanna  J. Holder  D. Horan  S. B. Hughes  T. B. Humensky  I. Jung  P. Kaaret  G. Kenny  M. Kertzman  D. B. Kieda  A. Konopelko  H. Krawczynski  F. Krennrich  M. J. Lang  S. Le Bohec  G. Maier  J. Millis  P. Moriarty  R. A. Ong  J. S. Perkins  K. Ragan  G. H. Sembroski  J. A. Toner  L. Valcarcel  V. V. Vassiliev  R. G. Wagner  S. P. Wakely  T. C. Weekes  R. J. White  D. A. Williams 《Astrophysics and Space Science》2007,309(1-4):299-303

In this paper we present the results of the past two years observations on the galactic microquasar LS I +61 303 with the Whipple 10 m gamma-ray telescope. The recent MAGIC detection of the source between 200 GeV and 4 TeV suggests that the source is periodic with very high energy (VHE) gamma-ray emission linked to its orbital cycle. The entire 50-hour data set obtained with Whipple from 2004 to 2006 was analyzed with no reliable detection resulting. The upper limits obtained in the 2005–2006 season covered several of the same epochs as the MAGIC Telescope detections, albeit with lower sensitivity. Upper limits are placed on emission during the orbital phases of 0→0.1 and 0.8→1, phases which are not included in the MAGIC data set.   相似文献   

Evaluation of Estrogenic Activity and Measurement of EDCs in Wastewater Treatment Plants     

B. C. Lee  J. Y. Jung  H. K. Kim 《中国海洋大学学报(英文版)》2006,5(4):351-356

1IntroductionDuringthe past several years,concern hasincreasedover the potential pollution of watershed by estrogeniccompounds,including steroidal hormones fromhumanand ani mal sources.Effluents from wastewater treat-ment plants are sources of endocrine-d…  相似文献   

Genetic responses of the ark shell Scapharca broughtonii Schrenck to environmental shock: High temperatures and long exposure times     

Eun Seob Cho  Choon Goon Jung  Yun Kyung Shin 《Ocean Science Journal》2009,44(2):61-67

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Improvement of daily precipitation estimations using PRISM with inverse-distance weighting     

Ha-Gyu Jeong  Joong-Bae Ahn  Joonlee Lee  Kyo-Moon Shim  Myung-Pyo Jung 《Theoretical and Applied Climatology》2020,139(3):923-934

Improved daily precipitation estimations were attempted using the parameter-elevation regressions on a parameter-elevation regression on independent slopes model (PRISM) with inverse-distance weighting (IDW) and a precipitation-masking algorithm for precipitation areas. The PRISM (PRISM_ORG) suffers two overestimation problems when the daily precipitation is estimated: overestimation of the precipitation intensity in mountainous regions and overestimation of the local precipitation areas. In order to solve the problem of overestimating the precipitation intensity, we used the IDW technique that employs the same input stations as those used in the PRISM regression (PRISM_IDW). A precipitation-masking algorithm that selectively masks the precipitation estimation grid points was additionally applied to the PRISM_IDW results (PRISM_MSK). For 6 months from March to August 2012, daily precipitation data were produced in a horizontal resolution of 1 km based on the above two experiments and PRISM_ORG. Afterwards, each experiment was evaluated for improvements. The monthly root mean squared errors (RMSEs) of PRISM_IDW and PRISM_MSK were reduced by 0.83 mm/day and 0.86 mm/day, respectively, compared to PRISM_ORG.  相似文献   

Ecosystem responses to climate change in a large on-river reservoir, Lake Paldang, Korea   总被引：3，自引：0，他引：3  

Hae-Kyung Park  Kang-Hyun Cho  Doo Hee Won  Jangho Lee  Dong-Soo Kong  Dong-Il Jung 《Climatic change》2013,120(1-2):477-489

The impact of climate change on a large river reservoir ecosystem was investigated. Long-term meteorological data showed that recent climate change, including warmer winters, increased precipitation intensity and extended dry periods, may have influenced the basin of Lake Paldang, the most downstream reservoir of a series of on-river reservoirs. Extreme hydrologic events and climate warming, acting independently and in combination, appear to be related to changes in the Lake Paldang ecosystem. A significant increase in chlorophyll a concentrations in early spring corresponded to the timing of ice break-up. An increase in winter temperatures, which resulted in a shorter time period of ice-cover and earlier ice break-up, appears to have stimulated phytoplankton growth in winter and early spring. Repeated intensive and extended influxes of turbid water, associated with more frequent extreme rainfall events, have increased concentration of suspended solids and may have influenced the biotic community structure of Lake Paldang. In the mid-2000s, the area vegetated by submerged hydrophytes, the abundance and biomass of the phylum Mollusca, as well as the abundance of fish from the subfamily Acheilognathinae, which spawn in the body of bivalve molluscs, was all smaller than in the late 1980s and early 1990s. Together, these results suggest that climate change may have contributed directly and indirectly to changes in each trophic level of the Lake Paldang ecosystem.  相似文献   

Hydraulic fracturing stress measurements near the Hohenzollern-Graben-structure,SW Germany     

F. Rummel  R. Jung 《Pure and Applied Geophysics》1975,113(1):321-330

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Visual framework for development and use of constitutive models     

Youssef M. A. Hashash  Donald C. Wotring  John I‐Chiang Yao  Jung‐Suk Lee  Qingwei Fu 《国际地质力学数值与分析法杂志》2002,26(15):1493-1513

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