Acid-base and copper-binding properties of three organic matter fractions isolated from a forest floor soil solution     

Joris W.J. van Schaik  Dan B. Kleja 《Geochimica et cosmochimica acta》2010,74(4):1391-4019

Vast amounts of knowledge about the proton- and metal-binding properties of dissolved organic matter (DOM) in natural waters have been obtained in studies on isolated humic and fulvic (hydrophobic) acids. Although macromolecular hydrophilic acids normally make up about one-third of DOM, their proton- and metal-binding properties are poorly known. Here, we investigated the acid-base and Cu-binding properties of the hydrophobic (fulvic) acid fraction and two hydrophilic fractions isolated from a soil solution. Proton titrations revealed a higher total charge for the hydrophilic acid fractions than for the hydrophobic acid fraction. The most hydrophilic fraction appeared to be dominated by weak acid sites, as evidenced by increased slope of the curve of surface charge versus pH at pH values above 6. The titration curves were poorly predicted by both Stockholm Humic Model (SHM) and NICA-Donnan model calculations using generic parameter values, but could be modelled accurately after optimisation of the proton-binding parameters (pH ? 9). Cu-binding isotherms for the three fractions were determined at pH values of 4, 6 and 9. With the optimised proton-binding parameters, the SHM model predictions for Cu binding improved, whereas the NICA-Donnan predictions deteriorated. After optimisation of Cu-binding parameters, both models described the experimental data satisfactorily. Iron(III) and aluminium competed strongly with Cu for binding sites at both pH 4 and pH 6. The SHM model predicted this competition reasonably well, but the NICA-Donnan model underestimated the effects significantly at pH 6. Overall, the Cu-binding behaviour of the two hydrophilic acid fractions was very similar to that of the hydrophobic acid fraction, despite the differences observed in proton-binding characteristics. These results show that for modelling purposes, it is essential to include the hydrophilic acid fraction in the pool of ‘active’ humic substances.  相似文献   

Containment of groundwater pollution (methyl tertiary butyl ether and benzene) to protect a drinking-water production site in Belgium     

Pieter Jan Haest  Richard Lookman  Ilse Van Keer  Johan Patyn  Jan Bronders  Marjan Joris  Jan Bellon  Florimond De Smedt 《Hydrogeology Journal》2010,18(8):1917-1925

The subsurface migration of methyl tertiary butyl ether (MTBE) and benzene towards a drinking-water production site in Belgium was monitored for 9 years. A large gasoline spill at a nearby fuel station had caused a 500-m long and 50-m-wide pollution plume of MTBE (10?30 mg/L) and benzene (2?10 mg/L). In order to prevent any intrusion of pollutants into the drinking-water supply, a conceptual model was used to design a pump-and-treat system that intercepted the gasoline-contaminated groundwater emanating from the spill. The contaminated soil in the spill zone was excavated. A numerical mass transport model was developed to evaluate the ongoing plume containment. The model describes the subsurface MTBE migration and was regularly updated, based on groundwater monitoring data and the measured mass of MTBE extracted with the pump-and-treat system. With continued interception pumping, the MTBE plume can be remediated in 14 years. Without it, MTBE and benzene concentrations up to 600 μg/L could have reached the drinking-water production site and the plume would persist for 9 years longer. Source zone treatment combined with plume interception pumping is a suitable risk-based remediation strategy for the containment of MTBE and benzene groundwater pollution.  相似文献   

New techniques for integral field spectroscopy – II. Performance of the GNIRS IFU     

Jeremy Allington-Smith  Cornelis M. Dubbeldam  Robert Content  David Robertson  James Turner  Bernadette Rodgers  Jonathan Elias  Joris Gerssen †  Mark Swinbank 《Monthly notices of the Royal Astronomical Society》2007,376(2):785-792

  相似文献   

Cold seeps in Monterey Bay, California: Geochemistry of pore waters and relationship to benthic foraminiferal calcite     

Joris Gieskes  Anthony E. Rathburn  Jonathan B. Martin  M. Elena Prez  Chris Mahn  Joan M. Bernhard  Shelley Day 《Applied Geochemistry》2011,26(5):738-746

