Placental transfer of arsenic to fetus of Dall's porpoises (Phocoenoides dalli)     

Kubota R  Kunito T  Fujihara J  Tanabe S  Yang J  Miyazaki N 《Marine pollution bulletin》2005,51(8-12):845-849

Concentrations of total arsenic and individual arsenic compounds were determined in liver, muscle, kidney and blubber of mother and fetus of Dall’s porpoises collected from off Sanriku, Japan, in the year 2000 to characterize the placental transfer of arsenic to fetus in cetaceans. Arsenic was detected in all the tissues of Dall’s porpoises. Total arsenic concentrations in liver, kidney, muscle and blubber were 0.76, 0.69, 0.35 and 0.55 μg/g wet wt, respectively, for mother and 0.28, 0.23, 0.26 and 0.07 μg/g wet wt, respectively, for fetus. In all the tissues, concentrations of total arsenic in mother Dall’s porpoise were higher than in fetus. Arsenic speciation revealed that arsenobetaine was the major arsenic compound in liver, kidney and muscle of both mother and fetus. The percentage of arsenobetaine to total arsenic ranged from 76.0 to 91.0% in the tissues. Dimethylarsinic acid, arsenocholine, methylarsonic acid and an unidentified arsenic compound were also detected in tissues of both mother and fetus as minor constituents, whereas tetramethylarsonium ion was not detected in tissues of the fetus. These results suggest that arsenobetaine, dimethylarsinic acid, arsenocholine and methylarsonic acid are transferable from mother to fetus in Dall’s porpoises. To our knowledge, this is the first report on placental transfer of arsenic compounds to fetus in marine mammals.  相似文献   

Hydrochemical variations during flood pulses in the south‐west China peak cluster karst: impacts of CaCO3–H2O–CO2 interactions     

Zaihua Liu  Chris Groves  Daoxian Yuan  Joe Meiman  Guanghui Jiang  Shiyi He  Qiang Li 《水文研究》2004,18(13):2423-2437

High‐resolution measurements of rainfall, water level, pH, conductivity, temperature and carbonate chemistry parameters of groundwater at two adjacent locations within the peak cluster karst of the Guilin Karst Experimental Site in Guangxi Province, China, were made with different types of multiparameter sonde. The data were stored using data loggers recording with 2 min or 15 min resolution. Waters from a large, perennial spring represent the exit for the aquifer's conduit flow, and a nearby well measures water in the conduit‐adjacent, fractured media. During flood pulses, the pH of the conduit flow water rises as the conductivity falls. In contrast, and at the same time, the pH of groundwater in the fractures drops, as conductivity rises. As Ca²⁺ and HCO₃^? were the dominant (>90%) ions, we developed linear relationships (both r² > 0·91) between conductivity and those ions, respectively, and in turn calculated variations in the calcite saturation index (SI_C) and CO₂ partial pressure (P) of water during flood pulses. Results indicate that the P of fracture water during flood periods is higher than that at lower flows, and its SI_C is lower. Simultaneously, P of conduit water during the flood period is lower than that at lower flows, and its SI_C also is lower. From these results we conclude that at least two key processes are controlling hydrochemical variations during flood periods: (i) dilution by precipitation and (ii) water–rock–gas interactions. To explain hydrochemical variations in the fracture water, the water–rock–gas interactions may be more important. For example, during flood periods, soil gas with high CO₂ concentrations dissolves in water and enters the fracture system, the water, which in turn has become more highly undersaturated, dissolves more limestone, and the conductivity increases. Dilution of rainfall is more important in controlling hydrochemical variations of conduit water, because rainfall with higher pH (in this area apparently owing to interaction with limestone dust in the lower atmosphere) and low conductivity travels through the conduit system rapidly. These results illustrate that to understand the hydrochemical variations in karst systems, considering only water–rock interactions is not sufficient, and the variable effects of CO₂ on the system should be evaluated. Consideration of water–rock–gas interactions is thus a must in understanding variations in karst hydrochemistry. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Consideration on the topographic control of a baroclinic ocean current     

Masahisa Kubota 《Journal of Oceanography》1978,34(6):307-309

The stability of ocean currents is considered using a two-layer model including the vertical shear in the geostrophic balance and bottom topography. Applying the results, the Kuroshio current along the bottom contour seems to be more stable than any other combination of the current direction and the bottom contour.  相似文献   

