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161.
In order to evaluate rates of tectonometamorphic processes, growth rates of garnets from metamorphic rocks of the Tauern Window, Eastern Alps were measured using Rb-Sr isotopes. The garnet growth rates were determined from Rb-Sr isotopic zonation of single garnet crystals and the Rb-Sr isotopic compositions of their associated rock matrices. Garnets were analyzed from the Upper Schieferhülle (USH) and Lower Schieferhülle, (LSH) within the Tauern Window. Two garnets from the USH grew at rates of 0.67 –0.13 +0.19 mm/million years and 0.88 –0.19 +0.34 mm/million years, respectively, indicating an average growth duration of 5.4±1.7 million years. The duration of growth coupled with the amount of rotation recorded by inclusion trails in the USH garnets yields an average shear-strain rate during garnet growth of 2.7 –0.7 +1.2 ×10-14 s-1. Garnet growth in the sample from the USH occurred between 35.4±0.6 and 30±0.8 Ma. The garnet from the LSH grew at a rate of 0.23±0.015 mm/million years between 62±1.5 Ma and 30.2±1.5 Ma. Contemporaneous cessation of garnet growth in both units at 30 Ma is in accord with previous dating of the thermal peak of metamorphism in the Tauern Window. Correlation with previously published pressure-temperature paths for garnets from the USH and LSH yields approximate rates of burial, exhumation and heating during garnet growth. Assuming that theseP — T paths are applicable to the garnets in this study, the contemporaneous exhumation rates recorded by garnet in the USH and LSH were approximately 4 –2 +3 mm/year and 2±1 mm/year, respectively.  相似文献   
162.
This article is the first in a series designed to gain insight into the stellar oscillation problem from a somewhat novel point of view: that of potential scattering, well-known in the quantum mechanical literature. In this paper the known theoretical foundations are developed and applied in the context of the astrophysical problem, wherein the star itself (rather than any portion of it) is the potential which scatters waves and traps them. The basis for the identification of a precisely defined scattering problem is the existence of a linear Schrödinger equation associated both globally (Section 2) and locally (Section 8) with the nonlinear eigenvalue equation for nonradial stellar pulsations. The paper is also designed to be a fairly complete account of the relevant mathematical topics that are germane to a study of this kind. This paper is dedicated to the memory of Professor Zdenèk Kopal, who was a great source of professional encouragement to me during the last fifteen years of his life.  相似文献   
163.
Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)UNK | (001)mel and <10T0>UNK | <100>mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca3TiAl2Si3O14 and Ca3Ti(AlTi)(AlSi2)O14. A Ti-free analog with a formula of Ca3Al2Si4O14 synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is   相似文献   
164.
The Junggar Basin in NW China contains lacustrine hydrocarbon source rocks which are among the highest quality of hydrocarbon potential in the world. Oil reservoirs in the basin are very substantial: target reservoirs span Carboniferous to Tertiary strata and include Permo-Triassic lacustrine and fluvial sandstones. The Junggar Basin was a foreland basin during the late Permian to Cenozoic, possibly with strike-slip tectonics at the southern margin during Mesozoic time. The Cangfanggou Group, as one of the major reservoirs, is well-exposed in the eastern part of the southern Junggar Basin. A measured outcrop section and a number of borehole logs coupled with resistivity logs were used to attempt sequence stratigraphic analysis. Detailed sedimentological studies on the outcrops and borehole cores have demonstrated that the Cangfanggou Group is characterized by alternating lacustrine and fluvial deposits. Four depositional sequences have been recognized. For each sequence, the basal boundary is marked by erosional truncation of fluvial channel conglomeratic sandstones in sharp contact with underlying lacustrine or floodplain mudstones. The top of each lowstand systems tract is normally overlain by the transition to lacustrine or maximum flooding surface. The transgressive systems tract is normally not identifiable at the basin margin, but was developed in the basinward area and characterized by interbedded fining-upward distal fluvial and shallow lacustrine deposits. The highstand systems tract at the basin margin is characterized by very thick floodplain mudstones or shallow lacustrine deposits, and by typical coarsening-upward parasequences of shallow lacustrine deposits in more basinward areas. Sediment input to the basin was controlled by tectonics and climate. Depositional sequences were probably controlled by fluctuating change of lake level: this was in turn controlled by climate (runoff), modified by tectonics in specific areas.The sandstones studied are exclusively volcanic litharenites. Diagenetic studies suggest that the calcite cementation, pore-filling clay minerals and zeolites occluded substantial porosity in the sandstones examined because they are compositionally immature. However, notable secondary porosity in varying proportions is present in the sandstones of the Cangfanggou Group, resulting from the dissolution of unstable detrital grains. The lowstand fluvial/distal fluvial sandstones recorded the highest average porosity and highest permeability, in which some primary porosity may remain because early formed clay coatings inhibited further compaction. The combination of residual primary porosity and significant amount of secondary porosity in the sandstones of the Cangfanggou Group may constitute moderate to good reservoirs. In contrast, the lacustrine fine-grained sandstones is characterized by clay authigenesis and zeolitization, in which the porosity was obliterated by the zeolites and extensive illitization; the lowstand fluvial channel sandstones in the basin margin areas are characterized by extensive calcite cementation which greatly reduced the porosity and permeability.This is the fifth paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.  相似文献   
165.
