Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers     

Kathleen A. Radloff  Anya R. Manning  Brian Mailloux  Yan Zheng  M. Moshiur Rahman  M. Rezaul Huq  Kazi M. Ahmed  Alexander van Geen 《Applied Geochemistry》2008

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.  相似文献   

Composition and quality of coals in the Huaibei Coalfield, Anhui, China   总被引：3，自引：0，他引：3  

Liugen Zheng  Guijian Liu  Lei Wang  Chen-Lin Chou 《Journal of Geochemical Exploration》2008,97(2-3):59-68

The Huaibei Coalfield, Anhui Province, China, is one of the largest coalfields in China. The coals of Permian age are used mainly for power generation. Coal compositions and 47 trace elements of the No. 10 Coal of the Shanxi Formation, the No. 7, 5, and 4 Coals of the Lower Shihezi Formation, and the No. 3 Coal of the Upper Shihezi Formation from the Huaibei Coalfield were studied. The results indicate that the Huaibei coals have low ash, moisture, and sulfur contents, but high volatile matter and calorific value. The ash yield increases stratigraphically upwards, but the volatile matter and total sulfur contents show a slight decrease from the lower to upper seams. Magmatic intrusion into the No. 5 Coal resulted in high ash, volatile matter, and calorific value, but low moisture value in the coal. Among the studied 47 trace elements, Ba, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Th, U, V, and Zn are of environmental concerns. Four elements Hg, Mo, Zn, and Sb are clearly enriched in the coals as compared with the upper continental crust.  相似文献   

塔里木西部地区古生代断裂活动的方式和机制   总被引：15，自引：2，他引：13       下载免费PDF全文

李曰俊  吴根耀  孟庆龙  师骏  冯晓军  郑民 《地质科学》2008,43(4):727-745

基于系统的地震剖面解释及其与塔中地区的对比,本文探讨了塔里木西部地区古生代断裂活动的方式和机制。玛东断裂带是一条宽阔的北东向盖层滑脱型褶皱冲断带,前展式向东南扩展,冲断作用发生在奥陶纪末。巴东断裂(吐土休克Ⅱ号断裂)为北西向基底卷入型冲断带,奥陶纪末和中二叠世末发生冲断。巴西断裂和塔参2井南断裂是海西期的正断层。塔里木古板块古生代的发育受邻侧的造山带演化制约,近东西向和北东向断裂奥陶纪末的冲断是继承基底构造发育的。塔中地区的近北西向断裂是晚寒武世的新生断裂,加里东运动可分为两幕:奥陶纪末的冲断(艾比湖运动)和晚志留-中泥盆世的冲断-走滑,后者向西明显减弱。塔里木西部的部分北西向断裂(如康西断裂)可归入塔中北西向断裂系。北东向的玛东断裂带是其西的向北(东)冲断的吐木休克断裂带与其东的向南偏东冲断的塔中8-1井——塔中5井断裂带之间的调节断层。  相似文献   

四川大陆槽稀土矿床碳酸岩-英碱正长岩锆石U-Pb年代学和Hf同位素性质及其地质意义   总被引：5，自引：2，他引：3  

田世洪  侯增谦  杨竹森  杨志明  袁忠信  王彦斌  谢玉玲  刘英超  李政 《岩石学报》2008,24(3)

川西冕宁-德昌稀土成矿带是中国最重要的稀土成矿带之一,所有稀土矿床均与碳酸岩-正长岩杂岩体有关.前人研究表明,牦牛坪、木落寨和里庄碳酸岩-碱性杂岩体成岩年龄与其相应矿床的成矿年龄基本一致,而大陆槽正长岩年龄与REE矿床的成矿年龄相差甚远.本文对大陆槽碳酸岩、英碱正长岩进行了SHRIMP U-Pb锆石年代学和LA-MC-ICPMS锆石Hf同位素原位测量,它们的形成年龄分别为12.99±0.94Ma、14.53±0.31Ma,表明两者是同时形成的,且与其成矿年龄基本一致.碳酸岩和正长岩的εHf(t)值、Hf模式年龄与它们的εNd(t)值、Nd模式年龄所展现出来的特征一致,说明在其形成过程中有地壳物质的加入.  相似文献   

海拉尔盆地贝尔凹陷兴安岭群储层粘土矿物组成及成因研究   总被引：1，自引：0，他引：1  

刘钦甫  付正  候丽华  郑丽华 《矿物学报》2008,28(1):43-47

油田注水开发是保持地层能量,提高采收率的有效手段.海拉尔地区由于粘土矿物含量高,在开发过程中储层遇水易泥化、坍塌,严重影响油气的有效开采.通过X射线衍射、偏光显微镜观察和扫描电镜分析,确定了海拉尔盆地贝16断块兴安岭群储层自上而下存在三种粘土矿物组合:蒙脱石 高岭石 (绿泥石)→高岭石 伊/蒙间层 伊利石 (绿泥石)→伊利石 绿泥石 绿/蒙间层 伊/蒙间层.粘土总量在9.1%～69.1%之间,由地层浅部到深部呈现由高到低的变化规律.详细研究了水敏性极强的钠蒙脱石及其间层矿物,认为凝灰物质的水解蚀变以及长石和中、酸性岩屑在成岩过程中的次生变化是造成海拉尔地区粘土含量高的主要因素.  相似文献   

