Pyrolysis gas chromatography-mass spectrometry to characterize organic matter and its relationship to uranium content of Appalachian Devonian black shales     

Joel S. Leventhal 《Geochimica et cosmochimica acta》1981,45(6):883-889

Gas Chromatographic analysis of volatile products formed by stepwise pyrolysis of black shales can be used to characterize the kerogen by relating it to separated, identified precursors such as land-derived vitrinite and marine-source Tasmanites. Analysis of a Tasmanites sample shows exclusively $\text{n-}\text{alkane}$ and -alkene pyrolysis products, whereas a vitrinite sample shows a predominance of one- and two-ring substituted aromatics. For core samples from northern Tennessee and for a suite of outcrop samples from eastern Kentucky, the organic matter type and the U content (<10?120ppm) show variations that are related to precursor organic materials. The samples that show a high vitrinite component in their pyrolysis products are also those samples with high contents of U.  相似文献   

Chlorinated cooling waters in the marine environment: Development of effluent guidelines     

Judith M. Capuzzo  Joel C. Goldman  John A. Davidson  Sarah A. Lawrence 《Marine pollution bulletin》1977,8(7):161-163

The effects of free chlorine and chloramine on stage I lobster larvae and juvenile killifish were investigated in continuous flow bioassay units. In comparing mortality and changes in standard respiration rates during and after exposure to either chlorine form, significant respiratory stress was observed with exposure to sublethal levels. Sublethal responses to free and combined chlorine should be considered when establishing regulations for chlorine residuals in cooling waters.  相似文献   

The roughness of the dark side of Iapetus from the 2004 to 2005 flyby     

Janice S. Lee  Bonnie J. Buratti  Joel Mosher 《Icarus》2010,206(2):623-630

The roughness of a planetary surface offers clues to its past geologic history. We apply a surface roughness model developed by Buratti and Veverka (Buratti, B.J., Veverka, J. [1985]. Icarus 64, 320-328) to Cassini ISS data from the January 1st, 2005 flyby of Iapetus. This model uses the observed scattering behavior to provide a depth to radius factor q quantifying the size of idealized craters on the surface. Our findings indicate that the surface on the dark side is significantly smoother than the surfaces of other icy low-albedo saturnian satellites. We have found that the average depth to radius on the leading (dark) side is 0.084, corresponding to a Hapke mean slope angle of 6°. As compared to the 13-33° Hapke mean slope angle of other icy satellites (Buratti, B.J., and 10 colleagues [2008]. Icarus 193, 309-322), our results present a clearly different picture for the leading surface of Iapetus, suggesting that the dark deposit contributes to the decrease in macroscopic surface roughness of the leading side. Attempts were made to obtain an average depth to radius value for the trailing (bright) side; however the scans of the bright side from this flyby exhibited large variations in albedo, resulting in results that were physically unrealistic.  相似文献   

An in situ XAS study of copper(I) transport as hydrosulfide complexes in hydrothermal solutions (25-592 °C, 180-600 bar): Speciation and solubility in vapor and liquid phases     

B.E. Etschmann  W. Liu  H. Müller  O. Proux  J. Brugger 《Geochimica et cosmochimica acta》2010,74(16):4723-2827

Chloride and hydrosulfide are the principal ligands assumed to govern transport of copper in hydrothermal fluids. Existing solubility experiments suggest that Cu(I)-hydrosulfide complexes are dominant compared to chloride complexes at low salinities in alkaline solutions (H₂S_(aq)/HS⁻ pH buffer), and may be important in transporting Cu in low density magmatic vapors, potentially controlling the liquid-vapor partitioning of Cu. This study provides the first in situ evidence of the solubility of copper sulfides and the nature and structure of the predominant Cu species in sulfur-containing fluids at temperatures up to 592 °C and pressures of 180-600 bar. XANES and EXAFS data show that at elevated T (?200 °C), Cu solubility occurs via a linear Cu complex. At 428 °C in alkaline solutions, Cu is coordinated by two sulfur atoms in a distorted linear coordination (angle ∼150-160°). This geometry is consistent with the species predicted by earlier solubility studies. In addition, in situ measurements of the solubility of chalcocite in 2 m NaHS solutions performed in this study are in remarkably good agreement with the solubilities calculated using available thermodynamic data for Cu(I)-hydrosulfide complexes, also supporting the interpretation of speciation in these studies and validating the extrapolation of low-T thermodynamic properties for to high P-T. Data on phase separation for the 2 m NaHS solution show that while significant amounts of copper can be partitioned into the vapor phase, there is no indication for preferential partitioning of Cu into the vapor. This is consistent with recent partitioning experiments conducted in autoclaves by Pokrovski et al. (2008a) and Simon et al. (2006). XANES data suggest that the species present in the low density phase is very similar to that present in the high density liquid, i.e., , although Cu(HS)(H₂S)⁰ cannot be excluded on the basis of XAS data.  相似文献   

