Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy     

Seunghee Han  Joris Gieskes  Anna Obraztsova  Dimitri D. Deheyn  Bradley M. Tebo 《Estuarine, Coastal and Shelf Science》2011

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.  相似文献   

Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries   总被引：2，自引：0，他引：2  

Seunghee Han  Anna Obraztsova  Patrizia Pretto  Dimitri D. Deheyn  Joris Gieskes  Bradley M. Tebo   《Marine Chemistry》2008,111(3-4):214-220

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.  相似文献   

Isogeometric finite element analysis of poroelasticity     

Faisal Irzal  Joris J. C. Remmers  Clemens V. Verhoosel  René de Borst 《国际地质力学数值与分析法杂志》2013,37(12):1891-1907

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The effect of dust on Tremaine–Weinberg measurements     

Joris Gerssen  Victor P. Debattista 《Monthly notices of the Royal Astronomical Society》2007,378(1):189-197

We investigate the effect of dust on the observed rotation rate of a stellar bar. The only direct way to measure this quantity relies on the Tremaine & Weinberg (TW) method which requires that the tracer satisfies the continuity equation. Thus, it has been applied largely to early-type barred galaxies. We show using numerical simulations of barred galaxies that dust attenuation factors typically found in these systems change the observed bar pattern speed by 20–40 per cent. We also address the effect of star formation on the TW method and find that it does not change the results significantly. The results presented here suggest that applications of the TW method can be extended to include barred galaxies covering the full range of Hubble type.  相似文献   

Statistical Revision of the Moment Method     

Joris De Ridder  Geert Molenberghs  Conny Aerts 《Astrophysics and Space Science》2003,284(1):125-128

The moment method is a well known technique, which uses a time series ofthe first 3 moments of a spectral line, to estimate the (discrete) modeparameters and m. The method, contrary to Doppler imaging,also yields other interesting(real-valued) parameters such as the inclination angle i, or v sin i,during its identification procedure.In this paper, we are not only interested in the estimation of thesereal-valued parameters themselves but also inreliable estimates for their uncertainty.We designed a statistical formalism for the moment method based on theso-called generalized estimating equations (GEE). This formalismaims to estimate the uncertainty of the real-valued parameters taking intoaccount that the different moments of a line profile are correlated and –more importantly – that the uncertainty of the observed moments depends onthe pulsation parameters. The latter property of the moment method makesthe least-squares technique a poor choice to estimate the uncertainty ofthe real-valued parameters. We implemented the GEE method and presentan application to a high-resolution spectroscopic dataset of the slowly pulsating B star HD181558.  相似文献   

A study of the chemistry of pore fluids and authigenic carbonates in methane seep environments: Kodiak Trench, Hydrate Ridge, Monterey Bay, and Eel River Basin   总被引：3，自引：0，他引：3  

Joris Gieskes  Chris Mahn  Shelley Day  Jonathan B. Martin  Jens Greinert  Tony Rathburn  Brian McAdoo 《Chemical Geology》2005,220(3-4):329-345

Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ¹³C (DIC) values are low (isotopically light), whereas in the Eel River area ( 350–500 m), δ¹³C (DIC) values are much higher (isotopically heavier). In all cases, the δ¹³C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ¹³C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ¹³C (up to 23‰;) and δ¹⁸O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.  相似文献   

Predicting catchment sediment yield in Mediterranean environments: the importance of sediment sources and connectivity in Italian drainage basins   总被引：2，自引：0，他引：2  

Joris de Vente  Jean Poesen  Paolo Bazzoffi  Anton Van Rompaey  Gert Verstraeten 《地球表面变化过程与地形》2006,31(8):1017-1034

