Mercury in sediments of Ulhas estuary   总被引：5，自引：0，他引：5  

Ram A  Rokade MA  Borole DV  Zingde MD 《Marine pollution bulletin》2003,46(7):846-857

Hg levels in water, suspended particulate matter and sediment of the Ulhas estuary are under considerable environmental stress due to the indiscriminate release of effluents from a variety of industries including chlor-alkali plants. Concentration ranges of dissolved (0.04-0.61 micro gl(-1)) and particulate (1.13-6.43 micro gg(-1)) Hg reveal a definite enhancement of levels in the estuary. The Hg burden in sediment upstream of the weir that limits the tidal influence is low (0.08-0.19 micro gg(-1)) with low C(org) content (1.8-2.9%). The high Hg content of the sediment just below the weir varies seasonally (highest concentration recorded being 38.45 micro gg(-1)) due to incremental accretion of sediment as the fresh water flow over the weir progressively decreases. The 30 km segment of the estuary sustains markedly high levels of Hg in the sediment with an exponential decrease in the seaward direction from the weir. Higher concentrations than the expected background prevail in all the estuarine cores up to the bottom, though the overall concentration decreases from about 20 micro gg(-1) in core 7 (inner estuary) to 1 micro gg(-1) in core 31 (outer estuary). The Hg in sediment is associated with C(org), while its correlation with Al, Fe and Mn is poor. The Hg profiles in cores from the Arabian Sea (stations 34, 35 and 37) have a distinct horizon of enhanced concentration in the 5-60 cm segment. Based on 210Pb dating of core 37, the sediment at the bottom of this core is inferred to have been deposited in the year 1949, roughly two year prior to the establishment of the first chlor-alkali plant and represents the background (0.06-0.10 micro gg(-1)). The Hg profiles in the offshore cores indicate a marked increase in transfer of Hg to sediment subsequent to 1980, with a peak around 1990-1992. Based on the index of geoaccumulation it is considered that the estuarine segment between stations 4 and 23 is extremely polluted, while the sediment from the open coast is moderately polluted in the top 25-30 cm with respect to Hg. The enrichment factor of Hg in the sediment is 350-700 for core 4 and decreases to 0-7 for the open-shore cores.  相似文献   

Stable isotope (C,O, S) systematics of the mercury mineralization at Idrija,Slovenia: constraints on fluid source and alteration processes     

Jo?t?V.?Lavri?Email author  Jorge?E.?Spangenberg 《Mineralium Deposita》2003,38(7):886-899

The world-class Idrija mercury deposit (western Slovenia) is hosted by highly deformed Permocarboniferous to Middle Triassic sedimentary rocks within a complex tectonic structure at the transition between the External Dinarides and the Southern Alps. Concordant and discordant mineralization formed concomitant with Middle Triassic bimodal volcanism in an aborted rift. A multiple isotopic (C, O, S) investigation of host rocks and ore minerals was performed to put constraints on the source and composition of the fluid, and the hydrothermal alteration. The distributions of the ¹³C and ¹⁸O values of host and gangue carbonates are indicative of a fracture-controlled hydrothermal system, with locally high fluid-rock ratios. Quantitative modeling of the ¹³C and ¹⁸O covariation for host carbonates during temperature dependent fluid-rock interaction, and concomitant precipitation of void-filling dolomites points to a slightly acidic hydrothermal fluid (¹³C–4 and ¹⁸O+10), which most likely evolved during isotopic exchange with carbonates under low fluid/rock ratios. The ³⁴S values of hydrothermal and sedimentary sulfur minerals were used to re-evaluate the previously proposed magmatic and evaporitic sulfur sources for the mineralization, and to assess the importance of other possible sulfur sources such as the contemporaneous seawater sulfate, sedimentary pyrite, and organic sulfur compounds. The ³⁴S values of the sulfides show a large variation at deposit down to hand-specimen scale. They range for cinnabar and pyrite from –19.1 to +22.8, and from –22.4 to +59.6, respectively, suggesting mixing of sulfur from different sources. The peak of ³⁴S values of cinnabar and pyrite close to 0 is compatible with ore sulfur derived dominantly from a magmatic fluid and/or from hydrothermal leaching of basement rocks. The similar stratigraphic trends of the ³⁴S values of both cinnabar and pyrite suggest a minor contribution of sedimentary sulfur (pyrite and organic sulfur) to the ore formation. Some of the positive ³⁴S values are probably derived from thermochemical reduction of evaporitic and contemporaneous seawater sulfates.Editorial handling: P. Lattanzi  相似文献   

