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981.
The Junggar Basin in NW China contains lacustrine hydrocarbon source rocks which are among the highest quality of hydrocarbon potential in the world. Oil reservoirs in the basin are very substantial: target reservoirs span Carboniferous to Tertiary strata and include Permo-Triassic lacustrine and fluvial sandstones. The Junggar Basin was a foreland basin during the late Permian to Cenozoic, possibly with strike-slip tectonics at the southern margin during Mesozoic time. The Cangfanggou Group, as one of the major reservoirs, is well-exposed in the eastern part of the southern Junggar Basin. A measured outcrop section and a number of borehole logs coupled with resistivity logs were used to attempt sequence stratigraphic analysis. Detailed sedimentological studies on the outcrops and borehole cores have demonstrated that the Cangfanggou Group is characterized by alternating lacustrine and fluvial deposits. Four depositional sequences have been recognized. For each sequence, the basal boundary is marked by erosional truncation of fluvial channel conglomeratic sandstones in sharp contact with underlying lacustrine or floodplain mudstones. The top of each lowstand systems tract is normally overlain by the transition to lacustrine or maximum flooding surface. The transgressive systems tract is normally not identifiable at the basin margin, but was developed in the basinward area and characterized by interbedded fining-upward distal fluvial and shallow lacustrine deposits. The highstand systems tract at the basin margin is characterized by very thick floodplain mudstones or shallow lacustrine deposits, and by typical coarsening-upward parasequences of shallow lacustrine deposits in more basinward areas. Sediment input to the basin was controlled by tectonics and climate. Depositional sequences were probably controlled by fluctuating change of lake level: this was in turn controlled by climate (runoff), modified by tectonics in specific areas.The sandstones studied are exclusively volcanic litharenites. Diagenetic studies suggest that the calcite cementation, pore-filling clay minerals and zeolites occluded substantial porosity in the sandstones examined because they are compositionally immature. However, notable secondary porosity in varying proportions is present in the sandstones of the Cangfanggou Group, resulting from the dissolution of unstable detrital grains. The lowstand fluvial/distal fluvial sandstones recorded the highest average porosity and highest permeability, in which some primary porosity may remain because early formed clay coatings inhibited further compaction. The combination of residual primary porosity and significant amount of secondary porosity in the sandstones of the Cangfanggou Group may constitute moderate to good reservoirs. In contrast, the lacustrine fine-grained sandstones is characterized by clay authigenesis and zeolitization, in which the porosity was obliterated by the zeolites and extensive illitization; the lowstand fluvial channel sandstones in the basin margin areas are characterized by extensive calcite cementation which greatly reduced the porosity and permeability.This is the fifth paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.  相似文献   
982.
Summary A model of the polluted arctic troposphere is constructed to estimate the magnitude and seasonal variation of the climate forcing function of arctic haze. Using a pill-box bathtub model for the Arctic and envisioning it to be filled with pollution from industrial sources in Eurasia, we estimate that maximum climate perturbation from arctic contamination occurs in the spring months. The major perturbation to the radiation budget is a lowering of the albedo (heating) of the earth-atmosphere system around the vernal equinox and is due to a trace amount (about 5% by mass) of black carbon associated with the removal-resistant submicron mode of aerosols. The black carbon over the reflecting polar ice/snow introduces a heating of about 1.5 degree per day into the haze layer.With 8 Figures  相似文献   
983.
Summary Hourly measurements of solar irradiance in the wave band excluding photosynthetically active radiation (PAR) and solar irradiance (SI) were made over a 12-month period at the National Observatory of Athens, for obtaining the ratios of PAR to SI. These irradiance ratios exhibit dependence on sky conditions, with slightly larger values being observed under cloudy skies and seasonal variations, attributable to changes in local air mass climatology. The highest values have been obtained during the growing season (April–September). The mean annual value of 0.473 observed for the irradiance ratio in the PAR band compares favorably with values reported in the literature for different locations over a wide geographical area.With 2 Figures  相似文献   
984.
