Variability of ozone in the marine boundary layer of the equatorial Pacific Ocean     

Xiao-Ming Hu  Jeffrey M. Sigler  Jose D. Fuentes 《Journal of Atmospheric Chemistry》2010,66(3):117-136

This study examines the processes controlling the diurnal variability of ozone (O₃) in the marine boundary layer of the Kwajalein Atoll, Republic of the Marshall Islands (latitude 8° 43′ N, longitude 167° 44′ E), during July to September 1999. At the study site, situated in the equatorial Pacific Ocean, O₃ mixing ratios remained low, with an overall average of 9–10 parts per billion on a volume basis (ppbv) and a standard deviation of 2.5 ppbv. In the absence of convective storms, daily O₃ mixing ratios decreased after sunrise and reached minimum during the afternoon in response to photochemical reactions. The peak-to-peak amplitude of O₃ diurnal variation was approximately 1–3 ppbv. During the daytime, O₃ photolysis, hydroperoxyl radicals, hydroxyl radicals, and bromine atoms contributed to the destruction of O₃, which explained the observed minimum O₃ levels observed in the afternoon. The entrainment of O₃-richer air from the free troposphere to the local marine boundary layer provided a recovery mechanism of surface O₃ mixing ratio with a transport rate of 0.04 to 0.2 ppbv per hour during nighttime. In the presence of convection, downward transport of O₃-richer tropospheric air increased surface O₃ mixing ratios by 3–12 ppbv. The magnitude of O₃ increase due to moist convection was lower than that observed over the continent (as high as 20–30 ppbv). Differences were ascribed to the higher O₃ levels in the continental troposphere and weaker convection over the ocean. Present results suggest that moist convection plays a role in surface-level O₃ dynamics in the tropical marine boundary layer.  相似文献   

Future change of climate in South America in the late twenty-first century: intercomparison of scenarios from three regional climate models   总被引：2，自引：1，他引：1  

Jose A. Marengo  Tercio Ambrizzi  Rosmeri P. da Rocha  Lincoln M. Alves  Santiago V. Cuadra  Maria C. Valverde  Roger R. Torres  Daniel C. Santos  Simone E. T. Ferraz 《Climate Dynamics》2010,35(6):1073-1097

Regional climate change projections for the last half of the twenty-first century have been produced for South America, as part of the CREAS (Cenarios REgionalizados de Clima Futuro da America do Sul) regional project. Three regional climate models RCMs (Eta CCS, RegCM3 and HadRM3P) were nested within the HadAM3P global model. The simulations cover a 30-year period representing present climate (1961–1990) and projections for the IPCC A2 high emission scenario for 2071–2100. The focus was on the changes in the mean circulation and surface variables, in particular, surface air temperature and precipitation. There is a consistent pattern of changes in circulation, rainfall and temperatures as depicted by the three models. The HadRM3P shows intensification and a more southward position of the subtropical Pacific high, while a pattern of intensification/weakening during summer/winter is projected by the Eta CCS/RegCM3. There is a tendency for a weakening of the subtropical westerly jet from the Eta CCS and HadRM3P, consistent with other studies. There are indications that regions such of Northeast Brazil and central-eastern and southern Amazonia may experience rainfall deficiency in the future, while the Northwest coast of Peru-Ecuador and northern Argentina may experience rainfall excesses in a warmer future, and these changes may vary with the seasons. The three models show warming in the A2 scenario stronger in the tropical region, especially in the 5°N–15°S band, both in summer and especially in winter, reaching up to 6–8°C warmer than in the present. In southern South America, the warming in summer varies between 2 and 4°C and in winter between 3 and 5°C in the same region from the 3 models. These changes are consistent with changes in low level circulation from the models, and they are comparable with changes in rainfall and temperature extremes reported elsewhere. In summary, some aspects of projected future climate change are quite robust across this set of model runs for some regions, as the Northwest coast of Peru-Ecuador, northern Argentina, Eastern Amazonia and Northeast Brazil, whereas for other regions they are less robust as in Pantanal region of West Central and southeastern Brazil.  相似文献   