Predicting sediment yield at the catchment scale is one of the main challenges in geomorphologic research. The application of both physics‐based models and regression models has until now not provided very satisfying results for prediction of sediment yield for medium to large sized catchments (c. >50 km²). The explanation for this lies in a combination of the large data requirements of most models and a lack of knowledge to describe all processes and process interactions at the catchment scale. In particular, point sources of sediment (e.g. gullies, mass movements), connectivity and sediment transport remain difficult to describe in most models. From reservoir sedimentation data of 44 Italian catchments, it appeared that there was a (non‐significant) positive relation between catchment area and sediment yield. This is in contrast to what is generally expected from the theory of decreasing sediment delivery rates with increasing catchment area. Furthermore, this positive relation suggests that processes other than upland erosion are responsible for catchment sediment yield. Here we explore the potential of the Factorial Scoring Model (FSM) and the Pacific Southwest Interagency Committee (PSIAC) model to predict sediment yield, and indicate the most important sediment sources. In these models different factors are used to characterize a drainage basin in terms of sensitivity to erosion and connectivity. In both models an index is calculated that is related to sediment yield. The FSM explained between 36 and 61 per cent of the variation in sediment yield, and the PSIAC model between 57 and 62 per cent, depending on the factors used to characterize the catchments. The FSM model performed best based on a factor to describe gullies, lithology, landslides, catchment shape and vegetation. Topography and catchment area did not explain additional variance. In particular, the addition of the landslide factor resulted in a significantly increased model performance. The FSM and PSIAC model both performed better than a spatially distributed model describing water erosion and sediment transport, which was applied to the same catchments but explained only between 20 and 51 per cent of the variation in sediment yield. Model results confirmed the hypothesis that processes other than upland erosion are probably responsible for sediment yield in the Italian catchments. A promising future development of the models is by the use of detailed spatially distributed data to determine the scores, decrease model subjectivity and provide spatially distributed output. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Particulate iron and manganese in the Santa Barbara Basin,California     

Alan M. Shiller  Joris M. Gieskes  N. Brian Price 《Geochimica et cosmochimica acta》1985,49(5):1239-1249

Particulate Fe and Mn may be important trace metal scavengers in the water column as well as being probable indicators of biologically mediated redox processes. A study has been made of suspended particulate composition in the Santa Barbara Basin, a shallow near-shore basin off southern California with sub-oxic conditions below sill depth. Observations have revealed several interesting phenomena relating to the geochemistry of Fe and Mn. Most striking is a profound enrichment of particulate Fe in samples from the bottom two hundred meters. These particulates have a constant Fe/P mole ratio of about three and may originate at the sediment-water interface or may be transported to the basin from local marshes. For particulate Mn, enrichments are observed both in the sub-sill waters and near the base of the euphotic zone. A consideration of particle removal rates suggests that the sub-photic zone enrichment has a biogenic origin. In the sub-sill waters, enrichment in Mn is apparently due to the precipitation of dissolved Mn diffusing from the anoxic basin sediments. A simple mass balance suggests that most of the Mn lost from the sediments is transported from the Santa Barbara Basin in dissolved form.  相似文献   

Ancient charcoal as a natural archive for paleofire regime and vegetation change in the Mayumbe,Democratic Republic of the Congo     

Wannes Hubau  Jan Van den Bulcke  Peter Kitin  Florias Mees  Geert Baert  Dirk Verschuren  Laurent Nsenga  Joris Van Acker  Hans Beeckman 《Quaternary Research》2013

Charcoal was sampled in four soil profiles at the Mayumbe forest boundary (DRC). Five fire events were recorded and 44 charcoal types were identified. One stratified profile yielded charcoal assemblages around 530 cal yr BP and > 43.5 cal ka BP in age. The oldest assemblage precedes the period of recorded anthropogenic burning, illustrating occasional long-term absence of fire but also natural wildfire occurrences within tropical rainforest. No other charcoal assemblages older than 2500 cal yr BP were recorded, perhaps due to bioturbation and colluvial reworking. The recorded paleofires were possibly associated with short-lived climate anomalies. Progressively dry climatic conditions since ca. 4000 cal yr BP onward did not promote paleofire occurrence until increasing seasonality affected vegetation at the end of the third millennium BP, as illustrated by a fire occurring in mature rainforest that persisted until around 2050 cal yr BP. During a drought episode coinciding with the ‘Medieval Climate Anomaly’, mature rainforest was locally replaced by woodland savanna. Charcoal remains from pioneer forest indicate that fire hampered forest regeneration after climatic drought episodes. The presence of pottery shards and oil-palm endocarps associated with two relatively recent paleofires suggests that the effects of climate variability were amplified by human activities.  相似文献   

The implications of data selection for regional erosion and sediment yield modelling     

Joris de Vente  Jean Poesen  Gerard Govers  Carolina Boix‐Fayos 《地球表面变化过程与地形》2009,34(15):1994-2007

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