Response of transient rock uplift and base level knickpoints to erosional efficiency contrasts in bedrock streams     

Joshua A. Wolpert  Adam M. Forte 《地球表面变化过程与地形》2021,46(10):2092-2109

Knickpoints in bedrock streams are often interpreted as transient features generated by a change in boundary conditions. It is typically assumed that knickpoints propagate upstream with constant vertical velocities, though this relies on a stream being in erosional steady state (erosion rate equals rock uplift rate) prior to the knickpoint's formation. Recent modeling and field studies suggest that along-stream contrasts in rock erodibility perturb streams from erosional steady state. To evaluate how contrasts in rock erodibility might impact knickpoint interpretations, we test parameter space (rock erodibility, rock contact dip angle, change in rock uplift rate) in a one-dimensional (1D) bedrock stream model that has variable rock erodibility and produces a knickpoint with a sudden change in rock uplift rate. Upstream of a rock contact, the vertical velocity of a knickpoint generated by a change in rock uplift rate is strongly correlated with how the rock contact has previously perturbed erosion rates. These knickpoints increase vertical velocity upon propagating upstream of a hard over soft contact and decrease vertical velocity upon propagating upstream of a soft over hard contact. However, interactions with other transient perturbations produced by rock contacts make for nuances in knickpoint behavior. Rock contacts also influence the geometry of knickpoints, which can become particularly difficult to identify upstream of soft over hard rock contacts. Using our simulations, we demonstrate how a contact's along-stream horizontal migration rate and cross-contact change in rock strength control how much an upstream reach is perturbed from erosional steady state. When simulations include multiple contacts, the knickpoint is particularly prone to colliding with other transient perturbations and can even disappear altogether if rock contact dips are sufficiently shallow. Caution should be taken when analyzing stream profiles in areas with significant changes in rock strength, especially when rock contact dip angles are near the stream's slope.  相似文献   

Spatial distribution and source diagnosis of polycyclic aromatic hydrocarbons in soils from Chengdu Economic Region,Sichuan Province,western China     

Xinli Xing  Shihua Qi  Jiaquan Zhang  Chenxi Wu  Yuan Zhang  Dan Yang  Joshua Owago Odhiambo 《Journal of Geochemical Exploration》2011

Surface soils from the Chengdu Economic Region (CER) were analyzed for sixteen United States Environment Protection Agency priority polycyclic aromatic hydrocarbons (PAHs) to study the spatial distribution and to identify the sources of PAHs. Relatively high concentrations (more than 1500 ngg^− 1) of high molecular weight PAHs were found in Chengdu Plain, in the middle of CER, while high concentrations (more than 500 ng g^− 1) of low molecular weight PAHs were detected in the surrounding mountains. The concentrations of ∑₁₆-PAHs in topsoil samples from CER (12.52–75,431.47 ngg^− 1, average value was 3233.92 ngg^− 1) were higher than that from the southern China (21.91–3077 ngg^− 1, average value was less than 500 ngg^− 1), and they were comparable to concentrations in soils from the northern China (366–254,080 ngg^− 1, mean value was more than 3000 ngg^− 1). The concentrations from CER were also much higher than the concentrations of some world clean regions such as Antarctic (34.9–171 ngg^− 1), European high mountains (9–11,000 ngg^− 1, mean value was 158 ngg^− 1) and some Europe residential (736 ngg^− 1) and arable soils (60–145 ngg^− 1, mean value was 66 ngg^− 1). The ratio of tracer compounds (BaA/(BaA + Chr), Flo/(Flo + Pyr), and IcdP/(IcdP + BghiP)) indicated that the high concentrations of PAHs in soils were mainly derived from fossil fuels combustion in mountain region and from the incomplete combustion of petroleum in developed plain area (such as Chengdu and Deyang). From the above distribution characteristics and ratios of tracer compounds, we inferred the reasons for the distribution pattern of PAHs in CER were the domestic heating, emissions, and the physicochemical properties of PAHs.  相似文献   

Erosion-driven drawdown of atmospheric carbon dioxide: The organic pathway     

Niels Hovius  Albert Galy  Robert G. Hilton  Robert Sparkes  Joanne Smith  Kao Shuh-Ji  Chen Hongey  Lin In-Tian  A. Joshua West 《Applied Geochemistry》2011

Rapidly eroding, coastal mountain belts, where steep rivers and submarine channels connect upland sources to nearby marine sinks are hotspots of organic carbon transfer from life biomass, soil and exhumed bedrock into geological storage. Using observations from the Southern Alps of New Zealand, and Taiwan, we have mapped this organic pathway to geological carbon sequestration, and can evaluate the magnitude and efficiency of transfers between sources and sinks. We demonstrate that POC is harvested by landsliding, but importantly also by common and widespread surface runoff on steep hillslopes. Although terrestrially sourced POC is found in many sedimentary environments associated with mountain belts and frontier basins, it appears to be most abundantly trapped and preserved in marine turbidites. The loss of all forms of POC in onward transport through short, steep routing systems to this repository is limited. This is in marked contrast to larger routing systems, in which only the most resilient forms of POC survive into long-term deposition.  相似文献   