Climate change,weather variability and corn yield at a higher latitude locale: Southwestern Quebec   总被引：5，自引：0，他引：5  

Juan Jose Almaraz  Fazli Mabood  Xiaomin Zhou  Edward G. Gregorich  Donald L. Smith 《Climatic change》2008,88(2):187-197

Climate change has led to increased temperatures, and simulation models suggest that this should affect crop production in important agricultural regions of the world. Nations at higher latitudes, such as Canada, will be most affected. We studied the relationship between climate variability (temperature and precipitation) and corn yield trends over a period of 33 years for the Monteregie region of south-western Quebec using historical yield and climate records and statistical models. Growing season mean temperature has increased in Monterregie, mainly due to increased September temperature. Precipitation did not show any clear trend over the 33 year period. Yield increased about 118 kg ha⁻¹ year⁻¹ from 1973 to 2005 (under normal weather conditions) due mainly to changes in technology (genetics and management). Two climate variables were strongly associated with corn yield variability: July temperature and May precipitation. These two variables explain more than a half of yield variability associated with climate. In conclusion, July temperatures below normal and May precipitation above normal have negative effects on corn yield, and the growing seasons have warmed, largely due to increases in the September temperature.  相似文献   

An exact solution to the relativistic advance of perihelion: correcting the Einstein approximation     

Jose Mario Saca 《Astrophysics and Space Science》2008,315(1-4):365-365

New calculations of the main term of the advance of perihelion for the asteroid Icarus and planet Mercury are discussed. With the help of this author’s previously published formula for the advance, results are then compared to the values given by Einstein’s approximation.  相似文献   

Bivalves,Tributyltin and Green Tides: Ecosystem-Level Impact?     

Jose M. Ruiz 《Marine Ecology》1999,20(1):1-9

Filter feeders such as bivalves are increasingly being shown to control phytoplankton blooms in eutrophic estuaries. The possibility of such a top-down effect on macroalgae, however, has not been considered previously even though most green tide algal species reproduce by pelagic swarmers that are equivalent to phytoplankton. This work presents circumstantial evidence from an oyster-culturing French embayment where, despite eutrophication since the mid-1970s, macroalgae did not proliferate until 1982. This was also the year when tributyltin pollution from antifouling paints dropped substantially following a world-wide prime ban that was implemented to save the shellfish industry. From the recorded evolution of the oyster stock, it is shown how tributyltin reduced the bivalve filter capacity within those years and resulted in Enteromorpha swarmers being much more likely to germinate and bloom. This suggests that the green tides had been successively contained by the biological activity and the chemical pressure. The effects of the latter on the former would thus have cascaded to ecosystem-level changes, and so the functional role of bivalves should be evaluated and preserved wherever relevant.  相似文献   

Aeolian dune migration along the Ceará coast, north-eastern Brazil     

Jose A. Jimenez  Luis P. Maia  Jordi Serra  & Jader Morais 《Sedimentology》1999,46(4):689-701

Aeolian dune dimensions and migration rates are analysed along the Ceará coast, north-east Brazil. Dunes that are currently mobile along the Ceará coast are composed of barchans and sand sheets. The results show that barchans maintain an equilibrium form, which can be characterized by values of dimensionless shape parameters H/W and W/L , where H is the dune height, W is the wing-to-wing width and L is the dune length. Dunes are highly mobile, with average migration rates of 17·5 m year⁻¹ for barchans and 10 m year⁻¹ for sand sheets. The calculated migration rates were found to depend strongly on dune dimensions for both barchans and sand sheets, i.e. the larger the dune is, the lower the migration rate will be. This size dependence was associated with the existence of a representative common transport rate along the dune fields, which induces a different dune migration rate dependent on dune size. Finally, from the observed dune evolution, an aggregated scale aeolian sediment transport was inferred. This bulk transport rate, of the order of 90–100 m³ m⁻¹ year⁻¹, is only valid for a timescale of years to decades, which is the timescale used in dune evolution analysis.  相似文献   

Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes     

Anitha Senthamizhan  Brabu Balusamy  Doriana Debellis  Jose Alejandro Heredia-Guerrero  Giorgio Mancini  Riccardo Carzino  Luca Ceseracciu  Athanassia Athanassiou  Despina Fragouli 《洁净——土壤、空气、水》2023,51(1):2200284

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.  相似文献   

Experimental study of deformable connection consisting of buckling‐restrained brace and rubber bearings to connect floor system to lateral force resisting system          下载免费PDF全文

Georgios Tsampras  Richard Sause  Robert B. Fleischman  Jose I. Restrepo 《地震工程与结构动力学》2017,46(8):1287-1305

This paper presents experimental and numerical studies of a full‐scale deformable connection used to connect the floor system of the flexible gravity load resisting system to the stiff lateral force resisting system (LFRS) of an earthquake‐resistant building. The purpose of the deformable connection is to limit the earthquake‐induced horizontal inertia force transferred from the floor system to the LFRS and, thereby, to reduce the horizontal floor accelerations and the forces in the LFRS. The deformable connection that was studied consists of a buckling‐restrained brace (BRB) and steel‐reinforced laminated low‐damping rubber bearings (RB). The test results show that the force–deformation responses of the connection are stable, and the dynamic force responses are larger than the quasi‐static force responses. The BRB+RB force–deformation response depends mainly on the BRB response. A detailed discussion of the BRB experimental force–deformation response is presented. The experimental results show that the maximum plastic deformation range controls the isotropic hardening of the BRB. The hardened BRB force–deformation responses are used to calculate the overstrength adjustment factors. Details and limitations of a validated, accurate model for the connection force–deformation response are presented. Numerical simulation results for a 12‐story reinforced concrete wall building with deformable connections show the effects of including the RB in the deformable connection and the effect of modeling the BRB isotropic hardening on the building seismic response. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Runup uncertainty on planar beaches     

Torres-Freyermuth  Alec  Pintado-Pati&#;o  Jose Carlos  Pedrozo-Acu&#;a  Adri&#;n  Puleo  Jack A.  Baldock  Tom E. 《Ocean Dynamics》2019,69(11):1359-1371

Parameterization of wave runup is of paramount importance for an assessment of coastal hazards. Parametric models employ wave (e.g., H_s and L_p) and beach (i.e., β) parameters to estimate extreme runup (e.g., R_2%). Thus, recent studies have been devoted to improving such parameterizations by including additional information regarding wave forcing or beach morphology features. However, the effects of intra-wave dynamics, related to the random nature of the wave transformation process, on runup statistics have not been incorporated. This work employs a phase- and depth- resolving model, based on the Reynolds-averaged Navier-Stokes equations, to investigate different sources of variability associated with runup on planar beaches. The numerical model is validated with laboratory runup data. Subsequently, the role of both aleatory uncertainty and other known sources of runup variability (i.e., frequency spreading and bed roughness) is investigated. Model results show that aleatory uncertainty can be more important than the contributions from other sources of variability such as the bed roughness and frequency spreading. Ensemble results are employed to develop a new parametric model which uses the Hunt (J Waterw Port Coastal Ocean Eng 85:123–152, 1959) scaling parameter \(\beta \left (H_{s}L_{p}\right )^{1/2}\).

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Comparative study of As,Cd, Cu,Cr, Mg,Mn, Ni,Pb and Zn concentrations between sediment and water from estuary and port     

I. Bejarano-Ramirez  Jose M. Jurado  R. Muñiz-Valencia  Á. Alcázar  Silvia G. Ceballos-Magaña  A. Olivos-Ortiz  O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342

The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献