Influence of the seasonal thermocline on the intrusion of Kuroshio across the continental shelf northeast of Taiwan     

Ching-Sheng Chern  Joe Wang 《Journal of Oceanography》1994,50(6):691-711

The hydrographic surveys in an area immediately northeast of Taiwan showed that the Kuroshio surface water intruded onto the shelf in the spring and there was a thick mixed layer and weak vertical stratification in the Kuroshio at the time. During the summer season, a strong thermocline was developed in the Kuroshio and the flow shifted offshore from Taiwan in front of the continental shelf break of the East China Sea. A numerical model is used to examine the effect of this seasonal thermocline on the flow pattern of the survey area. We find that the surface strength of the disturbance above the Su-Ao ridge is closely related to the occurrence of the on-shelf intrusion of Kuroshio. The presence of a seasonal thermocline in the Kuroshio can greatly diminish this disturbance in the surface level.  相似文献   

Downstream transition of the Tsushima Current west of Kyushu in summer   总被引：1，自引：0，他引：1  

Osamu Katoh  Kazuyuki Teshima  Katsuhiko Kubota  Kazuo Tsukiyama 《Journal of Oceanography》1996,52(1):93-108

In order to clarify detailed current structures west of Kyushu, ADCP measurements were carried out in July and September 1990 by the quadrireciprocal method (Katoh, 1988) for removing diurnal and semidiurnal tidal flows from observed flows. On the basis of these results, together with data of routine oceanographic observations, we study the downstream transition of the Tsushima Current west of Kyushu in summer. In the southwest of the Goto Islands, a northward current identified as the Tsushima Current was clearly found. In the south of Cheju, a westward current bifurcated from the Tsushima Current. In the northwest of the Goto Islands, the Tsushima Current narrowed and its velocity became strengthened. Salinity of the Tsushima Current water was much diluted by a current from the Cheju Strait. Near the west coast of the Goto Islands, a countercurrent bifurcating from the Tsushima Current often occurred. The volume transport of the Tsushima Current was 2.3 Sv (1 Sv=10⁶ m³s^–1) on the northern side of latitude 31°N. The substantial bifurcation of the Tsushima Current toward the Eastern and Western Channels of the Tsushima Strait occurred in the vicinity of Tsushima. The volume transport through the Western Channel was two to three times larger than that through the Eastern Channel. The baroclinic component in volume transport of the Tsushima Current west of Kyushu was much smaller than that in the Japan Sea.  相似文献   

Continental shelf waves off the Fukushima coast     

Masahisa Kubota 《Journal of Oceanography》1985,41(2):105-112

Numerical experiments are performed on shelf waves forced by wind stress with a spectral peak around a period of 100 hr. Water depth in the numerical model is a function of offshore distance only and resembles a bathymetric profile off the Fukushima coast. A pair of vortices alined in the offshore direction and a large vortex are reproduced and they propagate southward outside the forced region. Judging from the propagation speed, the former corresponds to the second-mode and the latter to the first-mode shelf waves. In the forced region, the propagation speed of a trough and a ridge is slow, 3–5km hr^–1. These propagation characteristics reproduce those observed along the Fukushima coast and this propagation speed corresponds to that of second-and third-mode shelf waves. Thus, it is concluded that the periodical current fluctuations observed in the inshore region along the Fukushima coast are due to motions associated with the second-and third-mode shelf waves.  相似文献   

Continental shelf waves off the fukushima coast Part I: Observations     

Masahisa Kubota  Kisaburo Nakata  Yoshiharu Nakamura 《Journal of Oceanography》1981,37(5):267-278

Current records obtained in the inshore region along the Fukushima coast are analyzed. The existence of periodical current fluctuations whose period is about 100 hours and whose amplitude is as large as 15–25cm s^–1 is recognized. Auto-spectral analyses are made also for sea level, atmospheric pressure and wind records. Each spectrum has significant peaks at the similar period to the current spectrum. The wind spectrum has a broad peak compared with the current. The periodical current fluctuations propagate southward with speed of 3–5 km h^–1. These propagation speeds seem to correspond to those of the second-and third-mode shelf waves.  相似文献   