When seed fails: The contested nature of neoliberalism in South Korea     

Sook-Jin Kim  Joel Wainwright 《Geoforum》2010,41(5):723-733

In recent years, many geographers have examined the ways that the production of nature has changed as a result of neoliberal practices. In this paper we examine a conflict in South Korea that started when some Chinese-cabbage seeds were affected by a virus, causing crop failure. This failure came shortly after liberalization in the Korean seed industry led to foreign ownership of the firm that sold the seed. We focus in particular on the farmers’ creative political responses - and their subsequent defeat in court. Drawing on Antonio Gramsci’s insights on politics, science, and law, we examine how the seed failure came to be evaluated through scientific and legal practices. We argue that the adjudication of the truth of the seed failure through science and law reveals how socionatures are contested under prevailing hegemonic conditions. These conditions are both general and specific: although law and science are relatively hegemonic spheres of truth-production in all capitalist societies, the ways that the seeds were disputed and evaluated were distinctly Korean.  相似文献   

A major element,PGE and Re–Os isotope study of Middle Atlas (Morocco) peridotite xenoliths: Evidence for coupled introduction of metasomatic sulphides and clinopyroxene     

Nadine Wittig  D. Graham Pearson  Joel A. Baker  Svend Duggen  Kaj Hoernle 《Lithos》2010,115(1-4):15-26

We present major element and PGE (platinum-group-element) abundances in addition to Re–Os isotope data for 11 spinel-facies whole rock peridotites from a single maar from the Middle Atlas Mountains, Morocco.Major element systematics of these xenoliths are generally correlated with indices of depletion. FeO–MgO systematics appear to suggest spinel-facies melting in the range of 5 to 25%. However, Al₂O₃ abundances in these xenoliths appear elevated relative to primitive mantle (Prima). The Al₂O₃ abundances in conjunction with other major elements require distinct re-enrichment of the Middle Atlas continental mantle root due to melt/rock reaction and precipitation of amphibole and/or clinopyroxene from passing silicate melts akin to MORB or OIB that evolved in reverse direction along the melting curves in e.g. FeO–MgO space. Sc and V confirm the range of apparent depletion and also indicate that the currently preserved fO₂ in these peridotites is distinctly different from fO₂ conditions observed in subduction zones.The majority of these xenoliths have low Os and Ir (I-PGEs) concentrations relative to Prima and modelled sulphide- and clinopyroxene-depleted residues of mantle melting under low fO₂, mid-ocean ridge-like conditions. Moreover, Pt and Pd (P-PGE) abundances are elevated when compared to their expected abundances after substantial melt extraction. Importantly, the systematically low Ir abundances in the majority of samples show well-correlated trends with Al₂O₃, MgO and Cu that are inconsistent with established melting trends. Os isotopes in the Middle Atlas xenoliths range from ¹⁸⁷Os/¹⁸⁸Os = 0.11604 to 0.12664 although most samples are close to chondritic. The Os isotope ratios are decoupled from ¹⁸⁷Re/¹⁸⁸Os but, together with Re abundances, also exhibit a good correlation with Al₂O₃, MgO and Cu.The major element, I-PGE and Os isotope correlations suggest that the initial melt depletion led to the exhaustion of sulphide and clinopyroxene (20 to 30%) without significant stabilization of I-PGE-rich alloys. During later modal metasomatism of the refractory Middle Atlas continental mantle root with silicate melts akin to MORB or OIB the introduction of clinopyroxene/amphibole reduced the volume of the melt inducing sulphur saturation in these melts causing precipitation of secondary sulphides. This coupled crystallization of pyroxenes and sulphides (chalcopyrite) resulted in the two-component mixing systematics exhibited by I-PGEs, Os isotopes with major elements and Cu preserved in the Middle Atlas continental mantle root.  相似文献   

Propagation of vertical and horizontal source data errors into a TIN with linear interpolation   总被引：1，自引：0，他引：1  

Lei Fan  Joel Smethurst  Peter Atkinson  William Powrie 《International journal of geographical information science》2014,28(7):1378-1400