Stability and equation of state of post-aragonite BaCO3     

Joshua P. Townsend  Yun-Yuan Chang  Xiaoting Lou  Miguel Merino  Scott J. Kirklin  Jeff W. Doak  Ahmed Issa  Chris Wolverton  Sergey N. Tkachev  Przemyslaw Dera  Steven D. Jacobsen 《Physics and Chemistry of Minerals》2013,40(5):447-453

At ambient conditions, witherite is the stable form of BaCO₃ and has the aragonite structure with space group Pmcn. Above ~10 GPa, BaCO₃ adopts a post-aragonite structure with space group Pmmn. High-pressure and high-temperature synchrotron X-ray diffraction experiments were used to study the stability and equation of state of post-aragonite BaCO₃, which remained stable to the highest experimental P–T conditions of 150 GPa and 2,000 K. We obtained a bulk modulus K ₀ = 88(2) GPa with $K'$  = 4.8(3) and V ₀ = 128.1(5) ų using a third-order Birch-Murnaghan fit to the 300 K experimental data. We also carried out density functional theory (DFT) calculations of enthalpy (H) of two structures of BaCO₃ relative to the enthalpy of the post-aragonite phase. In agreement with previous studies and the current experiments, the calculations show aragonite to post-aragonite phase transitions at ~8 GPa. We also tested a potential high-pressure post–post-aragonite structure (space group C222 ₁ ) featuring four-fold coordination of oxygen around carbon. In agreement with previous DFT studies, ΔH between the C222 ₁ structure and post-aragonite (Pmmn) decreases with pressure, but the Pmmn structure remains energetically favorable to pressures greater than 200 GPa. We conclude that post–post-aragonite phase transformations of carbonates do not follow systematic trends observed for post-aragonite transitions governed solely by the ionic radii of their metal cations.  相似文献   

Carbonate Mineral Saturation State as the Recruitment Cue for Settling Bivalves in Marine Muds     

Mark A. Green  George G. Waldbusser  Lane Hubazc  Eric Cathcart  Joshua Hall 《Estuaries and Coasts》2013,36(1):18-27

After a pelagic larval phase, infaunal bivalves undergo metamorphosis and transition to the underlying sediments to begin the benthic stage of their life history, where they explore and then either accept or reject sediments. Although the settlement cues used by juvenile infaunal bivalves are poorly understood, here we provide evidence that carbonate saturation state is a significant chemical cue in both direct observation laboratory studies and field manipulations. In the laboratory, plantigrade-stage Mercenaria mercenaria (200 μm shell height) showed a significant positive relationship between percent burrowed and Ω_aragonite, with an increasing probability of settlement with increasing saturation state. In the field, we increased bivalve recruitment by a factor of three in a 30-day field study by raising the pH (～0.3) and saturation state of surface sediments by buffering sediments with crushed shell (CaCO₃). The susceptibility of infaunal bivalves to dissolution mortality and the tight coupling of other sedimentary biogeochemical processes with carbonate dynamics suggest that mineral thermodynamics may be an overarching cue new settlers are responding to.  相似文献   

Nature and degree of aqueous alteration in CM and CI carbonaceous chondrites     

Driss Takir  Joshua P. Emery  Harry Y. Mcsween Jr.  Charles A. Hibbitts  Roger N. Clark  Neil Pearson  Alian Wang 《Meteoritics & planetary science》2013,48(9):1618-1637

We investigated the petrologic, geochemical, and spectral parameters that relate to the type and degree of aqueous alteration in nine CM chondrites and one CI (Ivuna) carbonaceous chondrite. Our underlying hypothesis is that the position and shape of the 3 μm band is diagnostic of phyllosilicate mineralogy. We measured reflectance spectra of the chondrites under dry conditions (elevated temperatures) and vacuum (10^?8 to 10^?7 torr) to minimize adsorbed water and mimic the space environment, for subsequent comparison with reflectance spectra of asteroids. We have identified three spectral CM groups in addition to Ivuna. “Group 1,” the least altered group as determined from various alteration indices, is characterized by 3 μm band centers at longer wavelengths, and is consistent with cronstedtite (Fe‐serpentine). “Group 3,” the most altered group, is characterized by 3 μm band centers at shorter wavelengths and is consistent with antigorite (serpentine). “Group 2” is an intermediate group between group 1 and 3. Ivuna exhibits a unique spectrum that is distinct from the CM meteorites and is consistent with lizardite and chrysotile (serpentine). The petrologic and geochemical parameters, which were determined using electron microprobe analyses and microscopic observations, are found to be consistent with the three spectral groups. These results indicate that the distinct parent body aqueous alteration environments experienced by these carbonaceous chondrites can be distinguished using reflectance spectroscopy. High‐quality ground‐based telescopic observations of Main Belt asteroids can be expected to reveal not just whether an asteroid is hydrated, but also details of the alteration state.  相似文献   