Yesterday's Freeway Network of Tomorrow          下载免费PDF全文

Joe Weber 《Geographical review》2016,106(1):54-71

In 1939, the Futurama exhibit at the New York World's Fair amazed visitors with its diorama showing futuristic freeways crossing the countryside and reshaping cities. After the fair, the exhibit's designer, Norman Bel Geddes, elaborated the model into a proposal for a national freeway network. This paper examines the network structure and geographic dimensions of Bel Geddes's vision and compares it to the Interstate Highway System, created several years later. Despite the futuristic trappings inherited from the Futurama model, the two networks are surprisingly similar except in their relation to cities, which Bel Geddes's network avoids. The majority of elements in Bel Geddes's system have been incorporated into actual routes and networks, and it can be expected that his system would have gone through many of the same adaptations to changing economic, environmental, and political circumstances as the Interstate Highway System.  相似文献   

Ti-in-zircon thermometry applied to contrasting Archean metamorphic and igneous systems     

Joe Hiess  Allen P. Nutman  Vickie C. Bennett  Peter Holden 《Chemical Geology》2008,247(3-4):323-338

Ti-in-zircon thermometry with SHRIMP II multi-collector has been applied to two well-documented Archean igneous and metamorphic samples from southern West Greenland. Zircons from 2.71 Ga partial melt segregation G03/38 formed in a small (< 1 m³), closed system within a mafic rock under high pressure granulite facies conditions. Results of 14 Ti analyses present a mean apparent zircon crystallization temperature of 679 ± 11 °C, underestimating independent garnet-clinopyroxene thermometry by 20–50 °C but consistent with reduced a_TiO2 in this system. 36 spot analysis on 15 zircons from 3.81 Ga meta-tonalite G97/18, with an estimated magmatic temperature > 1000 °C, yield a low-temperature focused normal distribution with a mean of 683 ± 32 °C, further demonstrated by high resolution Ti mapping of two individual grains. This distribution is interpreted to represent the temperature of the residual magma at zircon saturation, late in the crystallization history of the tonalite. Hypothetically, Ti-in-zircon thermometry on Eoarchaean detrital zircons sourced from such a high temperature tonalite would present a low-temperature biased image of the host magma, which could be misconstrued as being a minimum melt granite. Multiple analyses from individual zircons can yield complex Ti distributions and associated apparent temperature patterns, reflecting cooling history and local chemical environments in large magma chambers. In addition to inclusions and crystal imperfections, which can yield apparent high temperature anomalies, zircon surfaces can also record extreme (> 1000 °C) apparent Ti temperatures. In our studies these were traced to ⁴⁹Ti (or a molecular isobaric interference) contamination derived from the double sided adhesive tape used in sample preparation, and should not be assigned geological significance.  相似文献   

The stratigraphic and geographic distribution of giant craters and remobilised sediment mounds on the mid Norway margin,and their relation to long term fluid flow     

Gordon W.M. Lawrence  Joe A. Cartwright 《Marine and Petroleum Geology》2010,27(4):733-747

Large craters associated with mounds of remobilised sediment have been recently mapped on the mid Norway margin in the Møre Basin. These craters and mounds may be linked to the long term migration of fluids upwards from the lower levels of the Møre Basin which exploit hydrothermal vent complexes emplaced in the late Paleocene and early Eocene. All of the craters are located on a regionally correlative seismic surface that is correlated with the basal shear plane of Slide W, a slide located at the base of the Plio-Pleistocene Naust Formation. The Craters are positioned in the western area of the Møre Basin at the foot of the continental slope on the crests and flanks of Miocene domes, where Oligocene biosiliceous ooze subcrops on the basal shear surface of Slide W. Not all of the craters are filled by Slide W. Mounds are emplaced above those craters which are filled by Slide W on the top surface of Slide W. Stratal relationships show that the mounds were emplaced on the paleo-seabed. We present and discuss two models that illustrate processes that may have been involved in the formation of craters and remobilisation of sediments. In one model, an eruption of fluid from beneath remobilises ooze into ooze mounds in a single event triggering slope failure, whereas in the other model the emplacement of Slide W and later slides loads low density ooze causing it to undergo liquefaction, a process which may have been facilitated by the trapping of continuous long term fluid migrating from beneath, causing the ooze to remobilise into ooze mounds in two or more events.  相似文献