This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of 137Cs, 134Cs and 241Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the 210Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm-2 yr-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm-2 yr-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.  相似文献   
166.
A mapping model is constructed to describe asteroid motion near the 3 : 1 mean motion resonance with Jupiter, in the plane. The topology of the phase space of this mapping coincides with that of the real system, which is considered to be the elliptic restricted three body problem with the Sun and Jupiter as primaries. This model is valid for all values of the eccentricity. This is achieved by the introduction of a correcting term to the averaged Hamiltonian which is valid for small values of the ecentricity.We start with a two dimensional mapping which represents the circular restricted three body problem. This provides the basic framework for the complete model, but cannot explain the generation of a gap in the distribution of the asteroids at this resonance. The next approximation is a four dimensional mapping, corresponding to the elliptic restricted problem. It is found that chaotic regions exist near the 3 : 1 resonance, due to the interaction between the two degrees of freedom, for initial conditions close to a critical curve of the circular model. As a consequence of the chaotic motion, the eccentricity of the asteroid jumps to high values and close encounters with Mars and even Earth may occur, thus generating a gap. It is found that the generation of chaos depends also on the phase (i.e. the angles andv) and as a consequence, there exist islands of ordered motion inside the sea of chaotic motion near the 3 : 1 resonance. Thus, the model of the elliptic restricted three body problem cannot explain completely the generation of a gap, although the density in the distribution of the asteroids will be much less than far from the resonance. Finally, we take into account the effect of the gravitational attraction of Saturn on Jupiter's orbit, and in particular the variation of the eccentricity and the argument of perihelion. This generates a mixing of the phases and as a consequence the whole phase space near the 3 : 1 resonance becomes chaotic. This chaotic zone is in good agreement with the observations.  相似文献   
167.
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169.
Post-depositional mobility of137Cs,239+240Pu and210Pb was assessed in six small lake basins by comparing sedimentary nuclide profiles with their known fallout history. Laminae couplets, when present, were determined to be varves because the137Cs and239+240Pu 1963 fallout peaks are present in laminae couplets corresponding to years 1962–1964. There is no evidence of mobility of210Pb, because 1) mass accumulation rates based on210Pb agree with those based on137Cs and239+240Pu peak depths and with those based on varve counts, and 2)210Pb ages agree with varve ages. Significant mobility of137Cs is evident from the penetration of137Cs to depths 15–20 cm deeper than239+240Pu. Deep penetration of137Cs in spite of a sharp gradient below the peak is interpreted by a numerical model to suggest that137Cs is present in two distinct forms in these sediments, 67–82% as an immobile form and 18–33% reversibly adsorbed with a K d of approximately 5000. The profiles can be interpreted equally well assuming a small portionof the total137Cs was present as an extremely mobile phase (K d 5000) in the months to years following peak fallout, slowly becoming more strongly adsorbed. High NH 4 + concentrations in porewaters may enhance diffusion of the mobile form of137Cs, but not of the immobile form of137Cs that defines the sharp gradient. Mobility of137Cs is likely also enhanced by the low clay content and the high porosity of these sediments. Thus the first detection of137Cs in the sediments cannot automatically be assumed to correspond to a date of 1952 (initial testing of thermonuclear weapons), although the depth of the peak can be assumed to correspond to 1963 (the year of maximum fallout from testing of thermonuclear weapons).239+240Pu is a more reliable sediment chronometer than137Cs because it is significantly less mobile.This is the sixth of a series of papers to be published by this journal following the 20 th anniversary of the first application of210Pb dating of lake sediments. Dr P.G. Appleby is guest editing this series.  相似文献   
170.
Chemical equilibrium calculations on the stability of pure and dissolved graphite and cohenite (Fe3C), several other carbides, and several carbonates have been carried out for a system with solar elemental abundances over a very wide range of temperature and pressure. The calculated abundances of condensed carbon compounds are similar to the observed inventories on Earth and Venus, but fully 10 times smaller than the minimum carbon abundance found in ordinary chondrites. The total carbon content of most iron meteorites is compatible with their origin as a cooling FeNiCSP solution which was saturated with dissolved carbon at the solidus, such as would be produced by melting an ordinary chondrite, not by direct condensation from or equilibrium with the primitive solar nebula. It is argued that the carbon content of Mars need not be appreciably greater than that of the Earth. Material with even lower formation temperatures than Mars, such as the primitive material in the asteroid belt, may retain substantially more carbon as disequilibrium polymeric organic matter, possibly by the Fischer-Tropsch mechanism favored by Anders. Carbonates are not found as equilibrium products in a solar-composition system, and are probably secondary alteration products. CaCO3 might, however, persist in a solar-composition gas at temperatures below 460°K and pressures below 10?6.6 bar. The most stable condensed carbon compounds are found to be graphite, Fe3C, and possibly TiC, all in solid solution in the metal phase.  相似文献   
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