An extensive geochemical and biogeochemical examination of CH₄ seeps in the Clam Flats area of Monterey Bay provides insight into the character of relationships between seep geochemistry and benthic foraminiferal geochemistry. The area is characterized by sulfide-rich fluids. Sulfide increases are associated with large increases in alkalinity, as well as small decreases in dissolved Ca and Mg. In addition, only small increases in NH₄ are observed, but values of δ¹³C of dissolved inorganic C are as low as −60‰ at shallow depths (<3 cm). These observations indicate that all these processes are related to the bacterial oxidation of CH₄, which is transported upward by slow seepage of pore fluids. The geochemistry of the pore fluids should be relevant to the geochemistry of the carbonate tests of living and dead foraminifera. However, a profound disequilibrium of approximately an order of magnitude occurs between the δ¹³C values of stained (cytoplasm-containing) foraminiferal carbonate and the C isotope values of ambient pore water dissolved inorganic C. Reasons are unclear for this isotopic disequilibrium, but have important implications for interpretations of foraminiferal carbonate as a paleoenvironmental proxy. Much fine scale work is needed to fully understand the relationships between the biogeochemistry of benthic foraminifera and the geochemistry of the pore waters where they live.  相似文献   

An Analysis of Turbulent Heat Fluxes and the Energy Balance During the REFLEX Campaign     

Christiaan van der Tol  Wim Timmermans  Chiara Corbari  Arnaud Carrara  Joris Timmermans  Zhongbo Su 《Acta Geophysica》2015,63(6):1516-1539

Three eddy covariance stations were installed at the Barrax experimental farm during the Land-Atmosphere Exchanges (REFLEX) airborne training and measurement campaign to provide ground truth data of energy balance fluxes and vertical temperature and wind profiles. The energy balance closure ratio (EBR) was 105% for a homogeneous camelina site, 86% at a sparse reforestation site, and 73% for a vineyard. We hypothesize that the lower closure in the last site was related to the limited fetch. Incorporating a vertical gradient of soil thermal properties decreased the RMSE of the energy balance at the camelina site by 16 W m^?2. At the camelina site, eddy covariance estimates of sensible and latent heat fluxes could be reproduced well using mean vertical profiles of wind and temperature, provided that the Monin—Obukhov length is known. Measured surface temperature and sensible heat fluxes suggested high excess resistance for heat (kB^?1 = 17).  相似文献   

Sediment yield variability in Spain: a quantitative and semiqualitative analysis using reservoir sedimentation rates   总被引：3，自引：0，他引：3  

Gert Verstraeten  Jean Poesen  Joris de Vente  Xenia Koninckx 《Geomorphology》2003,50(4):327-348

An existing dataset of area-specific sediment yield (SSY) for 60 catchments in Spain that was retrieved from sediment deposition rates in reservoirs [Avendaño Salas, C., Sanz Montero, E., Rayán, C., Gómez Montaña, 1997. Sediment yield at Spanish reservoirs and its relationship with the drainage basin area. In: Proceedings of the 19th Symposium of Large Dams, Florence, 1997. ICOLD (International Committee on Large Dams), pp. 863–874] reveals that catchment area alone explains only 17% of the variability in SSY. In this study, an attempt to explain the remaining variability in SSY was made using a quantitative and a semiqualitative approach for 22 catchments. During a field survey, the 22 selected catchments were characterised by topography, vegetation cover, lithology, shape and the presence of gullies in the broad vicinity of the reservoir. This information was used to develop a factorial scoring index model that provides a fairly accurate and reliable prediction of SSY. A classical multiple regression model using climatic, topographic and land use properties derived from regional datasets could not explain as much variance as the qualitative index model, nor did it appear to be as reliable. The same conclusion could be drawn when using the CORINE soil erosion risk map of southern Europe. The low prediction capability of the multiple regression models and the CORINE soil erosion risk map could be attributed mainly to the fact that these methods do not incorporate gully erosion and that the land cover data are not a good representation of soil cover. Both variables have been shown to be of great importance during the field surveys. Future assessments of SSY could be quickly and efficiently made using the proposed factorial scoring index model. In comparison with other models, which demand more data, the index model offers an alternative prediction tool.  相似文献   

Evidence for extensive diagenesis,Madagascar Basin,Deep Sea Drilling Site 245     

Joris M. Gieskes  Miriam Kastner  Theodore B. Warner 《Geochimica et cosmochimica acta》1975,39(10):1385-1393