Annual floods in New England (USA) and Atlantic Canada: synoptic climatology and generating mechanisms   总被引：1，自引：1，他引：0  

Mathias J. Collins  Johnathan P. Kirk  Joshua Pettit  Arthur T. DeGaetano  M. Sam McCown  Thomas C. Peterson 《自然地理学》2014,35(3):195-219

New England and Atlantic Canada are characterized by mixed flood regimes that reflect different storm types, antecedent land surface conditions, and flood seasonality. Mixed flood regimes are known to complicate flood risk analyses, yet the synoptic climatology and precipitation mechanisms that generate annual floods in this region have not been described in detail. We analyzed a set of long-term annual flood records at climate-sensitive stream gauges across the region and classified the synoptic climatology of each annual flood, quantitatively describing the precipitation mechanisms, and characterize flood seasonality. We find that annual floods here are dominantly generated by Great Lakes-sourced storms and Coastal lows, known locally as ‘nor’easters.’ Great Lakes storms tend to be associated with lower magnitude annual floods (<75th percentile) and Coastal lows are more clearly associated with higher magnitude events (>75th percentile). Tropical cyclones account for few of all annual floods, including extreme events, despite causing some of the region’s largest and most destructive floods. Late winter/early spring is when the greatest number of annual floods occur region wide, and rainfall is the dominant flood-producing mechanism. Rainfall in combination with snowmelt is also important. Both mechanisms are expected to be impacted by projected regional climate change. We find little evidence for associations between flood-producing synoptic storm types or precipitation mechanisms and large-scale atmospheric circulation indices or time periods, despite upward trends in New England annual flood magnitudes. To more completely investigate such associations, partial duration flood series that include more floods than just the largest of each year, and their associated synoptic climatologies and precipitation mechanisms, should be analyzed.  相似文献   

Landscape position and spatial patterns in the distribution of land use within the southern Appalachian Mountains   总被引：1，自引：1，他引：0  

Joshua S. Rice  Ryan E. Emanuel 《自然地理学》2014,35(5):443-457

Understanding the forces that influence the distribution of land use and land-use change (LUC) is an essential step in developing effective strategies for managing these issues. We examined the influence of landscape position on spatial patterns in land-use distribution within the Little Tennessee River Basin (LTRB) of the southern Appalachian Mountains. We show that landscape position, defined with respect to both natural and anthropogenic spatial variables, provides for the identification of statistically significant differences in the distribution of common forms of land use in the study region. Using the same variables, significant differences in the landscape positions subject to land-use change in the LTRB are also examined. These results suggest landscape position exerts a strong influence on the distribution of different forms of land use and the likeliness of given area undergoing LUC. The approach presented here, of considering land use as a function of landscape position that responds to both natural and anthropogenic forces, may prove useful in aiding the development of future strategies to address the consequences of land use in many regions.  相似文献   

“Story-Networks” of Livestock and Climate Change: Actors,Their Artifacts,and the Shaping of Urban Print Media     

Keith Chun Leem Lee  Joshua Peter Newell  Jennifer Wolch  Nicole Schneider  Pascale Joassart-Marcelli 《社会与自然资源》2014,27(9):948-963

Despite widespread media coverage of livestock-related issues and growing scientific evidence linking meat production and climate change, systematic content analysis of this relationship in media coverage has been surprisingly minimal. In this article, we combine actor-network theory with framing theory to develop the basis for “story-networks”—networks of actants and artifacts that shape how a media report or “story” is framed. We coded livestock-related articles from a major U.S. newspaper, the Los Angeles Times, over the 1999–2010 period to understand how various actants and artifacts shaped different story-networks. Just 5% of all livestock articles addressed connections with climate change; these articles focused on technology, lifestyle, or policy. Distinctive story-networks characterized each category, framing the livestock–climate change linkage as an issue to be addressed through either technological innovation, individual lifestyle choices, or policy action. In each story-network type, varying configurations of actants and artifacts were involved, including the cattle themselves.  相似文献   

Symbol Store: sharing map symbols for emergency management     

Anthony C. Robinson  Scott Pezanowski  Sarah Troedson  Raechel Bianchetti  Justine Blanford  Joshua Stevens 《制图学和地理信息科学》2013,40(5):415-426

Maps are a primary means for supporting information sharing and collaboration in emergency management and crisis situations. While a variety of formalized map symbol standards for emergency contexts exist, they have not been widely adopted by mapmakers. Informal symbol conventions are commonly used within emergency management stakeholder groups, but until now there has not been a flexible mechanism for discovering, sharing, and previewing these symbol sets among mapmakers. In this paper, we describe the design and development of the Symbol Store, a visually enabled, web-based interactive tool intended to help mapmakers share point symbols. The Symbol Store allows users to browse symbols by keyword, category tags, and contributors. It also allows for symbols to be previewed on realistic maps prior to download. An initial prototype of the Symbol Store was evaluated by flood mapping experts from the State of California, and the results of this user study led to multiple refinements now implemented in the public version of Symbol Store located at www.symbolstore.org.  相似文献