Oxydation expérimentale de Fe-tourmalines et corrélation avec une déprotonation des groupes hydroxyleAnnealing in oxidising conditions of Fe-tourmalines and correlated deprotonation of OH groups     

Yves Fuchs  Martine Lagache  Jorge Linares 《Comptes Rendus Geoscience》2002,334(4):245-249

Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O₂)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe²⁺ into Fe³⁺ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe²⁺ into Fe³⁺ is charge-balanced by deprotonation of the external OH₍₃₎ groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249.  相似文献   

Le Bassin lusitanien (Portugal) à l'Aptien supérieur–Albien : organisation séquentielle,proposition de corrélations, évolutionThe Lusitanian Basin (Portugal) during the late Aptian–Albian: sequential arrangement,proposal of correlations,evolution     

Jorge Dinis  Jacques Rey  Pierre-Charles de Graciansky 《Comptes Rendus Geoscience》2002,334(10):757-764

. Three transgressive–regressive 2nd-order cycles were identified in the Upper Aptian–Albian fluvial and marine deposits of the Lusitanian Basin. Its widespread nature, probably including eustatic origin, allows correlation between the southern package, with precise stratigraphic positioning, and the northern series with a poorly constrained age. The main unconformities can be related to the onset of an oceanic crust, in the western margin of Galicia during the Late Aptian, in the bay of Biscay during the Early Albian, and, to the northwest of the Galicia triple point, during the Middle to Late Albian transition, and, at the Albian–Cenomanian boundary, to a probable compressive event with Africa due to the rotation of Iberia. To cite this article: J. Dinis et al., C. R. Geoscience 334 (2002) 757–764.  相似文献   

Low-amplitude, synsedimentary folding of a deltaic complex: Roda Sandstone (lower Eocene), South-Pyrenean Foreland Basin     

M. López-Blanco  M. Marzo  J.A. Muñoz 《Basin Research》2003,15(1):73-96

The South‐Pyrenean Foreland Basin is a sedimentary trough developed during Palaeogene times in response Pyrenean orogenesis. The structural development of the chain progressively involved the foreland basin deposits resulting in synsedimentary thrusting and growth of folds through the basin. The lower Eocene Roda Sandstone was deposited in a shallow‐marine environment whose topography (bathymetry) was modified by a series of growing gentle folds. This synsedimentary folding is evidenced in the field (i) thickening of sedimentary units above synclinal structures and thinning over anticlines; (ii) carbonate platform deposits growing on top of anticlines; (iii) the areal distribution of benthic foraminifera in transgressive facies assemblages determined by an irregular, fold‐influenced palaeobathymetry; (iv) variation of sandstone palaeocurrents related to the presence of a sedimentary trough formed by the synsedimentary growth of a syncline. In addition, synsedimentary folding has been evidenced from seismic data. In the Roda Sandstone example, the growth of gentle folds occurred in an area with high sedimentation rates (～0.21 ± 0.06 mm y^?1). Due to the high sedimentation rates, exceeding the folds uplift rate (～0.10 ± 0.01 mm y^?1), there are no noticeable unconformities in the growth strata at outcrop scale. However, the effects on the sedimentation are very significant, because the sediments were deposited close to sea level, and thus were very sensitive to fauna and facies distribution.  相似文献   

Habitat, occurrence and conservation of Saharo-Arabian-Turanian element Forsskaolea tenacissima L. in the Iberian Peninsula   总被引：1，自引：0，他引：1  

Javier Cabello  Domingo Alcaraz  Francisco Gmez-Mercado  Juan F. Mota  Javier Navarro  Julio Peas  Esther Gimnez 《Journal of Arid Environments》2003,53(4):491-500

The aim of this study is to assess the Iberian populations of Forsskaolea tenacissima L. according to its biogeographical interest, habitat, geographical range and conservation status. Results point out that they are restricted to gravel wadis of Tabernas Desert (SE Spain), are scarcely included in protected areas and represent historically isolated populations with relict behaviour. We also describe a new association, Senecioni-Forsskaoleetum tenacissimae. Conservation status of species is cause for concern and two conservation actions must be carried out. Firstly, protected areas should house Forsskaolea populations and secondly, phytosociological characterization of a community allows inventorying its habitat and directing conservation efforts to community level.  相似文献   

吉林省土壤中有效锰、铜、钼和锌含量的时空变化   总被引：5，自引：0，他引：5  

杨娟  王冬艳 《世界地质》2003,22(4):392-395

选择吉林省的五个大豆种植区(敦化、桦甸、榆树、农安、白城)、四个水稻种植区(白城、九台、延吉、梅河口)及3个草场分布区(镇赉、洮南、大安)，对其土壤中有效锰、铜、钼和锌的含量在过去20年的变化作了比较和分析。经研究表明：吉林省土壤中有效锰和有效铜含量较20年前有所增高，有效钼含量总体呈降低趋势，中部部分地区和东部地区土壤有效锌含量降低，其余地区含量增高。空间分布东部高于中西部。  相似文献   