The abundance and 13C/12C ratios of carbon were analyzed in basaltic glass from twenty locations along the Juan de Fuca Ridge using a 3-step combustion/extraction technique. Carbon released during the first two combustion steps at 400-500 degrees C and 600-650 degrees C is interpreted to be secondary, and only the carbon recovered during a final combustion step at approximately 1200 degrees C is thought to be indigenous to the samples. For carbon released at approximately 1200 degrees C, glasses analyzed as 1-2 mm chips contained 23-146 ppm C with delta 13C values of -4.8 to -9.3%, whereas samples crushed to 38-63 microns or 63-90 microns yielded 56-103 ppm C with delta 13C values of -6.1 to -9.2%. The concentrations and isotopic compositions of the primary carbon dissolved in the glasses and present in the vesicles are similar to those previously reported for other ocean-ridge basalts. The Juan de Fuca basaltic magmas were not in equilibrium with respect to carbon when they erupted and quenched on the sea floor. Evidence of disequilibrium includes (1) a large range of carbon contents among glasses collected at similar depths, (2) a highly variable calculated carbon isotopic fractionation between melt and vapor determined by comparing crushed and uncrushed splits of the same sample, and (3) a lack of correlation between vesicle abundance, carbon concentration, and depth of eruption. Variations in carbon concentration and delta 13C ratios along the ridge do not correlate with major element chemistry. The observed relationship between carbon concentrations and delta 13C values may be explained by late-stage, variable degrees of open-system (Rayleigh-like) degassing.  相似文献   
985.
Three types of enrichment processes may be distinguished inspinel peridotite mantle xenoliths from the West Eifel (Germany):
  1. Enrichmentof light rare earth elements (LREE) occurs in wholerocks andclinopyroxenes in conjunction with the formation ofTi-pooramphiboles (<0•5%) in a low-tempetature suite(900C).
  2. Enrichment in high field strength elements (HFSE; Ti and Hf)is associated with strong zoning of TiO2 in amphibole adjacentto mica hornblendite veins. A reheating from 900 to 1050C associatedwith this vein formation is reflected by the zoning profilesin orthopyroxenes with Ca, Al, and Cr increasing from core torim.
  3. Moderate enrichment of LREE without amphibole formationin ahigh-temperature suite (1125C) is observed at the contactofperidotites to pyroxenite veins yielding the same temperature.
  4. Based on geochemical and isotopic evidence, enrichment process(1) is inferred to be due to interaction of peridotites fromthe subcrustal lithosphere with low-density fluids. Process(2) represents a subsequent interaction of amphibole-bearingperidotites formed during the first process with basic meltsmoving through a system of cross-cutting dykes and veins. Processes(2) and (3) are linked to the Quaternary West Eifel volcanism.Geothermobarometry of the xenoliths shows that these processesare related to different depth regimes of the lower lithosphere.
  相似文献   
986.
Mafic hypabyssal rocks in the western Triassic and Paleozoicbelt provide important clues to the nature of accretion andarc evolution along this sector of the North American margin.In the east-central part of the belt, near Sawyers Bar, somediabases have been metamorphosed before and accompanying emplacementof the mid-Jurassic English Peak and Russian Peak granitoidswithin the North Fork/Salmon River + Stuart Fork amalgamatedterrane. Certain other dikes/sills, chiefly mafic microdiorites,cut the calc-alkaline plutons but are themselves deutericallyaltered; at least two of these mafic microdiorites near theEnglish Peak body possess hornfelsic textures. Thus, althoughmost mafic microdioritic hypabyssals seem to have been injectedafter granitoid emplacement, a few must have preceded plutonicintrusion. Macroscopic appearances, phase assemblages, mineralcompositions, and textures of the mafic microdioritic and metadiabasicdikes/sills are sufficiently alike to preclude the ready fieldand petrographic distinction of the different magma series.Bulk-rock chemistries fall into two groups, however, with slightlymore porphyritic, altered, synplutonic mafic microdiorite samplesbeing distinctly richer in Si, K, P, Rb, Sr, Zr, and light rareearth elements (LREE) relative to the Mg + Cr + Ni-rich, preplutonicmetadiabases. Analyzed mafic microdiorites have bulk-rock chemicaland isotopic compositions similar to the more ferromagnesianportions of the