<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites     

S.-U. Weber  M. Grodzicki  C. A. Geiger  W. Lottermoser  G. Tippelt  G. J. Redhammer  M. Bernroider  G. Amthauer 《Physics and Chemistry of Minerals》2007,34(1):1-9

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.  相似文献   

Magmatic structures in the Krkonoše–Jizera Plutonic Complex,Bohemian Massif: evidence for localized multiphase flow and small-scale thermal–mechanical instabilities in a granitic magma chamber     

Jiří Žák  Josef Klomínský 《Journal of Volcanology and Geothermal Research》2007

The present paper examines magmatic structures in the Jizera and Liberec granites of the Krkonoše–Jizera Plutonic Complex, Bohemian Massif. The magmatic structures are here interpreted to preserve direct field evidence for highly localized magma flow and other processes in crystal-rich mushes, and to capture the evolution of physical processes in an ancient granitic magma chamber. We propose that after chamber-wide mixing and hybridization, as suggested by recent petrological studies, laminar magma flow became highly localized to weaker channel-like domains within the higher-strength crystal framework. Mafic schlieren formed at flow rims, and their formation presumably involved gravitational settling and velocity gradient flow sorting coupled with interstitial melt escape. Local thermal or compositional convection may have resulted in the formation of vertical schlieren tubes and ladder dikes whereas subhorizontal tubes or channels formed during flow driven by lateral gradients in magma pressure. After the cessation or deceleration of channel flow, gravity-driven processes (settling of crystals and enclaves, gravitational differentiation, development of downward dripping instabilities), accompanied by compaction, filter pressing and melt segregation, dominated in the crystal mush within the flow channels. Subsequently, magmatic folds developed in schlieren layers and the magma chamber recorded complex, late magmatic strains at high magma crystallinities. Late-stage magma pulsing into localized submagmatic cracks represents the latest events of magmatic history of the chamber prior to its final crystallization. We emphasize that the most favorable environments for the formation and preservation of magmatic structures, such as those hosted in the Jizera and Liberec granites, are slowly cooling crystal-rich mushes. Therefore, where preserved in plutons, these structures may lend strong support for a “mush model” of magmatic systems.  相似文献   

The international GLONASS experiment: products, progress and prospects   总被引：2，自引：0，他引：2  

R. Weber  T. A. Springer 《Journal of Geodesy》2001,75(11):559-568

 In October 1998 the IGEX field campaign, the first coordinated international effort to monitor GLONASS satellites on global basis, was started. Currently about 40 institutions worldwide support this effort either by providing GLONASS tracking data or in operating related data and analysis centers. The increasing quality and consistency of the calculated GLONASS orbits (about 25 cm early in 2000), even after the end of the official IGEX field campaign, are shown. Particular attention is drawn to the combination of precise ephemerides in order to generate a robust, reliable and complete IGEX orbits product. Some problems in modeling the effect of solar radiation pressure on GLONASS satellites are demonstrated. Finally, the expected benefits and prospects of the upcoming International GLOnass Service-Pilot Project (IGLOS-PP) of the International GPS Service (IGS) are discussed in more detail. Received: 17 August 2000 / Accepted: 12 April 2001  相似文献   

The impact of resolution on the accuracy of hydrologic data derived from DEMs   总被引：3，自引：0，他引：3  

TANG Guo-an  HUI Yang-he  Josef Strobl  LIU Wang-qing 《地理学报(英文版)》2001,11(4):393-401

1 Introduction Automated extraction of drainage features from DEMs is an effective alternative to the tedious manual mapping from topographic maps. The derived hydrologic characteristics include stream-channel networks, delineation of catchment boundaries, catchment area, catchment length, stream-channel long profiles and stream order etc. Other important characteristics of river catchments, such as the stream-channel density, stream-channel bifurcation ratios, stream-channel order, number…  相似文献   

Growth, ionic and osmotic relations of an Allenrolfea occidentalis population in an inland salt playa of the Great Basin Desert     

Bilquees Gul  Darrell J. Weber  M. Ajmal Khan 《Journal of Arid Environments》2001,48(4):445