天然含钒金红石加热、淬火及电子辐射改性实验研究   总被引：4，自引：5，他引：4       下载免费PDF全文

刘娟鲁安怀  郭延军李宁  李巧荣郑佳 《岩石矿物学杂志》2003,22(4):339-344

天然含钒金红石样品经过1273K加热、淬火和高能电子辐照处理后性质发生不同程度的变化。XRD谱峰显示处理前后样品没有发生物相变化，显微IR图谱证明原样、加热、淬火样品的表面有少量吸附水存在，而辐射样品的显微IR图谱上没有检测到吸附水的吸收峰。用XPS分析比较了处理前后样品表面主要元素Ti、O和V的价态及含量，结果表明，原样经过处理后表面钒和氧的原子百分含量增加，其中淬火样品表面吸附水和钒的含量相对于原样增加最为明显，光催化活性相应较高；加热样品表面的吸附水和钒的含量比原样稍有增加，光催化活性与原样相当；电子辐射样品表面钒的原子百分含量相对原样增加不明显，而对水的吸附能力相对原样较低，光催化效率也略低。  相似文献   

An experimental study of nominally symmetric and asymmetric structures isolated with the FPS     

Juan C. de la Llera  Jos L. Almazn 《地震工程与结构动力学》2003,32(6):891-918

This experimental investigation deals with the earthquake behaviour of a nominally symmetric and a mass‐asymmetric three‐storey structural model isolated with the frictional pendulum system (FPS). Both accidental and natural torsion are evaluated in the structure by using recorded accelerations in all building floors and measured deformations at the isolation level. A 3D‐shaking table was used to subject the model to five different ground motions, including impulsive as well as far‐field subduction‐zone type earthquakes. Results show that the analytical predictions of the earthquake behaviour of the isolated structure, as obtained from a physical model of the FPS, are in close agreement with the true complex inelastic measured behaviour of the FPS. Besides, experimental results also validate previous observations about the importance of accounting for the variability of the normal loads in modelling the earthquake behaviour of FPS isolators. Measured torsional deformation amplifications at the base of the building vary, in the mean, from 2.5% to 6% for the symmetric and asymmetric structural configurations, respectively. In relation to the fixed base structure, the reduction factors for the base shear of the isolated structure are, in the mean, about 3.9 for both configurations. Finally, it is concluded that the FPS is capable of controlling the lateral–torsional motions of mass‐asymmetric structures quite effectively by aligning the centre of mass of the superstructure with the centre of pendular and frictional resistance of the isolation system. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Physical model for dynamic analysis of structures with FPS isolators     

Jos L. Almazn  Juan C. De la Llera 《地震工程与结构动力学》2003,32(8):1157-1184

This article presents a physical model for frictional pendulum isolators (FPS) that is ready to be implemented in most commercial software. The model is capable of accounting for effects such as large deformations, sticking, and uplift and impact by sensing the normal loads in the isolators through a gap element. Sticking has been incorporated into the model by extending the Park–Wen hysteretic model to the case of large deformations. The proposed model has been tested against a theoretically ‘exact’ formulation leading to essentially identical results. To facilitate its use, the physical FPS model has been cast into a typical non‐linear structural element format, i.e. with deformation as input and restoring force as output. Examples of a building and a bridge have been chosen to show the potential of the element and to provide further insight into the earthquake response of structures with FPS isolators; in particular, in aspects such as the orientation in placement of the isolator, sticking, P? Δ, and other large deformation effects. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Inelastic displacement ratios for evaluation of existing structures     

Jorge Ruiz‐García  Eduardo Miranda 《地震工程与结构动力学》2003,32(8):1237-1258

Results of a detailed statistical study of constant relative strength inelastic displacement ratios to estimate maximum lateral inelastic displacement demands on existing structures from maximum lateral elastic displacement demands are presented. These ratios were computed for single‐degree‐of‐freedom systems with different levels of lateral strength normalized to the strength required to remain elastic when subjected to a relatively large ensemble of recorded earthquake ground motions. Three groups of soil conditions with shear wave velocities higher than 180m/s are considered. The influence of period of vibration, level of lateral yielding strength, site conditions, earthquake magnitude, distance to the source, and strain‐hardening ratio are evaluated and discussed. Mean inelastic displacement ratios and those associated with various percentiles are presented. A special emphasis is given to the dispersion of these ratios. It is concluded that distance to the source has a negligible influence on constant relative strength inelastic displacement ratios. However, for periods smaller than 1s earthquake magnitude and soil conditions have a moderate influence on these ratios. Strain hardening decreases maximum inelastic displacement at a fairly constant rate depending on the level of relative strength for periods of vibration longer than about 1.0s while it decreases maximum inelastic displacement non‐linearly as the period of vibration shortens and as the relative‐strength ratio increases for periods of vibration shorter than 1.0s. Finally, results from non‐linear regression analyses are presented that provide a simplified expression to be used to approximate mean inelastic displacement ratios during the evaluation of existing structures built on firm sites. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

从激光扫描数据中进行建筑物特征提取研究   总被引：42，自引：4，他引：42  

李必军  方志祥  任娟 《武汉大学学报(信息科学版)》2003,28(1):65-70

提出了一套基于建筑物几何特征的信息挖掘方案，并具体介绍了研究中采用的一些原理、方法与实用算法，从而可以直接从激光扫描数据中提取建筑物的平面外轮廓信息。利用本方案对车载激光扫描系统获取的城市建筑物试验数据进行了具体的处理，并给出了三维建模和可视化表达结果。  相似文献