Sediment contamination in floodplains and alluvial terraces as an historical record of gold exploitation in the Carmo River basin,Southeast Quadrilátero Ferrífero,Minas Gerais,Brazil     

Adivane Terezinha Costa  Hermínio Arias Nalini  Paulo de Tarso Amorim Castro  Jorge Carvalho de Lena  Peter Morgenstern  Kurt Friese 《洁净——土壤、空气、水》2006,34(3):245-256

This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na₂O, K₂O, SiO₂, CaO, MgO, Al₂O₃, Fe₂O₃, TiO₂, P₂O₅, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.  相似文献   

An audio-magnetotelluric investigation in Terceira Island (Azores)   总被引：2，自引：0，他引：2  

Fernando A. Monteiro Santos  Antnio Trota  Antnio Soares  Rafael Luzio  Nuno Loureno  Liliana Matos  Eugnio Almeida  Joo L. Gaspar  Jorge M. Miranda 《Journal of Applied Geophysics》2006,59(4):314-323

Ten audio-magnetotelluric soundings have been carried out along a profile crossing the Serra do Cume caldera in the eastern part of the Terceira Island (Azores). The main objectives of this investigation were to detect geoelectrical features related with tectonic structures and to characterize regional hydrological and hydrothermal aspects mainly those related to geothermal fluid dynamics.Three-dimensional numerical investigation showed that the data acquired at periods shorter than 1 s are not significantly affected by ocean effect. The data was analysed using the Smith's decomposition method in order to investigate possible distortions caused by superficial structures and to estimate a global regional strike. The results suggest that in general the soundings were not distorted. A regional N55°W strike was chosen for the two-dimensional data inversion.The low-resistivity zones (10–30 ohm-m) displayed in the central part of the 2-D geoelectrical model have been interpreted as caused by hydrothermal circulation. The low-resistivity anomalies at the ends of the profile might be attributed to alteration zones with interaction of seawater intrusion. High-resistivity (> 300 ohm-m) values have been related with less permeable zones in the SW of Cinco Picos and Guilherme Moniz caldera walls.  相似文献   

The Effect of Vegetation Productivity on Millet Prices in the Informal Markets of Mali, Burkina Faso and Niger     

Molly E. Brown  Jorge E. Pinzon  Stephen D. Prince 《Climatic change》2006,78(1):181-202

Systematic evaluation of food security throughout the Sahel has been attempted for nearly two decades. Food security analyses have used both food prices to determine the ability of the population to access food, and satellite-derived vegetation indices that measure vegetation production to establish how much food is available each year. The relationship between these two food security indicators is explored here using correspondence analysis and through the use of Markov chain models. Two sources of quantitative data were used: 8 km normalized difference vegetation index (NDVI) data from the Advanced Very High Resolution Radiometers (AVHRR) carried on the NOAA series of satellites, and monthly millet prices from 445 markets in Mali, Niger and Burkina Faso. The results show that the growing season vegetation production is related to the price of millet at the annual and the seasonal time scales. If the growing season was characterized by erratic, sparse rainfall, it resulted in higher prices, and well-distributed, abundant rainfall resulted in lower prices. The correspondence between vegetation production and millet prices is used to produce maps of millet prices for West Africa.  相似文献   

Late Pleistocene–Holocene environments in Valle Carbajal, Tierra del Fuego, Argentina   总被引：1，自引：0，他引：1  

Ana María Borromei  Andrea Coronato  Mirta Quattrocchio  Jorge Rabassa  Silvia Grill  Claudio Roig   《Journal of South American Earth Sciences》2007,23(4):321-335

The authors discuss Late Pleistocene–Holocene depositional environments in one of the Fuegian Andes valleys on the basis of palynological, geomorphological, and sedimentological analyses from two sites located near the Beagle Channel. The results obtained at these localities reinforce and refine the Late Pleistocene–Holocene climatic pattern previously recorded there. A colder period, associated with the Younger Dryas stadial event, is suggested by low Nothofagus pollen frequency, and communities of grass, low scrub, and shrub heath expanded into the low/middle slopes (10,310 ¹⁴C yr BP). By ca. 9500 ¹⁴C yr BP, warmer and drier conditions occurred, as evidenced by the development of open-grown vegetation in the valley floors (pollen zone O-3), followed by the expansion of open Nothofagus woodland (pollen zone O-2) in the middle Holocene. The milder climate subsequently changed, as indicated by the spreading of the closed forest and mire (pollen zone O-1), to more humid and cooler conditions during the last ca. 5000 yr BP.  相似文献   