大型海藻对富营养化海水养殖区的生物修复   总被引：1，自引：0，他引：1       下载免费PDF全文

江志兵  曾江宁  陈全震  廖一波  刘晶晶  郑平 《海洋开发与管理》2006,23(4):57-63

随着海水养殖的快速发展,养殖水体的自身污染和富营养化已成为严重的环境问题。作为生物滤器的大型海藻可以有效地吸收、利用养殖环境中多余的氮、磷等营养物质,从而减轻养殖废水对环境的影响,并提高养殖系统的经济输出,被广泛应用于鱼、虾和贝类等的综合养殖系统中,对富营养化海水养殖区进行生物修复。文章概述了大型海藻对富营养化海水养殖区进行生物修复的原因、原理、优点、研究进展以及应用大型海藻产生的效益和需要注意的问题。并指出在富营养化海水养殖区养殖大型海藻进行生物修复的方法可以实现海水养殖业的可持续发展。  相似文献   

Diel Patterns in Chlorophyll <Emphasis Type="Italic">a</Emphasis> Specific Absorption Coefficient and Absorption Efficiency Factor of Picoplankton     

Nobuaki?OhiEmail author  Hiroaki?Saito  Satoru?Taguchi 《Journal of Oceanography》2005,61(3):379-388

Diel patterns in the chlorophyll a specific absorption coefficient of surface picoplankton, a*_pico (γ) (m²·[mg chlorophyll a]⁻¹), were studied at 7 stations under daily cycle of in situ light condition in the western subarctic Pacific and Japan Sea. All the data were normalized by dividing the anomaly with daily averaged a*_pico (γ). Opposite diel patterns were observed for the normalized a*_pico (443) and a*_pico (675) with maximum toward dawn or dusk and minimum toward midday at 4 stations under low-irradiance (LI) conditions and vice versa at 3 stations under high-irradiance (HI) conditions. The absorption efficiency factors at red absorption peak, Q _a (675), were determined by reconstruction with intracellular chlorophyll a concentration and cell diameter. The normalized Q _a (675) also showed diel pattern with maximum toward midday and minimum toward dawn or dusk under LI. The diel pattern in a*_pico (675) and Q _a (675) were primarily caused by changes in intracellular chlorophyll a concentration due to photoadaptation under LI. The diel pattern in a*_pico (443) was influenced by pigmentation, as recognized by blue to red ratio [a*_pico (443)/a*_pico (675)] under HI. This study proposed that the opposite diel pattern in a*_pico (γ) might occur for a wide range of algal species. The results presented here have important consequences for the interpretation of diel variations in optical properties observed in the open ocean.  相似文献   

3厘米扫描成像微波辐射计在海洋感感中的初次应用     

孙元福  郑全安 《海洋学报》1981,3(3):400-409

所有物体都不断地发出电磁辐射,在微波谱段内黑体的辐射量B_bb可用瑞利—金斯公式表示:B_bb=2KT/λ2。  相似文献   

舟山枸杞水域的污损生物生态   总被引：1，自引：0，他引：1  

蔡如星  陈树庆 《海洋学研究》1994,12(3):42-56

本文系１９８８年９月～１９８９年９月在舟山枸杞乌里西岙水域进行挂板试验的结果。共获污损生物１３５种，其中，近岸的油库码头获７７种，远岸的养殖筏获１１０种。动物以亚热带高盐性种类为主，三角藤壶Ｂａｌａｎｕｓｔｒｉｇｕｎｕｓ、小海葵Ａｃｔｉｎｉａ、柯氏分胞孔苔虫Ｃｅｌｌｅｐｏｒｉｎａｃｏｓｔａｚｉｉ、西方三胞苔虫Ｔｒｉｃｅｌａｒｉａｏｃｃｉｄｅｎｔａｌｉｓ、艾氏美熄Ｃｌｔｉａｅｄｗａｒｄｓｉ、广口小桧叶螅Ｓｅｒｔｕｌａｒｅｌｌａｍｉｕｒｒｅｎｓｉｓ等占优势，藻类常见的有长石莼Ｕｌｖａｌｉｎｚａ、肠浒苔Ｅｎｔｅｒｏｍｏｒｐｈｙｉｎｔｅｓｔｉｎａｌｉｓ和日本多管藻Ｐｏｌｙｓｉｐｈｏｎｉａｊａｐｏｎｉｃａ。枸杞污损生物的附着期主要在夏季，附着量也以夏季最大。不同地点附着量的差异极大。夏季由于近岸三角藤壶大量附着，故生物量明显大子远岸，其他季节均是远岸大于近岸。夏季近岸三角藤壶的覆盖面积达１００％，生物量达１８１１９ｇ／ｍ２，占污损生物总生物量的９８％。故夏季是污损生物防除的主要季节，三角藤壶是防除的主要对象。与１９７５～１９７６年嵊山污损生物进行比较，发现两地污损生物的种类组成和群落结构极为相似，说明１０多年以来嵊山  相似文献   

秦山核电站邻近水域的流况分析     

羊天柱  许建平 《海洋学研究》1993,11(1):10-17

本文分析了秦山核电站邻近水域各测站的实测流、潮流和佘流分布及季节变化。结果表明:测区内潮流为非正规丰日浅海潮流,其运动形式呈往复流。核电站二期工程取水口附近(L_1,18站)为一大流速区,而一期工程出水口周围(L_2,L_2′站)有一相对小的流速区。大流速区落潮流历时大于涨潮流历时,而相对小流速区则相反;大流速区的余流较小,而小流速区的余流大。在四个季节中,涨潮流速秋季最大,春季次之,夏季最小;落潮流速秋季最大,夏季次之,春季最小。余流冬、秋两季较大。在实测流中以潮流为主,径流和季风的作用也相当显著。  相似文献