mid-Jurassic English Peak and Russian Peak plutoniccomplexes, whereas the metadiabases are comparable with theearly Mesozoic Salmon River metabasalts. Although the two groupsof dikes/sills probably overlap in age of emplacement, the maficmicrodiorite group is predominantly younger and uniform in oxygenisotopic composition (bulk-rock 18O 11•37, 11•4 and11•46) compared with the older, more intensely metamorphosed,and variably metasomatized Salmon River metadiabases (bulk-rock518 9•4, 11•0, and 15•3). Both types of maficdike/sill locally intrude the more easterly Stuart Fork terrane.Therefore, suturing and regional metamorphism of the outboardNorth Fork/Salmon River oceanic-island arc and inboard StuartFork subduction complex must have occurred during terminal stagesof injection of the pregranitoid diabases into the North Fork(oceanic-island basalts)/Salmon River (island-arc tholeiites)arc + Stuart Fork terrane, but before invasion of the amalgamatedterrane assembly by the calc-alkaline plutons and most compositionallyrelated synplutonic mafic microdiorite dikes/sills. Becauseof their lateral continuation both north and south of the SawyersBar area, the North Fork/Salmon River igneous suite documentsthe construction of an oceanic arc of considerable lateral extentin the central Klamaths before terrane accretion. Suturing wasimmediately followed by the mid-Jurassic intrusion of calc-alkalineplutons + syngranitoid mafic microdioritic hypabyssals.  相似文献   
987.
Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.  相似文献   
988.
The solid solution sanmartinite (ZnWO4)—cuproscheelite (CuWO4) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L3 absorption peak is observed for CuWO4, two distinct L3 absorption peaks with a separation of ~0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO6 next nearest neighbours in the (Cu,Zn)O6 chains, another having at least one ZnO6 next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO4) to P $\bar 1$ (CuWO4). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.  相似文献   
989.
We present new elasticity measurements on single-crystal fayalite and combine our results with other data from resonance, pulse superposition interferometry, and Brillouin scattering to provide a set of recommended values for the adiabatic elastic moduliC ij and their temperature variations. We use a resonance method (RPR) with specimens that were previously investigated by pulse superposition experiments. The nineC ij of fayalite are determined from three new sets of measurements. One set of our newC ij data is over the range 300–500 K. We believe that the relatively large discrep ncies found in someC ij are due in large part to specimen inhomogeneities (chemical and microstructural) coupled with differences in the way various techniques sample, rather than only systematic errors associated with experimental procedures or in the preparations of the specimens.Our recommendeaC ij's (GPa) and (C ij/T) p (GPa/K) are: The resulting values for the isotropic bulk and shear moduli,K s and , and their temperature derivatives are:K s=134(4) GPa; =50.7(0.3) GPa; (K s/T) p =–0.024(0.005) GPa/K; and (/T) p =–0.013(0.001) GPa/K. An important conclusion is thatK s increases as the Fe/(Fe+Mg) ratio in olivine is increased.  相似文献   
990.
Field measurements of wind, air temperature and humidity were taken at the eastern part of the Attika district in June 1991, to examine the topographic influences exerted on the local sea breezes. These influences are due either to the elongated Evia island, faced by the northern half of Attica coastline some tens of kilometers offshore, or to the coast-parallel range of Hymettos mountain, rising steeply 12 km onshore. The instrumentation consisted mainly of three tethered meteorological balloons released at characteristic sires (i.e., the coast, a location between shoreline and mountain foot and the mountain top) and three autographic ground-based anemometers operating at selected locations. Data from the ground-based and upper air stations of the Hellenic National Meteorological Service, as well as the diurnal weather maps were also obtained and analyzed. Observations were made under different synoptic wind and the latter was found to determine remarkably the significance of the topographic effects. A preliminary two-dimensional numerical approach was also made concerning the sea breeze capability to reach the Hymettos mountain top in the case of a weak opposing geostrophic flow.  相似文献   
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