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81.
82.
Vibrational modelling is at the present time the only known way to predict the heat capacities of the Earth's mantle minerals at high-pressure and high-temperature. To test the validity of this method for λ-type transitions, we have applied it to the α-β quartz transition (T 0=846±1 K). Raman spectra of quartz were recorded up to 900 K. Measured frequency shifts of the α-quartz Raman modes were then used in conjunction with available high-pressure Raman data to calculate intrinsic mode anharmonicity, through the parameter a i=(?Lnvi/?T)v. Vibrational modelling of the heat capacity at constant volume, Cv, and at constant pressure, Cp, including anharmonic corrections deduced from the a i parameters, are compared to experimental data. Taking into account the soft-mode associated to the α-β quartz transition, the model reproduces the excess of Cp related to the transition. Then, this study confirms that detecting a soft-mode from vibrational data allows one to predict λ-type transitions. However, when modelling the thermodynamic properties, the contribution of a soft-mode cannot be established from spectroscopic data. Therefore, one needs first to determine this contribution in order to predict the heat capacities of Earth's mantle minerals displaying λ-type transitions. In α-quartz, this contribution has been determined as 0.007% of the total number of the optic modes in the model of the density of states. 相似文献
83.
Carlos Pecharromán T. González-Carreño Juan E. Iglesias 《Physics and Chemistry of Minerals》1995,22(1):21-29
The infrared complex permittivity functions of three varieties of maghemite, γ-Fe2O3, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors. 相似文献
84.
Modelling the spatial and temporal distribution of rainfall intensity at local scale 总被引:1,自引:0,他引:1
Summary Accurate estimates of rainfall intensity distribution with high temporal and spatial resolution are necessary in most urban hydrological studies, such as planning, simulation or control of sewer networks. Traditionally, these data are obtained from intensity-duration-frequency (IDF) curves at sites with long rainfall intensity time-series, however, little attention is given to the spatial features of precipitation. In this paper, a mathematical model of a local scale storm that takes account of the spatial variability of rainfall and rain-cell movement is proposed. The model has been calibrated with a dense network of raingauges and a long rainfall intensity timeseries (60 years) and its parameters have been calculated for convective storms of return periods up to 15 years with their most frequently-observed rain-cell velocities (1 to 4 m/s).This work has been supported by the DGICYT, Project NAT91-0596.With 6 Figures 相似文献
85.
Puerto Galera Bay is a coastal lagoon with a variety of marine habitats and high species diversity. It is an area in the Phillippines where the growing influence of human activities is affecting the quality of its marine resources. This study examined the distribution and behaviour of nutrients and the physical hydrography of Puerto Galera Bay and determined how its physico-chemical nature affected the condition of biotic components in the bay. The relative importance of the nitrogen and phosphorus signals were used as indicators to implicate the influence of sewage and run-off into the bay. A nutrient pool accumulated in the bay as a result of low flushing rates. The interaction of hydrodynamic forcing with the biota have implications on the phytoplankton production and coral communities in the area. 相似文献
86.
This paper deals with the lower order (first four) nonstationary statistical moments of the response of linear systems with random stiffness and random damping properties subject to random nonstationary excitation modeled as white noise multiplied by an envelope function. The method of analysis is based on a Markov approach using stochastic differential equations (SDE). The linear SDE with random coefficients subject to random excitation with deterministic initial conditions are transformed to an equivalent nonlinear SDE with deterministic coefficients and random initial conditions subject to random excitation. In this procedure, new SDE with random initial conditions, deterministic coefficients and zero forcing functions are introduced to represent the random variables. The joint statistical moments of the response are determined by considering an augmented dynamic system with state variables made up of the displacement and velocity vectors and the random variables of the structural system. The zero time-lag joint statistical moment equations for the augmented state vector are derived from the Itô differential formula. The statistical moment equations are ordinary nonlinear differential equations where hierarchy of moments appear. The hierarchy is closed by the cumulant neglect closure method applied at the fourth order statistical moment level. General formulation is given for multi-degree-of-freedom (MDOF) systems and the performance of the method in problems with nonstationary excitations and large variabilities is illustrated for a single-degree-of-freedom (SDOF) oscillator. 相似文献
87.
88.
The analysis of rural social change has reached a point of somewhat saturated orthodoxy. Numerous studies over the last 20 years have served to reinforce a standard view that it is the ‘newcomer vs local’ conflict which lies at the heart of social and cultural changes in rural communities. Moreover, these broad categorisations have often been translated into class terms without due regard for the detailed circumstances of locality or intra-class fractions. This paper presents some evidence from an intensive study of 10 parishes in rural Gloucestershire, and seeks to provide a detailed background to the distribution of selected indicators of social change in that area. It focuses on the diversions and needs experienced by different social groups and suggests additional complexities to those recognised in traditional treatments of rural conflict. 相似文献
89.
In the Marvejols area (Southern french Massif Central), the gneissic Marvejols supergroup is overthrust on the metasedimentary “Série du Lot”, deposited in part prior to 540 Ma. The allochtonous terranes are characterized by the occurrence of a leptyno-amphibolitic group, a complex association of mafic and felsic rocks of igneous and sedimentary derivation. A 480±10 Ma age has been obtained by U-Pb dating of zircons, for the crystallization of both mafic and felsic meta-igneous rocks. These rocks were emplaced during an important extensional tectonics. Relics of eclogites, pyrigarnites, coronite gabbros and HP-trondhjemites are clear evidence for a further HP-HT event dated at 415±6 Ma on zircons from a HP trondhjemite. Subsequently, the Marvejols supergroup underwent an amphibolite facies metamorphism with incipient mobilization dated at 345±10 Ma. Rifting and thinning of the continental crust in Cambro-Ordovician times appears to be a major geodynamic feature which could account for the thermal events often referred to the “Caledonian” orogeny. The Silurian (415 Ma) age of the HP episode is clearly older than the main Variscan tectonometamorphic event; it is in agreement with Rb-Sr dating of the Moldanubian granulites and with some radiometric data from Southern Brittany (France). These results point to a compressive phase, probably in a subduction context, in view of the high pressures reached (15–20 Kb), after the Cambro-Ordovician distensive phase. The main final tectono-metamorphic paroxysm (blocking of subduction process and continental collison ?) is not prior to the end of Devonian (340–350 Ma) and is related to the Variscan orogeny s.s 相似文献
90.
Fredric L. Prikle Thomas R. Bement Jo Ann Howell Charles D. Koch Newton K. Stablein Richard J. Beckman Gary L. Tietjen 《Journal of Geochemical Exploration》1983,18(3):175-187
Throughout the aerial radiometric reconnaissance survey portion of the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) program, the identification of outliers (anomalies) was an important approach to locating regions with radio-element concentrations that are either higher or lower than expected. The method introduced herein to locate such regions involves three steps: selection of a high (or low) threshold for the variate of interest; use of the sample percentile to identify all points of interest; and movement of a window over the selected data to locate significant clusters of observations. These steps, applied to aerial radiometric 214Bi (equivalent uranium) data collected over the Copper Mountain area in Wyoming, resulted in the identification of areas enriched in that variate. 相似文献