Vulnerability assessment in a volcanic risk evaluation in Central Mexico through a multi-criteria-GIS approach   总被引：1，自引：1，他引：1  

José Fernando Aceves-Quesada  Jesús Díaz-Salgado  Jorge López-Blanco 《Natural Hazards》2007,40(2):339-356

The Valley of Toluca is a major industrial and agricultural area in Central Mexico, especially the City of Toluca, the capital of The State of Mexico. The Nevado de Toluca volcano is located to the southwest of The Toluca Basin. Results obtained from the vulnerability assessment phase of the study area (5,040 km² and 42 municipalities) are presented here as a part of a comprehensive volcanic risk assessment of The Toluca Basin. Information has been gathered and processed at a municipal level including thematic maps at 1:250,000 scale. A database has been built, classified and analyzed within a GIS environment; additionally, a Multi-Criteria Evaluation (MCE) approach was applied as an aid for the decision-making process. Cartographic results were five vulnerability maps: (1) Total Population, (2) Land Use/Cover, (3) Infrastructure, (4) Economic Units and (5) Total Vulnerability. Our main results suggest that the Toluca and Tianguistenco urban and industrial areas, to the north and northeast of The Valley of Toluca, are the most vulnerable areas, for their high concentration of population, infrastructure, economic activity, and exposure to volcanic events.  相似文献   

Mass functions of five distant northern open star clusters     

Ram Sagar  & W. K. Griffiths 《Monthly notices of the Royal Astronomical Society》1998,299(3):777-788

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Inversion of free oscillation data for an elliptical rotating earth in source moment tensor studies     

Jorge A. Mendiguren 《Pure and Applied Geophysics》1980,118(2):1192-1208

It is shown, through numerical experiments, that the effect of ignoring ellipticity and rotation of the earth when inverting free oscillation data in moment tensor studies, is to introduce spurious spectral components in the solution. For numerical simulation of the data conditions of the 1970 deep Colombian event the spurious part has isotropic and deviatoric components, besides a distortion in the phase spectra which may lead to artificial precursive source in the solution. The magnitude of the artificial isotropic component is of the order of 10% of the real source moment tensor, depending on the data set used in the inversion. Measuring the excitation of each mode at each station using the technique of integrating over the spectral peaks does not cancel completely the effect of multiplet splitting, in particular that splitting due to rotation of the earth. The effect of lateral heterogeneities was simulated by introducing arbitrary splitting parameters which produced scattering in the eigenperiods compatible with those observed. For that splitting the inversion rendered additional isotropic components.We conclude that the observed implosive precursor the the 1970 Colombian event could have been artificially introduced by ignoring rotation, ellipticity and lateral heterogeneities of the earth.A procedure to invert free oscillation data for an elliptical rotating earth is proposed. It could be applied to a laterally inhomogeneous earth if the excitation for that model could be computed. Its application to real data for the deep Colombian event indicates that we will need to improve our knowledge on the effect of rotation, ellipticity, lateral heterogeneities and anelasticity on free oscillation and their excitation in order to solve accurately for the six components of the moment tensor independently.  相似文献   

Deformational and crystallization history of the Precambrian rocks in north-central Aravalli Mountain,Rajasthan, India     

Ram S. Sharma 《Precambrian Research》1977,4(2):133-162

Large-scale structures, textures and mineral assemblages in the Precambrian rocks of the Banded Gneissic Complex and the overlying Delhi Group in north-central Aravalli Mountain reveal a complex deformational-crystallization history. In the basement Gneissic Complex at least three deformational events, D₀, D₁ and D₂, and two separate episodes of metamorphism, M₁ and M₂, are recognized. The supracrustal Delhi Rocks display only two phases of deformation, D₁ and D₂, associated with a single protracted period of metamorphism, M₂.The first phase of deformation (D₁) of the Delhi orogeny (1650-900 m.y.) produced large isoclinal folds that are overturned towards the southeast and have gentle plunges in NE and SW directions. The second phase of deformation (D₂) gave rise to tight open folds on the limbs and axial-plane surfaces of the D₁ folds. These folds generally plunge towards the N and NNW at 30°–80°. In the Basement Complex one more deformation (D₀) of the Pre-Delhi orogeny (> 2000 m.y.) is recorded by the presence of reclined and recumbent folds with W to WNW trending fold axes. The D₀ folds were superimposed by D₁ and D₂ folds during the Delhi orogeny.The three deformational events have been correlated with the crystallization periods of minerals in the rocks and a setting in time is established for this part of the Aravalli range.  相似文献