Digital elevation models (DEMs) have been widely used for a range of applications and form the basis of many GIS-related tasks. An essential aspect of a DEM is its accuracy, which depends on a variety of factors, such as source data quality, interpolation methods, data sampling density and the surface topographical characteristics. In recent years, point measurements acquired directly from land surveying such as differential global positioning system and light detection and ranging have become increasingly popular. These topographical data points can be used as the source data for the creation of DEMs at a local or regional scale. The errors in point measurements can be estimated in some cases. The focus of this article is on how the errors in the source data propagate into DEMs. The interpolation method considered is a triangulated irregular network (TIN) with linear interpolation. Both horizontal and vertical errors in source data points are considered in this study. An analytical method is derived for the error propagation into any particular point of interest within a TIN model. The solution is validated using Monte Carlo simulations and survey data obtained from a terrestrial laser scanner.  相似文献   

Terrain-influenced local wind forecasting for the Sasebo typhoon haven: Improved empirical techniques     

Joel W. Feldmeier  Wendell A. Nuss  Russell L. Elsberry 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(4):459-468

Although the Sasebo, Japan harbor is usually a “typhoon haven” from tropical cyclone (TC) winds due to terrain-blocking effects, in rare cases damaging winds occur that may be attributed to terrain channeling. An empirical parametric model technique is developed and tested that includes consideration of the TC wind structure, land frictional effects, and terrain influences affecting the maximum wind speeds in the harbor when TCs pass within 200 nautical miles of Sasebo. The terrain influence is represented by two sets of wind direction-dependent acceleration factors. The first set, which is directly from the ratio of the local wind to the adjusted parametric wind for TCs passages during 2003–2010, provides mean values that represent the terrain blocking and channeling effects, but the variability with wind direction may be suspect. The second set derived from a large sample of reanalysis winds not limited to TCs has better variability properties, but is not easily related to just the TC passages. A new nomogram modified to include TC wind structure has higher estimates of Sasebo sustained winds for some TC tracks that may be related to terrain influences, but is limited due to the number of TC structure estimates in the developmental sample. These empirical models have the advantage of ease and low cost for future use in also estimating the combined uncertainty in the local winds in Sasebo harbor due to TCs.  相似文献   

Improvement of distributed snowmelt energy balance modeling with MODIS‐based NDSI‐derived fractional snow‐covered area data     

Joel W. Homan  Charles H. Luce  James P. McNamara  Nancy F. Glenn 《水文研究》2011,25(4):650-660

Describing the spatial variability of heterogeneous snowpacks at a watershed or mountain‐front scale is important for improvements in large‐scale snowmelt modelling. Snowmelt depletion curves, which relate fractional decreases in snow‐covered area (SCA) against normalized decreases in snow water equivalent (SWE), are a common approach to scale‐up snowmelt models. Unfortunately, the kinds of ground‐based observations that are used to develop depletion curves are expensive to gather and impractical for large areas. We describe an approach incorporating remotely sensed fractional SCA (FSCA) data with coinciding daily snowmelt SWE outputs during ablation to quantify the shape of a depletion curve. We joined melt estimates from the Utah Energy Balance Snow Accumulation and Melt Model (UEB) with FSCA data calculated from a normalized difference snow index snow algorithm using NASA's moderate resolution imaging spectroradiometer (MODIS) visible (0·545–0·565 µm) and shortwave infrared (1·628–1·652 µm) reflectance data. We tested the approach at three 500 m² study sites, one in central Idaho and the other two on the North Slope in the Alaskan arctic. The UEB‐MODIS‐derived depletion curves were evaluated against depletion curves derived from ground‐based snow surveys. Comparisons showed strong agreement between the independent estimates. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

The art of adaptation: Living with climate change in the rural American Southwest     

Julie Brugger  Michael Crimmins 《Global Environmental Change》2013,23(6):1830-1840

As adaptation has come to the forefront in climate change discourse, research, and policy, it is crucial to consider the effects of how we interpret the concept. This paper draws attention to the need for interpretations that foster policies and institutions with the breadth and flexibility to recognize and support a wide range of locally relevant adaptation strategies. Social scientists have argued that, in practice, the standard definition of adaptation tends to prioritize economic over other values and technical over social responses, draw attention away from underlying causes of vulnerability and from the broader context in which adaptive responses take place, and exclude discussions of inequality, justice, and transformation. In this paper, we discuss an alternate understanding of adaptation, which we label “living with climate change,” that emerged from an ethnographic study of how rural residents of the U.S. Southwest understand, respond to, and plan for weather and climate in their daily lives, and we consider how it might inform efforts to develop a more comprehensive definition. The discussion brings into focus several underlying features of this lay conception of adaptation, which are crucial for understanding how adaptation actually unfolds on the ground: an ontology based on nature–society mutuality; an epistemology based on situated knowledge; practice based on performatively adjusting human activities to a dynamic biophysical and social environment; and a placed-based system of values. We suggest that these features help point the way toward a more comprehensive understanding of climate change adaptation, and one more fully informed by the understanding that we are living in the Anthropocene.  相似文献