Variation in growth, physiology and ionic relations patterns of Allenrolfea occidentalis, a perennial halophyte of dry habitats, was studied under field conditions from May 1996 to November 1997. An A. occidentalis community has a characteristic soil pH of 7·3–8·3. During the two years, the population was exposed to great variations in soil salinity, from 29 to 146 dS m⁻¹, and soil moisture, ranging from drought (9·2%) to wet (19%). The salt concentrations were significantly higher in the surface soil layers than in the subsurface layers. Seasonal changes in dry weight are directly related to soil salinity stress. Allenrolfea occidentalis had greater growth and biomass production under saline conditions. Na⁺and Cl⁻ions were accumulated in plant tissues in much greater amounts than K⁺, Ca²⁺, and Mg²⁺. Soil salinities were significantly reduced at the end of the growing season. Water potentials of the shoots decreased significantly with increasing salinity. The plant (F_v/F_mratio) was more affected by salinity and irradiation levels during the summer period.  相似文献   

From Land Cover to Land Use: A Methodology for Efficient Land Use Mapping over Large Areas     

Josef Cihlar  Louisa J. M. Jansen 《The Professional geographer》2001,53(2):275-289

Land use information over large areas is increasingly important for many studies related to environment in general and global change in particular. Yet there is a dearth of methodological knowledge in this area, especially regarding the practical task of producing land use maps. In this article, a systematic land use mapping approach is developed, based on land cover maps that in turn are produced through remote sensing. The concept is based on the recognition of varying strengths of land cover (LC) – land use (LU) relationships, from the thematic and spatial points of view. Several categories of relationships are identified, ranging from direct (case 1) to multiple/complex (case 4), and appropriate mapping strategies are discussed for these cases. Using a mapping study in Lebanon, it is shown that the principles embodied in this approach correspond to issues and conditions in real mapping situations. Finally, the concepts are translated into a series of steps through which the method can be applied to large areas, taking into consideration the specific requirements and constraints of each case. The final land use map represents an acceptable compromise between accuracy, level of detail, and cost.  相似文献   

Entwicklung eines Enzymimmunoassays zum Nachweis des Herbizids Mecoprop in Trink- und Grundwasser auf der Basis von Antikörpern aus den Eiern von Legehennen     

I. Westfehling  W. Weber  K. Rubach 《洁净——土壤、空气、水》1996,24(3):137-141

Development of an Enzyme Immunoassay for the Detection of Mecoprop in Drinking Water and Groundwater Based on Antibodies Raised in Chicken Egg Yolk Antibodies against mecoprop were isolated from egg yolk of immunized hens and were used for the development of an enzyme-linked immunosorbent assay. We tested assay parameters (pH and concentration of buffer, incubation temperature, kind of enzyme tracer) to optimize the standard curve for mecoprop. By decreasing the pH, the detection limit was reached at a concentration of 0.35 μg/L mecoprop. The concentration for 50% inhibition (50% B/B₀) was 2.8 μg/L. Dichlorprop and the methyl esters of both mecoprop and dichlorprop showed high crossreactivity (165%, 400% and 233%). Antibodies against mecoprop separated from egg yolk were compared to antibodies raised in rabbit for both sensitivity and specificity. Chicken immunoglobulins were found to be less sensitive and specific than the mammalian IgG's.  相似文献   

A radiation boundary condition for finite-element models: 1-D linear advection test     

Josef Brechler 《Studia Geophysica et Geodaetica》1992,36(2):188-197

Summary A linear 1-D advection equation is used to study the utilization of a finite-element method and open lateral boundary conditions. Two possible implementations of a radiation (Sommerfeld) boundary condition are tested for the case of a solitary wave passing through a computational domain — the case corresponding to zero lateral boundary values — and for the case of a simple sinusoidal wave which corresponds to a non-zero boundary forcing.  相似文献   

A contribution to the measurement of frequency dependence of electrical conductivity of rocks     

Marcela Laštovičková  Josef Bochníček 《Studia Geophysica et Geodaetica》1992,36(1):94-99

Summary Some errors of method occurring in A. C. measurements of the electrical conductivity of rocks are discussed. It is demonstrated that the difference between A.C. and D.C. conductivities, at given frequency, depends mostly on the magnitude of the D.C. conductivity and magnitude of the dielectric constant.  相似文献   

The effect of low-velocity sediments on the mislocation vectors of the GRF array   总被引：1，自引：0，他引：1  

F. Krüger  M. Weber 《Geophysical Journal International》1992,108(1):387-393

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