Deep Sea Drilling Hole 245 (31°32′S, 52° 18′E) in the southwest Indian Ocean shows pronounced linear concentration-depth gradients in interstitial dissolved Ca, Mg and Sr. Electrical conductivity tests enable us to make the estimate of a constant diffusion coefficient with depth of about 2 × 10^?6 cm²/sec. The shapes of the concentration-depth gradients suggest that the major reaction sites in this hole are situated in the basal sediments and/or underlying basalts. It is proposed that observed interstitial water concentration changes in Ca and Mg are related to alteration of basaltic material, whereas those in Sr are due to calcium carbonate recrystallization processes. Support for the basaltic material alteration hypothesis comes from petrochemical and mineralogical data. Geochemical data also indicate that the high contents in Fe and Mn of the basal sediments can be related to low temperature alteration of basaltic glass and not necessarily to ‘hydrothermal’ activity.  相似文献   

Water column anomalies associated with hydrothermal activity in the Guaymas Basin,Gulf of California     

Andrew C. Campbell  Joris M. Gieskes 《Earth and Planetary Science Letters》1984,68(1):57-72

Sea floor hydrothermal activity in the Guaymas Basin, Gulf of California, is quite different from that associated with ridge crest spreading centers. Injection of hydrothermal fluids occurs in the bottom of a semi-enclosed basin and water column anomalies produced by this activity increase to much higher values than in the open ocean. In the Guaymas Basin the hydrothermal venting generates large clouds of fine suspended particulate matter (SPM) 100–300 m above active mounds and chimneys. These hydrothermal clouds have potential temperature anomalies of about 0.010–0.020°C, are enriched in dissolved silica, particulate manganese, and depleted in dissolved oxygen relative to areas away from the vents. The particulate manganese values increase from about 3 nmol/kg at ～ 1000 m, well above the enclosing topography of the subsill basin, to 100–150 nmol/kg in the clouds of SPM and in the bottom nepheloid layer. The particulate Mn in the hydrothermal clouds appears to originate from both direct precipitation of dissolved Mn²⁺ injected by the vents and entrainment of Mn-rich SPM in the rising hydrothermal plumes. Injection of silica-rich vent fluids into the basin bottom waters produces a silica anomaly of 10–15 μmol relative to the other deep basins of the Gulf of California. Spillover of Guaymas Basin deep water produces a silica plume just above the basin sill depth which is detectable to the mouth of the Gulf. A simple two-endmember mixing model indicates that the deep waters of the Guaymas Basin contain approximately 0.1% hydrothermal fluid. Oxygen anomalies associated with the hydrothermal clouds are on the order of 5 μmol relative to regions away from active vents. The basin as a whole shows a depletion in oxygen of about 13 μmol relative to the other deep basins of the Gulf. The mixing model shows that this oxygen consumption can be explained by the oxidation of dissolved sulfide and methane injected by the hydrothermal vents. Box models of the deep basins of the southern Gulf of California indicate that the Guaymas Basin has a significantly higher source term for dissolved silica and sink term for dissolved oxygen than the other basins. The calculated flux of hydrothermal fluids into the Guaymas Basin is 10–12 m³/s.  相似文献   

Note on ``Electromagnetic Response of a Large Circular Loop Source on a Layered Earth: A New Computation Method' by N. P. Singh and T. Mogi     

Joris Van Deun  Ronald Cools 《Pure and Applied Geophysics》2007,164(5):1107-1111

  相似文献   

Environmental estrogens interact with and modulate the properties of plasma sex steroid-binding proteins in juvenile Atlantic salmon (Salmo salar)     

Knut-Erik Tollefsen  Joris F. A. Meys  Jorid Frydenlund  Jrgen Stenersen 《Marine environmental research》2002,54(3-5)

Environmental chemicals may modulate the endocrine system through interaction with plasma sex steroid-binding proteins (SBP) and SBP-regulated processes. Some of these chemicals, which are known to interact with the estrogen receptor (ER), were found to bind competitively to the Atlantic salmon (Salmo salar) SBP and potentially disrupt the endocrine function of these proteins. Furthermore, both weakly acting (di-n-butyl phthalate) and potent estrogen mimics (ethynylestradiol), were able to induce a substantial up-regulation of circulating levels of SBP in vivo. Interestingly, modulation of SBP-levels was found to be a more sensitive endpoint than chemically induced interference with classical ER-mediated mechanisms for weakly acting estrogen mimics like di-(n-butyl) phthalate. Interference with the endocrine function of SBPs may thus introduce a novel mechanism for endocrine disruption, and give additional answers to the question why some weakly acting xenoestrogens are causing “estrogen-like” reproductive disturbances in developing males.  相似文献